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All the compounds are characterized by IR and elemental analysis.we design and prepare a bipyridinium supramolecular compound and six coordination compounds, which are also characterized by IR, elemental analysis and X-ray structure analysis. According to X-ray structure analysis, hydrogen bonds and n-n stocking interactions participate in the architecture of three-dimensional framework [H2L1 (NO3)2 (H2O)2]n; one-dimensional zigzag coordination polymer [Hgl21.5CH3OH]n; binuclear metallamacrocycle (HgI2L2)2 3H2O; helical double-stranded one-dimensional coordination polymer [Co2(L2)2-2CH3OH]n; double-stranded one-dimensional coordination polymer [Co2(L3)2-CH3OH-CH3CN]n; and three-dimensional compound [Cu(C5H4NCOO)2(H2O)2]-H2O with hydrogen bonds, three-dimensional coordination polymer {[Cd(C5H6NCOO)2H2O]-DMF}n, which are indirectly obtained from the precursor ligand L3 through metal ion induced the hydrolysis of diamide and self-assembled with the hydrolyzate.

我们首次合成了一个双吡啶鎓超分子化合物和六个过渡金属配合物，并通过IR谱，元素分析和X-ray晶体衍射分析对它们进行了表征。X-ray晶体结构分析表明：超分子化合物[H_2L1·(NO_3)_2·(H_2O)_2]_n是由多种氢键和芳香环间的π-π堆积作用构建的三维无限结构；[HgI_2(L1)·1.5CH_3OH]_n是一维锯齿状配位聚合物；(HgI_2L2)_2·3H_2O是双核金属大环化合物；[Co_2(L2)_2·2CH_3OH]_n是具有一维双螺旋结构的配位聚合物；[Co_2(L3)_2·CH_3OH·CH_3CN]_n为一维双链结构的配位聚合物；以及由非直线形配体L3在金属离子Cu和Cd的诱导作用下发生水解，并且金属离子与水解产物——异烟酸根离子自组装，形成了三维氢键超分子化合物[Cu(C_5H_4NCOO)_2(H_2O)_2]·H_2O和三维配位聚合物{[Cd(C_5H_6NCOO)_2H_2O]·DMF}_n。

In this study, main chain of 4,4'-Biphenol combine different side chains to discuss polymer ~ polymer which synthesizes by the difference of structure of 1-Bromobutane、1-Bromoocatane、1-Bromododecane.To examinate luminance property and judge the correction for the structure of polymer ~ polymer by FT-IR、NMR-1H、UV、PL, in the meanwhile,to investigate into radiation wavelength under the condition of different side chains.

中文摘要 1。本实验是利用4，4'-Biphenol为起始物，与Allyl bromide反应，产生丙烯基芳基醚化合物，再利用克莱森重排反应将丙烯基转至邻位，然后在将OH基转变为不同链长的烷基醚合成出聚合物耤I），以FT-IR、NMR-1H、UV、PL测定其发光性质及判断产物结构是否正确，并探讨化合物在不同侧链之条件下，比较其放射波长。

In this experiment, 1 - hydroxy -2 - naphthoic acid was used as a template and the method of bulk polymerization was used to prepare molecular imprinting polymer molecularly imprinted polymer and blank polymer non-molecular imprinting polymer.

本文采用以1-羟基-2-萘甲酸为模板，本体聚合的方法制备了分子印迹聚合物MIP以及空白聚合物NIP。

The preliminary plan and actualized blue prints were presented,which was to construct an interact teaching,interpenetrative and flexible polymer science experiment course combined polymer chemistry,polymer physics and polymer process.Students learn from molecular design to synthesize polymer compounds and character properties of the materials,them process them to an utilized produce in this course.

设想将高分子化学、高分子物理和高分子成型加工三门实验课程有机地串联起来，组建成一门包括从高分子材料设计(用计算机软件进行分子设计、性能模拟)、聚合物合成、性能测试到加工成型，能环环相扣、互动式的、柔性化的高分子科学实验课程；提出了初步的实践方案。

According to the experiment results of degradation in field, degradation mechanism of the biodegradable mulch film can include four stages: the first, the material surface appeared deficiency while the surface area and interstice increased of material in the action of natural environment and microorganism; the second, along with the surface area and interstice of material increased and the gap strengthened, the chemical chain of the high polymer's principal chain broke as a result of the hydrolysis or the enzymatic effect in the action of hydration, causing the molecular weight and mechanics function descended; the third, the molecular of high polymer split the low polymer after its physical mechanical function descended, the material decomposed the fragments, the mass defect intensified; the fourth, the low polymer of fragments form in the natural environment, the microorganism, the biological enzyme became the smaller fragments, thus absorbed by the phagocytes, or further turn into CO2 and H2O due to hydrolysis.

根据田间降解试验结果推测，生物全降解地膜的降解机理可能包括四个阶段：第一，在自然环境、微生物作用下，材料表面出现缺陷，同时表面积增大、空隙增多；第二，随着材料表面积的增大、空隙的增多，吸水性增强，在自水合作用下，高聚物主链由于水解或酶解而使化学链断裂，导致分子量和力学性能下降；第三，在其物理机械性能下降后，高聚物分子链断裂为低聚物分子，材料裂解为碎片状，质量损失加剧；第四，碎片状低聚物在自然环境、微生物、生物酶作用下进一步水解变成尺寸更小的碎片，从而被吞噬细胞吸收，或进一步水解，生成CO2和H2O。

However, the thermal stability of metallic coordination polymer hardly enhanced in comparison with the polymer never coordinated transitional metallic ions. The reason might be that the energy of coordinate bond formed between metallic ion and polymer was trival in comparison with that of covalent bond in polymer. It started with coordinate bond when the coordinate polymer decomposed under high temperature, so it engendered little for the thermal stability at high temperature.

而金属配聚物较未配位金属的配体高温热稳定性提高不大，可能是由于金属离子与配体之间形成配位键的键能与配位体内的共价键键能相比要小得多，当金属配聚物受热裂解时，首先从配位键开始，因此对高温热稳定性的影响甚微。

An experiment is conducted to understand the effect of high molecular polymer fluid on the flow measurement using rotameter. In the experiment, the rotameters, which are composed of different floating elements with different shapes and materials in measuring tubes, are employed to measure the high molecular polymer fluid with viscosity from 1 MPa·s to 2 692 MPa·s. Through analyzing the impact of high molecular polymer fluid on the different rotameters, a general rule is obtained for measuring high polymer fluid using rotameter.

为了了解高分子聚合物黏性溶液对浮子流量计流量测量的影响，采用由不同材料与不同形状浮子构成的浮子流量计分别对动力黏度从1 MPa·s到2 692 MPa·s范围的高分子聚合物溶液进行流量测量，根据对不同浮子流量计受黏性影响实验的分析，获得了高分子聚合物黏性溶液对浮子流量计测量影响的规律。

The produced water which was made by crude oil dehydration containing polymer, alkaline and surfactant, brought many technique problems in the water treatment process system, this made the polymer flooding and water flooding water treatment technologies difficult to suit to the disposal requirement of the special water. The developed experiment research indicated that: because of the surfactant, the semidiameter of the oil droplets in the ASP flooding is much smaller than that in polymer flooding, and the stability of the oil droplets is higher than that in polymer flooding, The viscosity and combine difficulty of the oil droplets increased, and all the changes of speciality resulted in the increased difficulty in the ASP flooding produced water disposal.

三元复合驱采出液经脱水后得到的采出水中，因含有聚合物、碱和表面活性剂，给采出水处理工艺系统带来了一系列的技术问题，使已经应用于水驱和聚合物驱采出水处理的技术难以适应这种特性的采出水的处理要求，已经开展的实验研究表明：三元复合驱采出水中由于表面活性剂的存在，使采出水中油珠的粒径远远小于聚合物驱采出水，油珠的稳定性明显大于聚合物驱采出水；由于聚合物的存在，采出水粘度增大，使油珠聚并难度增大，这些特性的变化造成三元复合驱含油污水的处理难度大于聚合物驱。

The growth inhibiting rate of T24 cell lines were detected by MTT methods, apoptosis of cells were detected by flow cytometry, the mechanism of apoptosis was analyzed by detecting the protein expression of Bcl-2, Bax, Caspase-9, Caspase-3 and cytoplastic protein Cytochrome C. 4 We injected live T24 cells into the subcutaneous space of nude mice and successfully built up the animal model of bladder carcinoma. The effect of CS-PAA-EPI polymer magnetic microspheres targeting chemotherapy was investigated by HE staining, TUNEL ,tumor weight and volume inhibition rate. Results: 1 TEM revealed that the CS-PAA polymer magnetic microspheres were regular spherical shape,the average diameter was 80nm in dry condition. By controlling the pH value of the medium,polymers had positive or negative zeta potential. VSM showed the CS-PAA polymer magnetic microspheres had superparamagnetic. The diameter of CS-PAA-EPI polymer magnetic microspheres were 200nm in solution by DLS examining,the embedding ratio was 20%,the EPI loading rate was 15%, which was higer than reported in other articles. 2 Raw eye observation found that the rat"s bladder of treatment group was brown color,which meaned the aggregation of iron particles, compared with the control group, iron stain found iron particles were assembled in rat"s bladder of the treatment group, the amount of iron particles in liver and spleen were less obviously.

研究结果：1合成的CS-PAA磁性聚合物微球呈球形，大小均一，TEM测定其干态下粒径为80nm左右，磁化曲线证实具有超顺磁性，具有一定的PH敏感性，固载表柔比星后，水溶液性状稳定，无沉淀物，DLS测定直径约200nm左右，测定载药率为15％，较文献报道高，包封率为20％。2肉眼观察试验组大鼠膀胱表面呈褐色，可见大量的Fe粒子聚集，普鲁士兰染色法显示，试验组大鼠膀胱壁内有大量的Fe粒子，分布至膀胱壁全层，与对照组大鼠相比，试验组大鼠的肝、脾内的Fe粒子聚集量明显降低；HPLC测定结果与Fe染色相同；高剂量磁性CS-PAA-EPI生理盐水组及单纯EPI生理盐水组均在给药后14天出现血肌酐和尿素氮的升高，其他组大鼠血生化指标没有明显变化。3MTT法发现，高、中、低剂量磁性CS-PAA-EPI生理盐水组在外加磁场的协同作用下杀伤T24细胞效应明显高于单纯的EPI生理盐水组，FCM发现试验药物组可引起明显的肿瘤细胞凋亡，试验药物治疗组细胞胞浆内出现了由线粒体释放出的细胞色素C，试验组细胞Bcl-2蛋白减少，Bax蛋白变化不明显，Caspase-3、Caspase-9蛋白受到了激活活化。4高、中、低剂量磁性CS-PAA-EPI生理盐水组的瘤重抑制率和瘤体积抑制率均明显高于单纯的EPI生理盐水组(P＜0.01)，其中高剂量组的抑制率最高。

A kind of polymer degrading microbe JHW-31 was selected from Daqing Oilfield. The microbe was inoculated and cultured in the culture medium confected with polymer and a little sucrose for 7 days under the condition of pH 7.2 and temperature 45℃. The viscosity reduction rate of the polymer reached 92.1%,and the molecular weight of the polymer decreased from 18×106 to 0.5×106. The gross of the polymer decreased a little bit.

摘要从大庆油田筛选到聚合物降解菌种JHW-31，将菌种置于45℃、pH值为7.2的环境条件下，在添加少量蔗糖的聚合物培养基中培养7d，聚合物黏度可降低92.1%，并使其分子量从18×106降至0.5×106，聚合物总量也有所减少。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。