查询词典 polymerization

The technical advantage of NOY company is in civil yarn chip; that of Aquafil is in bulk carpet filament chip; that of Zimmer is in tyre cord yarn chip; while that of PE is in the capability of producing middle and high viscosity of PA-6 chips simultaneously, and in the world advanced chip for membrane; and that of Invent-Fischer is in the capability of producing both high quality PA-6 civil chip, and high viscosity of PA-6 chip through the solid condensation polymerization process in series.

NOY、Aquafil、Zimmer公司的技术优势分别在民用丝用PA-6切片、膨体地毯丝用PA-6切片以及轮胎帘子线用PA-6切片上；PE公司的技术优势主要是可同时生产中、高黏度PA-6切片，且在生产膜用PA-6切片上世界领先；Invent-Fischer公司技术优势在于既可生产高质量的民用丝级PA-6切片，又可通过串联固相后缩聚工序生产高黏度PA-6切片。

The key factors affecting the polymer intrinsic viscosity were found to be monomer recrystallization times,stannous octoate concentration and polymerization time.

单体重结晶次数、辛酸亚锡浓度、聚合时间等条件均是影响聚合物特性粘数的重要因素。

A novel biodegradable copolymer of poly and poly (γ-benzyl-L-glutamate) was successfully synthesized. Under appropriate conditions, the PBLG initiates the ring-opening polymerization of L-lactide to produce block copolymer, by using low toxicity stannous octoate as catalyst. The optimal reaction conditions were determined as follows; the catalytic agent: PBLG=1:1, the temperature is 120℃, the reaction time is 6h.

以L-丙交酯为原料，在催化剂辛酸锡酯Sn2的作用下，利用聚的活性端氨基引发LLA进行开环聚合，合成了聚L-丙交酯与聚的共聚物，对反应条件的各项因素进行了讨论，确定了最佳反应条件是：m：m=1：1；反应温度120℃；反应时间6h。

In 2000, Nishida et al synthesized the PPDO whose molecular weight could reach 142,000 but the monomer conversion could only reach 79.4% by using stannous octoate as catalyst with co-initiator under conditions that T = 100oC, M/I = 4900, t = 20 h, in 2000, the enzymatic polymerization of PDO was carried out at 100oC for 15 hours using 5wt% immobilized lipase CA by Nishida et al.

这主要是因为PDO的结构相对稳定，开环聚合要比GA、LA、CL困难一些，而且用于PDO开环聚合的催化剂体系单一，主要集中在Ti， Zr， Sn， Ld， La， Yb， Hg等重金属，然而这些重金属作为副产物，不容易从PPDO中分离出来，阻碍了PPDO作为医用材料的应用，这也造成了PPDO的成本昂贵。

The star shaped block copolymers were prepared by ring opening polymerization of ε caprolactone in the presence of multiarm PEG using stannous octoate as a catalyst.

以辛酸亚锡为催化剂，通过星型聚乙二醇引发ε己内酯开环聚合，制备了PEG b PCL嵌段共聚物，进一步以丙烯酸酯封端，合成了 3种水溶性大分子单体。

Due to the increasingly deep concerns about the cytotoxicity of stannous octoate, which is the most widely used catalyst for synthesizing polyesters derived from lactides (L-LA, D, L-LA, GA) via ring opening polymerization, a lot of new metal complexes of relatively low toxicity including Schiff base–Al complexes, Red-Al were developed and used to initiate the living, stereo-specific, and/or stereo-selective ROP of lactides.

由于合成聚乳酸类生物医用降解材料的最常用的催化剂辛酸亚锡 Sn2的细胞毒性问题已在世界范围内引起日益深切的关注，近年来国内外学者已研究开发出许多性能优异的低毒、非锡金属络合物催化剂（如：位阻西佛碱-Al 络合物， Red-Al 等）用于催化交酯类单体的活性、立构专一性及立构选择性聚合反应。

By use of titration analysis, the thesis investigated various factors such as isocyanate, PE molecular weight, reacting substance molecular ratio, reacting temperature and time etc. influencing upon prepolymerization step. It was found that 2, 4-tolulene diisocyanate and 4, 4'diphenylmethane diisocyanate is more rapidly reacted with PE600 than HDI. With PE molecular weight increasing, the reacting temperature or time should be raised or extended relevantly. Thus PE2000+2HDI pre-polymerization should be better carried out under some catalyst, for example, Triethylene diamine , Dibutyltin dilaurate and Tin octoate were used.

首先采用滴定分析方法对WRPU预聚反应的影响因素进行了研究：芳香族二异氰酸酯TDI、MDI比脂肪族二异氰酸酯HDI反应活性高，其中TDI在反应初始阶段的反应速率比MDI快，不过随着反应的进行，MDI比TDI反应速率加快，这主要是因为TDI分子中的两个-NCO反应活性差异大所致；二元醇分子量越大，反应速度越慢；聚醚二元醇比聚酯二元醇的反应速度快；当分子量超过2000的二元醇与HDI进行预聚反应时，需借助适当的催化剂来加快反应速度，从而使预聚反应能够顺利进行，分别选择DABCO、TOA和DBDTL三种催化剂进行催化反应，发现不同的催化剂，其催化效果相差较大。

The grafting of polycaprolcatone on starch by ring-opening polymerization of e -caprolactone was initiated from the starch hydroxyl functions in the presence of a catalyst such as stannous octoate Sn(0ct2, Dibutyltin dilaurate or titanium tetrabutoxide. The grafting ration could reach 16%. IR, X-ray diffraction and DSC were used to investigate the grafting-polymer.

在辛酸亚锡Sn(Oct_2、二月桂酸二丁基锡和钛酸丁酯等催化剂作用下，淀粉羟基引发己内酯单体进行配位聚合，淀粉接枝率可以达到16％，并通过红外光谱、X—ray衍射及DSC等测试手段对反应产物进行了表征。

The star-shaped block copolymers were prepared by ring-opening polymerization of ε-caprolactone in the presence of multiarm PEG using stannous octoate as a catalyst.Based on these star-shaped PEG- b -PCL,soluble macromers terminated with acrylate groups were synthesized.

以辛酸亚锡为催化剂，通过星型聚乙二醇引发ε-己内酯开环聚合，制备了PEG- b -PCL嵌段共聚物，进一步以丙烯酸酯封端，合成了3种水溶性大分子单体。

Usage: useful for pharmaceutical intermediate, especially useful for intermediate of synthesis aids inhibitor and metallocen catalyst for olefine polymerization.

用途：用作有机功能材料，医药合成中间体以及烯烃聚合用金属茂络合物催化剂配位体。。

The objective is to subjugate and discourage the people, because that allows the elite to continue to rule unopposed.

其目的是压制和打击人民的积极性，因为这可以让实权派继续统治不会沦为反对派。

GOD,this is the second time you vanquished me!

天啊，这是第二次你打败了我！