查询词典 porphyrin

It was also found that the absorption wavelength s of porphyrin and magnesium porphyrin had the general red shift.

计算结果表明溶剂环境中氢卟啉和镁卟啉分子的电子吸收光谱发生了普遍的红移，结合分子轨道理论对这种变化给出了可能的解释。

In the end, the application of chiral porphyrin is summarized. It is expected that chiral porphyrin would be effective catalysts in industrial production. Contents

最后总结了手性卟啉研究成果的应用范围，并展望了手性卟啉在催化氧化方面的研究和发展方向。

Methods In view of the selective accumulation of porphyrin derivatives in tumor tissue, three ftorafur-porphyrin compounds and three metal compounds were designed, and the target compounds were synthesized with satisfied yield via a four-step procedure starting from pyrrol and substituted benzaldehydes.

根据卟啉对肿瘤组织的选择性滞留作用，设计了3个卟啉替加氟化合物及3个金属络合物，并以吡咯和取代苯甲醛为原料经4步反应以满意的收率得到目标化合物。

Reactions of 2,6-pyridinedicarboxylic acid or 2,6-dibromomethyl pyridine with 5-(4-hydroxyphenyl)-10,15,20-triphenyl porphyrin, 5-(4-aminophenyl)-10,15,20 triphenyl porphyrin gave three novel bridged diporphyrins 3-5, respectively.

通过将2，6-吡啶二羧酸或2，6-二溴甲基吡啶分别与5-(4-羟基苯基)-10，15，20-三苯基卟啉(1)和5-(4-氨基苯基)-10，15，20-三苯基卟啉(2)反应，合成了3种新型的双卟啉化合物3~5。

Aggregation causes moderate downshifts(2～6 cm-1) for high-frequency modes involving the in-plane CC/CN stretches of the porphyrin core and a dramatic upshift (12 cm-1) for the out-of-plane saddling mode of the porphyrin ring.

聚集体的形成导致H8TPyP6+的卟啉环CC/CN面内伸缩振动向低波数方向位移2～6 cm-1，而卟啉环鞍形面外振动带向高波数方向位移12cm-1。

Secondly, a series of mono-tailed porphyrins——Zinc 5- 4-(ω-(1-adamantane amino) alkyloxy phenyl -10, 15, 20-triphenyl porphyrinate (ZnPCnA, n=4, 5, 6) and 5- 4-(ω-(1-adamantaneamino) alkyloxy phenyl -10, 15, 20-triphenyl porphyrin (H〓PC〓A, n=4) were synthesized, in which porphyrin subunit was connected with 1-adamantanamine by a flexible carbonic chain, in which the adamantyl group of adamantanamine, compared to other molecules, was a perfect guest to β-cyclodextrin and could be included into its cavity tightly in aqueous solution.

进一步的研究在NBCD和卟啉衍生物之间展开。

College of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072A novel diselenide porphyrins dimmers was synthesized using 5(4- hydroxylphenyl)-10,15,20- triphenyl porphyrin and selenium as raw materials. The structure of the novel porphyrin was confirmed by 1H NMR, IR, UV, and MS.

以5-(4-羟基苯基)-10，15，20-三苯基卟啉和硒粉为原料，合成了新型二硒双卟啉，用紫外可见光谱，红外光谱，核磁共振氢谱（1H NMR），高分辩质谱对目标产物的结构进行了确认。

The behaviors of supramolecular self-assembly of cabboxyl porphyrin-anthraquinone systems, carboxyl porphyrin zinc-copper systems, porphyrinatozinc-imidazolyl tailed porphyrinatomanganese systems, porphyrinatozinc-anthraquinone hybrids/imidazolyl tailed porphyrinatomanganese systems and porphyrinatozinc-fluorescein hybrids/imidazolyl tailed porphyrinatomanganese systems driven by hydrogen-bonding or coordination-bonding have been studied.

设计、合成了多种新型羧基卟啉、卟啉-蒽醌二元化合物和卟啉-荧光素二元化合物，研究了氢键或配位键驱动的羧基卟啉-蒽醌、羧基卟啉锌-羧基卟啉铜、锌卟啉-咪唑基尾式卟啉锰二元超分子，卟啉-蒽醌二元化合物与咪唑基尾式卟啉锰三元超分子的构建和光诱导电子转移性质。

But no electron transfer was found from the excited porphyrin moiety to the oxadiazole moiety. Moreover, cyclic voltammetric studies of the dyads 5a , 3b and 4b further indicated that electron transfer from the oxadiazole moiety to the porphyrin moiety was possible.

nm激发下不存在分子内卟啉基团向噁二唑基团的电子回传竞争；电化学性能测定进一步表明从噁二唑基团向卟啉基团的电子传递是可能的。

A new unsymmetrical metal porphyrin- 5-{4-[3-(2-nitro-phenoxyl) propoxy]phenyl }-10, 15, 20-tri-(4-methoxy phenyl )porphyrin copper (compound Ⅱ)was synthesized,and its UV-Vis spectra were measured and compared with other three symmetrical metalporphyrins.

本文合成了一个新的非对称卟啉铜化合物，测量了其紫外－可见光谱，并将此光谱结果与其他三种对称金属卟啉的光谱进行了比较。

In the negative and interrogative forms, of course, this is identical to the non-emphatic forms.

。但是，在否定句或疑问句里，这种带有"do"的方法表达的效果却没有什么强调的意思。

Go down on one's knees;kneel down

屈膝跪下。。。下跪祈祷