查询词典 photoionization

The photoionization dynamics of ammonia and benzene was studied by home-built femtosecond laser and TOF mass/photoelectron spectrometer.

报导了用自制飞秒激光器通过飞秒多光子电离质谱和光电子能谱对飞秒强激光场与分子相互作用的研究。

Using acetone as a photosensitizer,and N3· as an oxidant by pulse radiolysis method,the induced oxidation of cyclic-Phe-His in aqueous solution has been also reported in this paper,results similar to the photoionization of cyclic-Phe-His have been found.

而具有亲电子性的丙酮能在该环肽的苯丙氨酸残基的苯环上抽取电子，形成320nm和410nm的特征吸收峰，求出了自由基的有关动力学参数，并用脉冲辐解动态吸收光谱法印证了上述结果。

In addition, the detailed introduction is given on the endstation of atomic and molecular physics. The formative mechanism of molecular beam is discussed. The theory of time of flight mass spectrometry and multi-photoionization chamber are also discussed in this chapter. Last, the method of data acquisition is described.

另外，对原子分子物理实验站作了具体介绍，讨论了分子束的形成机理、飞行时间质谱仪的设计原理及多级光电离室的原理和结构，给出了该实验站仪器配备情况，并简要介绍了该实验站配套的数据采集方法。

In chapter 2 and 3, experimentally, using the Angular-Resolved high-resolution fast Electron Energy Loss Spectrometer , at the condition of 2. 5 keV incident energy and 50-60 meV energy resolution, we measured the Optical Oscillator Strength Density Spectra for the excitations of 4p, 4s or 3d electron. The oscillator strengths for excitations of the valent shell 4p electron were obtained, and comparisons were done between presently experimental and previously experimental and theoretical results. The experimental results of different groups agree with each other approximately, but the semi-experientially theoretical results do not match with the experimental results. The delayed maximum in the photoabsorption spectra was discussed. It should arise from the transition of 4p→∈d. For the excitation of the inner-valent 4s electron, the discrepancies for the resonant structures in previous electron-impact results and photoionization results were clarified in present work, which confirms again that the fast electron impact method is suitable to measure the optical oscillator strengths. The autoionization Rydberg series 4s〓ns (n=5, 6, 7) and 4s〓nd (n=4, 5, 6, 7) were identified without ambiguity by the measurement at 0°, 2° and 4°scattering angles. The energy levels and natural widths of the excitations of Kr3d and Ar2p inner shell, including optically allowed and forbidden transitions, were determined. The widths of these inner shell excitations are nearly the same, which was interpreted by the Resonant Auger effect .

在第二章和第三章，实验上，使用角分辨的高能量分辨快电子能量损失谱仪，在2.5keV电子入射能量和50-60meV能量分辨下，测量了Kr原子由价壳层4p到内价壳层4s，再到内壳层3d电子激发的光学振子强度密度谱；得到了价壳层4p电子激发束缚态的光学振子强度，与前人实验和半经验理论结果作了细致的比较，说明几家实验是比较符合的，但半经验的理论计算存在问题；分析了光吸收谱中的延迟极大现象，说明在第一电离阈值以上几个eV范围内的极大值源于4p→εd跃迁产生的延迟极大；对于内价壳层4s激发的自电离区，澄清了前人实验中电子碰撞方法和光学方法在共振结构上存在差异的问题，再一次肯定了快电子碰撞方法是获得绝对光学振子强度的一种好方法；通过在非0°散射角的测量（如2°和4°），清楚地标识了4s电子激发的光学禁戒跃迁自电离里德堡系列4s〓ns（n=5，6，7）和4s〓nd（n=4，5，6，7）；通过在0°和4°散射角的测量，观测并标识了几个新的内壳层光学禁戒跃迁能级，得到了Kr原子3d和Ar原子2p内壳层激发态（包括光学允许和禁戒跃迁形成的）的能级位置和自然宽度，用共振俄歇效应解释了这些内壳层激发态（不管是光学允许还是禁戒跃迁产生的）的自然宽度彼此比较接近的原因。

Our results reproduce all the structures near the higher energy edge shown in the experiment. The structures are attributed to the autoionization resonances from the detailed treatment of the photoionization process.

与实验结果的较好符合是由于对光电离过程的处理更精细的结果，在我们对光电离的处理中，比较完整地考虑自电离共振，这些共振对应较高能量处的光谱结构。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。