查询词典 propanediol

Using butyraldehyde and 1,2-propanediol as raw materials, H3PW6Mo6O 40 /TiO2 as catalyst, butyraldehyde 1,2-propanediol acetal is synthesized.

以二氧化钛负载磷钨钼杂多酸为催化剂，通过丁醛和1，2-丙二醇反应合成了丁醛1，2-丙二醇缩醛。

First, a chlorinator was self-designed in this paper, and dichloride of 2-methyl-1-propene was synthesized by 2-methyl-1-propene reacted with chlorine fast in this reactor. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the yield and selectivity of dichloride of 2-methyl-1-prop-ene were more than 65% and 80% respectively. Second, the preparation of 2-methylene-1, 3-propanediol, which dichloride of 2-methyl-1-propene reacted with alkali was investigated. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the conversion of dichloride of 2-methyl-1-propene was 100%. Moreover the preparation of MPO, which 2-methylene-1, 3-propanediol reacted with hydrogen, in presence of Al_2O_3-Pd catalyst, was gotten, and the product was appraised.

本文在氯化反应过程中，自行设计制作出了氯化管式反应器，在该反应器中异丁烯和氯气迅速混合反应生成二氯异丁烯，根据该氯化反应特征利用正交试验和单因素试验考察了有关因素的影响并优化得到了最佳工艺条件，二氯异丁烯的总收率达65％以上，选择性达80％；接着，对二氯异丁烯进行水解反应制得了2-甲烯-1，3-丙二醇，讨论了相关因素对水解反应的影响，并通过正交试验和单因素试验得到了较佳工艺条件，二氯异丁烯的转化率达100％；同时还对制备的2-甲烯-1，3-丙二醇在常压下采用三氧化二铝负载钯催化剂催化加氢得目的产物MPO，并对产品进行了鉴定，从而打通了整个工艺路线。

Propanediol oxidoreductase is the key enzyme in converting glycerol to 1,3-propanediol.

1，3-丙二醇氧化还原酶是以甘油为底物生产1，3-PD途径中的关键酶之一。

As to 1,3-propanediol oxidoreductase, the Km value for NAD and 1,3-propanediol are 0.15 ±10-3 M and 0.97±10-3 M respectively.

最后，本文考察了甘油脱氢酶和1，3—丙二醇氧化酶的动力学性质。

The results indicated that CHCl3 was optimum reagent and the reaction temperature was better controlled at 10~15℃. Dinitrogen tetraoxide and nitric acidhad a detrimental effect on the yield and purity of 1,2-propanediol dinitrate. When the concentrations of dinitrogen tetroxide and nitric acid were below 1.00% and 5.53% respectively, these detrimental effects could be neglected. Under the optimum conditions, the yields and the purity of 1,2-propanediol dinitrate were 99.01% and 95.89%, respectively.

同时考察了反应溶剂、反应温度、N_2O_5中N_2O_4和HNO_3杂质对1，2-丙二醇二硝酸酯收率和纯度的影响，结果表明，适宜的溶剂是CHCl3；适宜的反应温度为10～15℃；在适宜条件下，1，2-丙二醇二硝酸酯的收率和纯度可分别达到99.01%和95.89%；N_2O_4和HNO_3对产物的收率和纯度均有不利影响，但当N_2O_5中N_2O_4含量小于1.00%，HNO_3含量小于5.53%时，对产物收率和纯度的影响不大。

The invention relates to a process for producing polyethylene terephthalate 1, 3-propanediol, which comprises the following steps: using titanic acid ester as major catalyst, using germanium compounds and cobalt compounds as synergic catalyst, conducting esterification reaction for poly terephthalic acid and 1, 3-propanediol according to the molar 1:1.05-2.2 under the nitrogen pressure of 0.1-0.4MPa and 230-265 DEG C, or conducting ester exchanging reaction for poly terephthalic acid and 1, 3-propanediol according to the molar ratio 1:1.8-2.2 in 160-220 DEG C, decompressing reaction to high vacuum 10-150Pa, wherein the final temperature of reaction is 265-275 DEG C, recovering to normal pressure with nitrogen to obtain the PTT product.

本发明涉及一种生产聚对苯二甲酸1，3-丙二醇酯的方法，采用以钛酸酯为主催化剂，锗化合物和钴化合物为协同催化剂，对苯二甲酸二甲酯和1，3-丙二醇按摩尔1∶1.05-2.2，在0.1-0.4MPa氮气压力和230-265℃下进行酯化反应，或对苯二甲酸二甲酯和1，3-丙二醇按摩尔比1∶1.8-2.2，在160-220℃进行酯交换反应，将反应减压至高真空10-150Pa，反应终温在265-275℃，用氮气恢复到常压，得到本PTT产品；大大缩短了反应时间，直接聚合制备特性粘度在0.7-1.05dL/g的PTT切片，使反应产物色相良好，PTT产品可用于纤维加工及工程塑料领域。

Attempts in part I of the dissertation were to develop microemulsion systems using medium chain triglyceride, Captex 300, deionized water (H2O), and TPGS as surfactant for the oral delivery of protein drugs or poorly water soluble drugs. Pseudo-ternary phase diagrams were constructed to elucidate the phase behavior of systems composed of medium-chain triglyceride and water with TPGS as main surfactant, polysorbates (Tween 20, Tween 40, Tween 60 and Tween 80) as adjuvant surfactants, and polyethylene glycols (PEG 400 and PEG 600) and polyols (ethanediol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol and glycerin) as cosurfactants.

藉由拟三相图（Pseudo-ternary Phase Diagrams）的建立来了解中链型三酸甘油酯、去离子水及TPGS为主要界面活性剂配合聚醇山梨酯（如Tween 20、Tween 40、Tween 60及Tween 80）为辅助界面活性剂或聚乙二醇（如PEG 400及PEG 600）及多醇类（如乙二醇、1，2-丙二醇、1，3-丙二醇、1，3-丁二醇、1，4-丁二醇及甘油作为共界面活性剂所形成的微乳基剂之相变化。

Isobutyraldehyde 1,2-propanediol acetalwas synthesized from isobutyraldehyde and 1,2-propanediol in the presence of aminosulfonic acid as catalyst.

详实地阐述了新型固体超强酸SO2-4/TiO2-MoO3催化剂的制备方法及其应用实例———催化合成异丁醛1，2-丙二醇缩醛新工艺。

Intermidiate 1, 2-propanediol-sebacate was synthesized with 1, 2-propanediol and sebacic acid, then a novel degradable elastomer, poly, was synthesized by melt phase polycondensation of 1, 2-propanediol-sebacate and citric acid under under certain conditions.

通过癸二酸与1，2-丙二醇反应，生成中间体癸二酸聚酯二元醇，然后将中间体与柠檬酸在一定条件下熔融缩聚制得了一种可降解弹性体聚癸二酸丙二醇柠檬酸酯。

In comparison with the anaerobic batch fermentation of 1,3-propanediol from saponified glycerol, the bioprocess of two successive microbial fermentations for the production of 1,3-propanediol was feasible. The yield of 1,3-propanedio was higher than that of 1,3-propanediol directly from saponified glycero with 15 h in the two-stage fermentation in a 18h batch fermentation.

玉米淀粉。微生物发酵1，3一丙二醇(1，3-propanediol，简称1，3一PD)是一种重要的化工原料，与乙二醇、l，2一丙二醇和1，4一丁二醇有着相似的性质和用途，但又有许多其他二醇所不具备的优点，尤其是1，3-PD与对苯二甲酸合成的新型聚酯——聚对苯二甲酸丙二酯所展示的许多优良特性，使1，3一PD的研究开发日趋活跃。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了