查询词典 pinacol

An environmentally benign method to accelerate the pinacol rearrangement in high temperature liquid water by the addition of CO2 was proposed.

提出了一种通过引入CO2来提高高温液态水中频那醇重排反应速度的方法，测定了不同CO2初始压力和温度等对频那醇重排反应动力学的影响。

In aprotic solvents magnesium effects pinacol reductive coupling of aldehydes and ketones.

在非质子性溶剂，镁对频纳醇与醛和酮的还原耦合反应也有一定效果。

That is one of the best results in asymmetric catalyzed pinacol coupling reaction, which indicates that the tetradentate chiral Schiff-bases with C〓 symmetry and rigid structure may be developed into practical applications.

这说明，具有C〓对称性且其核心结构具有刚性的四齿Schiff--Base是最有希望获得有实用价值的新的手性化合物。

The pinacol coupling of carbonyl compounds affording pinacols is an important method for the formation of 1, 2-diols and one of the most powerful methods for constructing carbon-carbon bond.

醛酮的片呐醇偶联是合成片呐醇的经典而有效的方法之一，也是形成C-C键的有效途径，一般通过醛酮与金属试剂或金属络合物作用来实现。

The conventional pinacol coupling of carbonyl compounds was carried out by using metals or metal compounds as mediators under condition of anhydrous organic solvents.

传统的呐偶合反应必须在无水有机溶剂条件下，由金属或金属化合物促进羰基化合物进行呐偶合反应。

Previously, it was reported that the pinacol coupling of carbonyl compounds was achieved by zinc under strong base or weak acid condition.

曾经报道过金属锌在强碱介质或弱酸介质中，促进羰基化合物进行水相呐偶合反应。

5 The pinacol coupling reaction of aromatic aldehydes and ketones was performed in 8-95% yield with magnesium in 0. 1M aqueous NH4CI.

2.4 以蒙脱土K10和锌的体系中，在超声波作用下，研究了醛、酮的还原偶联反应，于22～30℃反应2～3小时，产率23～91％。

A reduction-coupling-etherification reaction between aromatic aldehydes or ketones (1) and alcohols ( 2 ) to yield corresponding diether ( 3 ) of pinacol in the presence of tin and chlorotrimethylsilane.

在三甲基氯硅烷、四氢呋喃体系中，芳香醛、酮和醇在金属锡的作用下发生还原-偶联-醚化反应生成相应的频那醇二醚类化合物。

Emphasis analyzed,researched and estimated pinacol rearrangement actions,catalysts,reaction machine,related some reaction formulae etc,and characteristic,regulation relative with migration groups and more uses.

重点分析、研究和评述了频呐醇重排的作用、所用的催化剂、反应机理、相关的一些反应式、与迁移基团相关的重排特征和规律以及其较多的应用等，也论及了反频呐醇重排反应恰好是频呐醇重排的逆过程。

The aluminium powder has been used to reduce titanium tetrachloride to generate the low valent titanium reagent which can induce the reductive coupling of aldehydes and ketones to form the corresponding pinacol s.

以价廉易得的铝粉还原四氯化钛制得低价钛，将其用于醛酮还原偶联，合成了6种片呐醇，其中对称片呐醇4种，不对称片呐醇2种。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。