查询词典 porphyrin

We firstly succeeded in the separation of the new cationic complexes of tetrakis (4-methoxyphenyl) porphyrin with yttrium, erbium, thulium and ytterbium (RE-TMOPP-Cl) by reserved-phase high performance liquid chromatography.

我们首次用高效液相色谱分离了性质极其相似的钇、铒、铥和镱四个重稀土的阳离子型四（4-甲氧基苯基）卟啉配合物。

In the first part, we have used hydrogen bonding-mediated rigidified aromatic oligoamide backbones to construct a new molecular tweezer which is appended with two zinc porphyrin moieties.

在第一部分工作中，我们通过分子内氢键驱动的刚性寡聚芳香酰胺骨架构建了一种新型的锌卟啉分子镊。

A novel butterfly-shaped fullerene-diporphyrin triad was designed and synthesized,in which 〓 is in the mid of two porphyrin rings and this structure feature enables it to be apotential candidate for the manufacture of Gr〓tzel solar cell and unimolecular logicalcircuit.

设计并合成了一个新的蝴蝶形富勒烯-双卟啉三元分子并确定了结构，两个卟啉环将〓夹在中间，这样的结构有利于探索增加电子／能量给体数目对电荷／能量向富勒烯传递速率的影响，并且这个分子可望被用于太阳能电池制造和单分子逻辑电路的设计上。

The pure isomers 3-(1-hydroxyethyl)-8-vinyldeuteroporphyrin Ⅸ and 3-vinyl-8-(1-hydroxyethyl)deuteroporphyrin Ⅸ were obtained from protoporphyrin Ⅸ dimethyl ester.Starting from these two acetylating compounds,eight new porphyrin derivatives were synthesized through an alkyloxy fission reaction.

以原卟啉Ⅸ二甲酯为起始原料，合成并分离得到3-(1-羟乙基)-8-乙烯基次卟啉Ⅸ（Ⅱ1）和3-乙烯基-8-(1-羟乙基)次卟啉Ⅸ（Ⅱ2）二个异构体，两者分别经酰化后与醇进行烷氧裂解反应合成了8个全新的卟啉衍生物。

The recognition properties between porphyrin dimer 4 and amygdalic acid was studied by UV-vis spectrum. The resu...

结果表明，双卟啉与苦杏仁酸之间形成1∶2的络合物，其结合位点在卟啉环内。

Porphyrin dimers ; synthesis ; interaction ; amygdalic acid

双卟啉化合物；合成；相互作用；苦杏仁酸

The reaction mechanism and the dynamic were investigated Some results were obtained as the following:1. Investigation on the photo-induced reaction mechanism of porphyrin/benzoquinonePoiphyrin/benzoquinone/CK3OD and benzoquinone/CDsOD were studied by CIDNP and ESR technique.

本文采用化学诱导动态核极化和电子自旋共振等方法，针对光合作用模型体系的光激发电子转移和基态相互作用以及跨膜电子传递反应动力学等问题，从反应机理及动力学等角度进行了探索性研究。

The second-order nonlinear optical properties of the binaphthyl bridged chiral bis-porphyrins were greatly improved by introducing push/pull substituents onto the porphyrin chromophore.

卟啉环上引入推／拉电子基团可以有效地提高手性联萘桥联双卟啉的二阶非线性光学系数。

A water-soluble porphyrin dimer containing eight positive charges, bridged by 4,4 -dicar- boxy-2,2 -bipyridyl, has been synthesized.

以4，4'-二羧酸-2，2'-联吡啶为桥联试剂，合成了一种含8个阳离子的水溶性桥联双卟啉。

The results indicate that, three-dimensional double-porphyrin derivatives with butadiyne linkages have very large TPA cross section, which is a promising direction for further development of novel TPA materials.

研究发现，以丁二烯为连接桥的三维双卟啉衍生物具有大的双光子吸收截面，是一类有应用前景的双光子吸收材料。

In the negative and interrogative forms, of course, this is identical to the non-emphatic forms.

。但是，在否定句或疑问句里，这种带有"do"的方法表达的效果却没有什么强调的意思。

Go down on one's knees;kneel down

屈膝跪下。。。下跪祈祷