查询词典 propenyl

The immobilized ligands have been applied to the Pd-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate.

这些负载的P-N 配体被应用到Pd催化的、1，3-二苯基-2-丙酸乙酯的烷基化反应中。

Chiral N,P ligand 5 was examined for the asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate with up to 89% yield and up to 81.6% ee.

化合物5用于钯催化的1，3-二苯基-2-烯丙基乙酸酯的不对称烯丙基烷基化反应，产率为89%，对映体过量最高为81.6% ee。

ABSTRACT Immobilized penicillin acylase (from E.coli) was used to catalyze 7 phenylacetamido 3 E propenyl cephalosporanic acid hydrolyzation into 7 amino 3 E propenyl cephalosporanic acid. Then, trans APRA was acylated with hydroxyethyl ester of 4 hydroxy D phenylglycine to obtain trans cefprozil.

以7 苯乙酰氨基 3 E 丙烯基 3 头孢菌素 4 羧酸为原料，在青霉素酰化酶作用下，首先酶法水解得到3 E 丙烯基 3 头孢菌素 4 羧酸，过滤固相酶，滤液调pH分离得到反式APRA固体；在青霉素酰化酶作用下，反式APRA再与对羟基苯甘氨酸乙二醇酯缩合，得到反式头孢丙烯；酶法合成所得的产品与进口反式头孢丙烯对照品一致。

To counter the problems present in the CO 2 removal with PC method in the little scale ammonia synthesis plant at present, the effect of CO 2 removal plant with carbonic propenyl ester method on the different factors of normal production has been analysed in detail.

针对目前小合成氨厂碳丙脱碳存在的问题，详细分析了影响碳丙脱碳装置正常生产的因素，总结了 90年代以来人们在解决生产实践中诸多问题的经验和方法，对碳丙脱碳工艺作了总结与评述。

Contained acrylamide propenyl disulfide and II and II propenyl disulfide and cyclic sulfide Alliin are higher than white garlic more than doubled.

所含丙烯二硫化物和二丙烯基二硫化物和二丙烯基硫化物及环蒜氨酸都高出白皮大蒜一倍以上。

It showed that the blend system had much slower Rp than that of hybrid monomer, either of acrylate double bond or propenyl ether double bond, and propenyl ether double bond conversion of hybrid monomer was much higher than that of the blend system at the end.

杂化单体与相同类型的混合体系相比，每种基团的反应动力学性质都得到了促进，丙烯酸酯和丙烯基醚双键的聚合速率都有了很大提高，丙烯基醚双键的转化率较混合体系有很大增加。

A commercial and practical synthesis rout with-2-(3-acetoxy-l-me-thyl-l~propenyl)-5,5-dimethyl-l,3-dioxane as starting material by couple,oxidation, Ramberg-Backlund and deprotection is chosen and studied in this paper.

本文选择了以2-(3-氯-1-甲基-1-丙烯)-5，5-二甲基-1，3-二噁烷为原料，经偶连、氧化、Ramberg-Bcklund反应及脱保护基四步反应的合成路线，对该中间体进行合成研究。

Results showed that the hybrid monomer could photopolymerize effectively and both free radical and cationic polymerization processes were improved. When 2-Hydroxy-2-methyl-1-phenyl-1-propanone (1173) was introduced into hybrid system containing UVI-6976, the final conversion of propenyl ether double bond and polymerization rate increased obviously. The comparison of photopolymerization kinetics between hybrid and blend system was investigated as well.

结果表明，以硫鎓盐为光引发剂时，这三种杂化单体均可以有效进行杂化光聚合反应，丙烯基醚和丙烯酸酯双键都显示出较快的反应速度和较高的最终转化率，同时在简单结构的硫鎓盐（UVI-6976）引发体系中加入自由基引发剂2-羟基-2-甲基-1-苯基-1-丙酮（1173）后，丙烯基醚双键的阳离子聚合速率和最终转化率都有了很大提高。

The reaction of the compound - 3 - triaiylstannyl -1,1 - diphenyl - 2 - propenyl - 1 -ol with ICl,Br2,I2 formed organotin halides ,which reacted with KOH to form organotin oxide or hydroxide.

首次以非碳环醇-3-三芳基锡基-1，1-二苯基-2-丙烯基-1-醇[Ph_2 CCH=CHSnAr_3]和卤素或拟卤素发生取代反应得到卤化物，并以此合成了氢氧化物、氧化物和配合物。

We prepared the pyrethric acid II through four reactions: esterification, oxidation, decomposition, diesterification. And the original synthesis route of the pyrethric acidII was improved: the yield of oxidation of allyl rise through increasing the activity of Selenium dioxide; in the document, tert-butyl-trans -2, 2-dimethy1-3-(2"-methoxycarbony1-1"-propenyl)cyclopropanecarboxy late was synthesized from tert-butyl-trans-2,2-dimethyl-3-(2 -formyl-r -propenyl) cyclopropanecarboxylate with two steps, with low yield.

我们经过酯化，氧化，成双酯，热分解四步反应，成功地得到了第二菊酸，并改进了原第二菊酸的合成路线：通过改变二氧化硒的活性提高了烯丙甲基的氧化产率；将原路线中醛氧化成羧酸、羧酸酯化的两步反应改为醛和甲醇、二氧化锰等作用一步直接酯化的方法，减少了反应步骤，提高了总收率。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新