查询词典 phosphine

The results ofthe addition of lithium phosphine showed the operation of a double stereo-differentiation effect and the chirality of the sulfinyl group dominated the asymmetricinduction.

在亚磷酸锂盐的加成反应中，这两个手性基团起双重诱导作用，其中亚磺酰基的手性中心起主导作用。

In this dissertation, preparation of polysubstituted ethene and heterocyclic compounds based on 2-hydroxyalkyl phenyl selenides andα-phenylselenopropionic acid reagents were further investigated as follow: Firstly, O-ethyl-O-vinyl phosphonates were prepared in a one-pot, two-step transformation by Mitsunobu reaction of 2-hydroxyalkyl phenyl selenides with monoethyl esters of phosphonic acid in the presence of diethyl azodicarboxylate and triphenyl phosphine (PPh3) followed by oxidation-eliminatio...

中文摘要：本文主要进一步探索了2-羟基烷基苯基硒醚、α-苯硒基丙酸试剂在制备多取代乙烯和杂环化合物反应中的应用，具体研究内容和结果如下：一、在偶氮二羧酸乙酯和三苯膦(PPh3)存在下，苯基-2-羟基烷基硒醚和O-乙基膦酸单酯发生Mitsunobu反应，无需分离和纯化反应中间体，直接使用30 %的双氧水进行氧化-消除反应，提供了&两步、一锅&合成O-乙基-O-乙烯基膦酸酯的新方法，该方法反应条件温和，操作简便，产物收率良好(76-82 %)。

In the second part, we used tri-octyl phosphine oxide as a model of TRPO,to study the γ radiolytic behavior of TOPO and its CH solution and the emulsificationphenomenon in the separation processes of radiolytic products. The structures of finalproducts were analyzed with IR spectra, UV spectra, MS and elemental analysis.

本论文的第二部分，以TOPO为TRPO的模式化合物，用终产物分析的方法对TOPO的辐解特性及乳化过程进行了研究，并运用红外光谱、紫外光谱以及元素分析、质谱等方法对乳化物的结构进行了分析。

A series of sulfonated poly(arylene thioether phosphine oxide)s with various degrees of sulfonation was prepared by polycondensation of 4,4'-thiobisbenzenethiol with the mixture of sBFPPO and BFPPO at different ratios. The effect of IEC on the properties of the products was studied.

以BFPPO、sBFPPO和4，4'-二巯基二苯硫醚为单体，通过改变BFPPO/sBFPPO的配比，合成了一系列不同磺化度的磺化聚芳硫醚三苯基氧膦，考察了IEC对产物性能的影响。

The cure kinetics of naphthyl/dicyclopentadiene epoxy resin and bis-phenoxy (3-hydroxy) phosphine oxide was investigated by differential scanning calorimetry under nonisothermal and isothermal condition.

用差示扫描量热仪研究了含萘环和二环戊二烯环结构环氧树脂NDEP和BHPPO的等温和非等温固化动力学。

A series of sulfonated poly(phthalazinone ether phosphine oxide)s were prepared via polycondensation of 4-(4-hydroxyphenyl) phthalazinone with sBFPPO and BFPPO.

通过将4-(4-羟基苯基)-2，3-二氮杂萘酮与二(4-氟苯)苯基氧膦和磺化二(4-氟苯)苯基氧膦单体共聚，制备了一系列磺化聚二氮杂萘酮醚三苯基氧膦。

Hese results indicated that phosphorus flame-retarded P1-UPR by condensation mechanism.(3) Bis-phenoxy (3-hydroxy) phenyl phosphine oxide was synthesized by phenyl phosphonic dichloride and resorcinol, and bisphenylphosphonate was synthesized by phenyl phosphonic dichloride and ethylene glycol.

G-FTIR对热分解气体的分析未发现含磷基团的特征吸收峰，SEM对不同DMMP用量的P1-UPR燃烧后的残留炭进行分析，结果表明随含磷量的增加，残留炭层趋向完整致密。

The cross-coupling reaction of DOPO with halogenated phenols were achieved for the first time, novel phenolic hydroxyl-containing reactive-type DOPO-based flame retardants used in epoxy resins were synthesized; the cross-coupling reactions of 2\'-hydroxybiphenyl-2-ylphosphinic acid or diphenyl phosphine oxide with halogenated phenols were studied according to the above result, new reactive-type flame retardants used in epoxy resins were synthesized.

采用Pd催化的方法首次实现了DOPO与卤代酚的交叉偶联，合成了新型含酚羟基的反应型DOPO基环氧树脂阻燃剂；在此基础上实现了2-(2-羟基苯基)苯基次磷酸和二苯基氧化膦与卤代酚的偶联，合成了新型反应型有机磷环氧树脂阻燃剂。

The structure of sulfonated polys from DB is similar to that of sulfonated poly(arylene thioether phosphine oxide)s from TB. The latter could be regarded as the"product"of the former provided that the ether unit of the former was replaced by the thioether unit. The studies illustrated that the latter exhibited much better oxidative stability than the former. This is due to the fact that the thioether unit of the former was oxidized into the sulfone or sulfoxide unit in Fenton reagent, which inactivated the adjacent benzene rings and thus retarded the degradation reaction.

从结构上看，后者可以看成是前者的醚基团被硫醚基团取代后的&产物&，其耐氧化性能比前者好得多，这是因为后者的硫醚基团在Fenton试剂中被氧化成为砜或亚砜基团，而砜或亚砜基是钝化基团，钝化了与之相连的苯环，阻碍了降解反应。

On the contrary, sulfonated poly(arylene thioether phosphine oxide)s, with a IEC of 1.60 meq/g, even denote a swelling of 70.1% at 80oC and thus lose most of the mechanical strength.

而前述IEC为1.60 meq/g的磺化聚芳硫醚三苯基氧膦在80oC下的溶胀率为70.1%，已经出现溶胀突变，显著丧失力学强度，其耐溶胀性能比磺化聚二氮杂萘酮醚三苯基氧膦差得多。

The concept of equivalent rotationally rigidity is offered and the formula of rotationally rigidity is obtained.

主要做了如下几个方面的工作：对伸臂位于顶部的单层框架—筒体模型进行分析，提出了等效转动约束的概念和转动约束刚度的表达式。

Male cats normally do not need aftercare with the exception of the night after the anesthetic.

男猫通常不需要善后除了晚上的麻醉。