查询词典 polymerization

In chapter 2 and 3, the ring-opening polymerization of 2, 2-dimethyl-trimethylene carbonate and trimethylene carbonate catalyzed by IMPPL were explored.

生物可降解聚碳酸酯在手术缝合线，骨固定材料和药物控制释放等领域的研究和应用越来越受到重视。

In this dissertation, two series of rare earth initiators: rare earth tri (2, 6-di-tert-butyl4-methylphenolate) and rare earth calixarene complex have been developed to ring-opening polymerize 2, 2-dimethyltrimethylene carbonate, trimethylene carbonate and ε-caprolactone at mild conditions. Both the polymerization features and mechanisms are discussed in details.

本论文为环碳酸酯、内酯的开环聚合开发了两类新型低毒性稀土催化剂：三(2，6-二叔丁基-4-甲基苯氧基)稀土配合物和对叔丁基杯芳烃稀土配合物，都可以在温和的反应条件下单组分引发2，2-二甲基三亚甲基环碳酸酯、三亚甲基环碳酸酯和ε-己内酯聚合，合成各种分子量的均聚和共聚材料，考察了催化剂结构、聚合条件等对聚合的影响，深入研究了聚合机理。

Next, another novel diamine, 5-5-(4-phenyl-1,3,4-oxadiazol-2-ylbenzene-1,3-diamine, was prepared and polymerization was carried out in the same way to obtain polyimides containig triphenylamine units and 1,3,4-oxadiazole moieties in the side chain .

接下来，合成另一个新型双胺5-5-(4-phenyl-1，3，4-oxadiazol-2-ylbenzene-1，3-diamine后，以相同方法进聚缩合反应，可制得另一系列三苯胺和1，3，4-恶二唑为侧链的聚醯亚胺。

First, N'-(4-aminophenyl)-N'-4-(5-phenyl-1,3,4-oxadiazol-2-ylphenylbenzene-1,4-diamine was prepared and polymerization was carried out by direct polycondensation with a series of dianhydrides to obtain polyimides containig triphenylamine units in the main chain and 1,3,4-oxadiazole moieties as pendent group.

首先合成新型双胺N'-(4-aminophenyl)-N'-4-(5-phenyl-1，3，4-oxadiazol-2-ylphenylbenzene-1，4-diamine后，与一系的芳香族二酐进聚缩合反应，可制得一系列三苯胺为主链且1，3，4-恶二唑为侧链的聚醯亚胺。

Keywords: cyclic trithiocarbonate;RAFT polymerization; multiblock polymer; narrow molecular weight distribution.

中文关键词：环状三硫酯；RAFT聚合；多嵌段聚合物，窄分子量分布

Firstly, the homopolymerization of acrylamide was carried out in aqueous phase by reversible addition-fragmentation chain transfer radical polymerization using a trithiocarbonate as a chain transfer agent.

整个过程分为两步，首先在水溶液中，通过RAFT控制得到亲水性单体丙烯酰胺的均聚物；然后以得到的均聚物作为水溶性的大分子链转移剂，在水相中条件下参与亲油性单体苯乙烯无皂乳液聚合。

Dithioester and trithiocarbonate RAFT reagents were synthesizedby different methods, and were used for the polymerization of styrene ormethacrylates, by thermal, thermo-initiator and photo-initiation.

针对这一问题，本文尝试用三种方法合成了结构不同的RAFT试剂，考察了热引发、引发剂引发以及紫外光引发条件下，二硫酯／三硫酯调控的常见单体苯乙烯以及丙烯酸酯的RAFT聚合。

The main assembly unit partition is to mach tables of the bill of material, and unassembled partition is to search liaison between parts, compute assembly polymerization.Chapter 5 gives the general architecture of a prototype system for assembly unit partition based on knowledge under the CATIA environment to validate the ideas and methods proposed in this dissertation.

第四章提出了分主体装配单元划分和未组合件划分两步进行、中间穿插知识的解决装配单元划分的核心思想；以树模型为基础，通过实例知识的运用解决主体装配单元划分，以图模型为基础，通过构造关联图上的聚合度，运用模糊综合评判的方法实现了对未组合件的划分。

The synthesis of the unbridged metallocene (2, 4-Me〓Ind)〓ZrCl〓, which is not found in reference. Polymerization of ethylene or propylene with the metallocene has high activity. The resulted ethylene/1-hexene copolymer characteristic of uniform comonomer distribution. The catalyst possess commercial value

合成了未见文献报道的非桥联茂金属（2，4-Me〓Ind）〓ZrCl〓，用这种茂金属催化乙烯或丙烯聚合均达到了很高的催化效率，所得的乙烯/1-己烯共聚物表现出共单体分布高度无序的特点，具有工业应用前景

An expansion monomer 3, 9-dihydroxymethyl-di (6-methyl-5 -hydroxyl)-2- heptanone-1, 5, 7, 11tetraoxaspiro [5, 5] undecane was synthesized and its volume change during polymerization is about +3.04%. Its prepolymer was also synthesized by toluene 2, 4-diisocyanide with it.

由三经甲基丙烷合成了螺环原碳酸酯单体3'、9'－二羟甲基－3'，9'-二乙基－1，5，7，11－-四氧杂螺环[5、5]十一烷单体（体积膨胀率＋3.04%）以及它的预聚物，并用其来改性环氧树脂B-63。

It seems likely that Kraft will return with a better offer.

看起来卡夫要重新考虑一个更好的出价了。

But he'd rather burn off my feelers and watch me squirm.

可他却放任那个家伙对我为所欲为！