查询词典 ozonide

The yield of dimethl 1, 15-pentadecanedioate was 80.5% when the ozonide of malania olceifera chum oil reacted with hydrogen peroxide at 55℃ for 2 hours.

在55℃下用H2O2作为氧化剂，裂解反应2h，1，15-十五二酸二甲酯的得率达到80.51%。

Due to the hindered nature of the vinyl group in- 27 3 days were required to reduce the ozonide; fortunately, the reaction progress can be monitored easily by TLC.

同酯-27手，下一组黑胶转为经醛啉臭氧、用人的臭氧减少与甲基或产后大出血3、治疗后，在指定四氢呋喃对异构；醛类-29年联合摄制产量65%的两步。

According to the analysis of density of state and charges density, we found that ozone molecular was chemically adsorbed on the bridge site of S1 as ozonide, and ozone molecule decomposed into one adsorbed surface oxygen atom and one free oxygen molecule.

态密度和电荷密度分析结果进一步证实了O3分子在S1上吸附是桥位化学吸附，形成表面臭氧化物，在S2上吸附分解为1个被吸附的表面氧原子和1个自由氧分子。

With ester- 27 in hand, the vinyl group was next converted to the aldehyde moiety via ozonolysis, employing reduction of the ozonide with dimethylsulfide or PPh 3 , followed by treatment with DBU in THF to effect epimerization; aldehyde- 29 was produced in a combined yield of 65% for the two steps.

同酯-27手，下一组黑胶转为经醛啉臭氧、用人的臭氧减少与甲基或产后大出血3、治疗后，在指定四氢呋喃对异构；醛类-29年联合摄制产量65%的两步。

The oxidation of C=C double bond in 4-isopropylideneC〓-trishomocubane-8, 11-dione was studied. Ozonolysis of that double bond was arrived and the ozonide was found much more stable than ordinary ozonides.

详细研究了4—异亚丙基—C〓—三高立方烷—8，11—二酮中碳—碳双键的氧化反应，实现了双键的臭氧化分解，并发现其臭氧化物具有不寻常的稳定性。

Whenpyridine was used as reductive decomposing agent, the expecting cholest-4-en-3,6-dione-22-al was obtained. However, when Zn/HOAc was used to decomposethe ozonide, C-4,5 double bond was further reduced to give cholest-3,6-dione-22-al as main product. 2 For the side-chain construction of compound (1), the solid-liquid phase-transfer Wittig reaction was used. When (3-methyl-2-oxobutyl)-triphenylarsonium bromide was used as reagent, the reaction can be carried out inmild reaction condition and the yield is higher than that when phosphorane wasused.

但使用Zn／HOAc作为分解剂时，却得到其氢化产物胆甾-3， 6-二酮-22-醛；2在甾体支链引入过程中，采用固-液相转移Wittig反应的方法，用(3-甲基)-2-氧丁基三苯基溴化胂作为试剂，反应在非常温和的条件下便可完成，而且产率比传统采用膦烷的方法更高；3在对某些甾酮化合物的选择性还原反应研究时，发现在〓还原体系中，当加入某些金属离子后，反应有更好的区域选择性和立体选择性。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。