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And the linear relationship between creaturely activity of halogenated phenols and the molecular topological index is obtained.

研究了卤代苯酚对结核菌抑制活性,抗菌活性,呆鲦鱼毒性,水生生物毒性,诱发浮萍萎黄病活性,细胞色素P-450转化活性等六项生物活性分别同卤代苯酚分子连接性指数的相关性。

Starain LHG1 could not only utilize the intermediate products of cycloalkanes-clohexanone and cyclopentanone, but also could degrade alkane, aromatic hydrocarbon and phenols, such as liquid paraffin,solid paraffin, naphthalene and phenol.

LHG1菌株能够利用环烷烃代谢的中间产物环己酮和环戊酮。此外,LHG1菌株还能降解液体石蜡、固体石蜡、萘和苯酚等链烃、芳香烃和酚类。

The composition comprises: 35 to 65 wt % of an anionic detergent or surfactant selected from alkyl benzene sulphonic acids, alpha olefine sulfonates, long chain fatty acid sulphates, higher fatty acids, as well as the alkali metal and alkaline earth metal salts thereof, and natural detersive agents, and mixtures of any of these; 3 to 15 wt % of a non-ionic detergent or surfactant selected from alkoxylated alkyl phenols and alkoxylated fatty alcohols; 5 to 10 wt % of a water-swellable cellulose derivative or a salt thereof, wherein the cellulose derivative exhibits a viscosity of at least about 1500 cps, measured in a 1 % aqueous solution at 25 DEG C with a Brookfield viscometer having spindle 3, speed 30rpm, factor 40 for viscosities of 2500-3500 cps; 6 to 20 wt % of a solubility regulator selected from alkali metal and alkaline earth metal chlorides, carbonates and sulphates, aluminosilicates and starch; and 0 to 20 wt % of a fragrance or perfume in solid, liquid or microencapsulated form.

该组合物包含:a35―65%重量的阴离子洗涤剂,其选自烷基苯磺酸、α-链烯烃磺酸盐、长链脂肪酸硫酸盐、高级脂肪酸以及其碱金属和碱土金属盐和天然的去污剂,和任何这些组分的混合物;b)3―15%重量的非离子洗涤剂,选自烷氧基化烷基酚和烷氧基化脂肪醇;c)5~10%重量的水可溶涨的纤维素衍生物或它们的盐,其中纤维素衍生物按1%水溶液在25℃下用Brookfield粘度计(3号转轴,转速30rpm,2500―3500cps粘度的因子是40测定;具有粘度至少约1500cps;d)6―20%重量的溶解性调节剂,选自碱金属和碱土金属氯化物、碳酸盐和硫酸盐、硅铝酸盐和淀粉;和e)0~20%重量的为固体、液体或微囊包封形式的香精。

It was found that the more easily systhesized and stable N, N-acetal or N, Ohemiacetal can replace N-tosyl imino ester to react with phenols in the presence of TiCl〓, and α-arylglycine derivatives were also obtained in high yields and high regioselectivity.

进一步研究发现,更易合成的N,N-或N,O-缩醛可以作为亚胺酯的替代物和酚类化合物发生傅克反应。路易酸TiCl〓能有效地促进酚类化合物和亚胺酯的傅克反应较高产率、较高区域选择性的得到2-羟基α-芳香甘氨酸衍生物。

A type of novel dis-substituted α-arylglycine derivatives was synthesized in high yields and high regioselectivity via the stepwise Friedel-Crafts reaction of phenols with N-tosyl imino ester promoted by TiCl〓.

发现在Mg/MeOH/超声波条件下,能高产率的得到N-Tos裂解后N-Boc保护的α-芳香甘氨酸衍生物,实现了一条简单、实用的合成N-Boc保护的α-芳香甘氨酸衍生物的方法。

The results of the present research are as follows, The correlation between physico-chemical properties of organic compounds and their competitive power was studied, and it was indicated that organic compounds preferable to form H-bonding with organic matter of sorbents have stronger competitive power; Sorption behaviors of ionizable organic compounds in different species and their competitive power were examined, and the results showed that phenols and carbonxylic acids with benzyl circle have much stronger competitive power in molecular species than in ionized species, because negative charges of anionic forms can depressed their adsorption on the surface of the sediment; in contrast, organic bases such as aniline and p-chloroaniline show weaker competitive power in molecular species than in ionized species, and this is because both species of the organic bases could adsorb strongly onto the sediment; there is a correlation between competitive power of organic pollutants in multi-solute systems and their sorption isotherm nonlinearity in single-solute systems, and organic compounds whose sorption isotherms is linear in single-solute systems hardly have competitive power in multi-solute systems; Competitive sorption effects in more than two-solutes systems was studied, and it was exhibited that mixture of two cosolutes each of which could suppress sorption of nominal solute onto the sediment had synergistically competitive sorption effect on the nominal solute; A method about incorporating sorption/desorption of organic pollutants into river water quality model was developed, and discussion about degree of sorption/desorption effect on model prediction for different organic compounds was made, which will provide theoretical basis and practical processes for setting up more accurate water quality model.

论文主要取得了以下研究成果。(1)有机化合物的吸附竞争能力与其物化性质具有相关性,易与沉积物有机质形成氢键的化合物其竞争能力也比较强;(2)可离子化有机化合物的吸附竞争能力与其存在形态有关。酚类、含苯环的羧酸类化合物,其离子态的吸附竞争能力远小于分子态,其机理为有机酸阴离子所带的负电荷抑制了表面吸附能力,主要发生分配作用;而苯胺类化合物,其离子态和分子态都表现出显著的竞争能力,而且离子态的竞争能力略强于分子态,原因在于有机碱阳离子所带的正电荷促进了其表面吸附能力;有机化合物竞争能力的强弱与其单组分吸附等温线的非线性程度具有一定的相关性,吸附等温线近似为线性的化合物没有或只具有微弱的竞争能力;(3)对目标有机化合物的吸附具有竞争效应的有机化合物混合后,将对目标有机化合物的吸附产生协同竞争效应;(4)以京杭运河为例,率先提出了将有机污染物的吸附/脱附作用及水文水力参数耦合到水质模型中的方法,并讨论了吸附/脱附作用对不同有机污染物预测模型的影响,为建立更准确的水质模型及进行更客观的风险和生态评估提供了参考依据。

With it, simple, mechanistically significant and highly predictive QSAR models were developed. These QSARs successfully model and predict the short-term phytotoxicity of substituted phenols involved both polar narcosis and bio-reactivity, the growth inhibition toxicity to Saccharomyces cerevisiae of substituted nitrobenzenes with mixed mechanisms of toxic action based on electrophilicity and the growth inhibition toxicity to Saccharomyces cerevisiae of large set of substituted benzenes with complex molecular structures and multiple mechanisms of action.

应用响应曲面分析方法建立了形式简单、意义明确并且具有高度预测性的QSAR模型,成功地预测了具有多种毒性机制的取代苯酚对高等植物的短期生长抑制毒性、具有多种亲电反应性机制的取代硝基苯对酿酒酵母菌生长抑制的反应性毒性以及结构复杂、机制多样的78种取代苯衍生物对酿酒酵母菌生长抑制毒性。

Objective To explore the optimal techniques in separation of phenols from Melastoma dodecandrum with macroporous resins.

目的 筛选大孔树脂分离纯化地菍中总酚类物质的最佳工艺。

AM1 method was employed to calculate ΔHOF values of methoxyl phenols, and the values were used as theoretical parameters to investigate the stabilizing effect of p-type lone pair electrons of methoxyl oxygen on the phenoxyl free radicals.

用AM1方法计算了几种甲氧基苯酚的ΔHOF值,以此为理论指标探讨了甲氧基氧的p型孤对电子对苯氧自由基的稳定作用。

First of all, a monophase microemulsion was prepared with Triton X-100 as surfactant, and the nitration of phenols by concentrated nitric acid in the systems was studied. The influence of the mass fraction of nitric acid, oil/water volume ratio, reaction temperature and other factors on the reaction conversion and selectivity was examined.

首先在非离子表面活性剂Triton X-100形成的单相微乳体系中,用浓硝酸对苯酚进行选择性硝化反应,研究了硝酸的质量分数、微乳中油/水比、反应温度等因素对反应转化率及硝化选择性的影响。

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