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For example, H, atomic weight of 100,794 hydrogen, carbon FC atomic weight of 1201, the atomic weight of oxygen O for 1594, Copper Cu for F63546 and so on. F history, had also used the other two kinds of "benchmarks", and there have been two kinds of scales used in parallel .1803 years, J Dalton published the first atomic table, the hydrogen-quality of the original F son as a "benchmark "requiring H, atomic weight is 1. In 1826, JJ Berzelius Tony F are presented to the quality of 116 oxygen atoms O as a" baseline "(scheduled for O, E atomic weight 16), which is has been in use to 1961 "Oxygen unit." 1929, found that the oxygen in nature, in addition to the greatest abundance of 16O, there are a small amount of slightly heavier 17O and 18O two kinds of isotopes, and the different sources of oxygen, its composition is slightly different.

例如氢H的原子量为100794,碳FC的原子量为1201,氧O的原子量为1594,铜Cu为F63546等。F历史上,还曾用过另外两种"基准",并且有过两种标度并行使用。1803年,J道尔顿发表的第一张原子量表,把氢原F子的质量作为"基准",规定H的原子量为1.1826年,JJ贝F采利乌斯提出,以氧原子O质量的116作为"基准"(定O的E原子量为16),这就是一直沿用到1961年的"氧单位"。1929年发现,自然界中的氧,除丰度最大的16O以外,还有少量稍重的17O和18O两种同位素,并且不同来源的氧,其组成也稍有不同。

Major content of this work includes five aspects as follows:(1). Oxygen sensitive materials had been prepared by carrier covalence method, and the preparation mechanism of the materials had been investigated by FI-IR, SEM, and the detection experiment of oxygen. Then through the detection of oxygen, the sensitivity and stability had been estimated, and it was studied that the properties of materials would be affected by the various factors.(2). Oxygen sensitive materials had been prepared by carrier covalence-cross linking method, and the preparation mechanism of the materials had been investigated by FI-IR, SEM, and the detection experiment of oxygen. Then through the detection of oxygen and spectrophotometer, the sensitivity and stability had been estimated, and it was studied that the properties of materials would be affected by the various factors.(3). For the detection of gaseous oxygen, the fiber optical sensor on basis of oxygen sensitive materials had a respond time of 10s, detection limit of 5ppmand detection precision of 0.5%. The sensor had good repeatability and stability, a less delay and at least 1 year life-span.

本论文主要包括以下五个方面的内容:(1)载体共价法制备氧敏感材料:通过红外光谱、扫描电镜图谱和氧测试实验探讨该氧敏感材料的制备机理,通过氧测试实验评价该氧敏感材料的氧敏感性和稳定性,同时研究了各种因素对该氧敏感材料性能的影响(2)载体共价—交联法制备氧敏感材料:通过红外光谱、扫描电镜图谱和氧测试实验探讨该氧敏感材料的制备机理,通过氧测试实验和分光光度计评价该氧敏感材料的氧敏感性和稳定性,同时研究了各种因素对该氧敏感材料性能的影响(3)氧敏感材料在光纤气态氧传感器中的应用:该传感器的响应时间为10s,检测下限为5ppm,检测精度为0.5%,具有较好的重复性和稳定性,迟滞较小,使用寿命至少为1年,适合各种环境下气态氧浓度的检测。

The Activated Ploy-oxygen Aerator adopts magnetic engineering technology to send the oxygen of air which is gathered and activated by polyoxier to the mixing chamber of main engine under water, and the process of water and oxygen synthesization is finished rapidly by the use of magnetizer and activated oxygen enriched air under water, which has been cut into tiny air bubbles by the high-speed rotated propeller of the mixing chamber in the process of water and oxygen synthesization, which can increase the affinity of water and oxygen. When flow rate of water is more than the buoyancy force of the tiny air bubbles, it is difficult for the tiny air bubbles to float on water in short time and the tiny air bubbles can stay in water for longer time, which can increase the efficiency of water dissolving oxygen and make the power efficiency of the machine is greater than traditional aerator obviously.

聚氧活化曝气增氧机采用磁性工程技术,将空气中的氧经聚氧器聚集活化后送到水下主机的混合室,由水下的磁化器和活化富氧空气快捷完成水气合成程序,在水气合成过程中已被混合室内高速旋转的离心叶轮切割成微小气泡,这些随射流、射向水下方的小气泡,其动能消耗至零后,在水中的浮力作用下、开始缓慢上升,由于提高了水与氧亲合力的小气泡只靠浮力沿着螺旋型的曲线缓慢浮升,这些小气泡在短时间很难浮上水面,因此延长了小气泡在水中的停留时间和行走路程,大大提高水中溶解氧的效率,使该机的动力效率明显高于传统曝气装置。

The major components of oxygen scavenger films are polymer, oxidizable compounds, and catalyst. In this study, the oxygen scavenging capacity and oxygen scavenging rate of the oxygen scavenger film in water were determined for evaluating the performance of the films. The results showed that the film composed of polyethylene, 4% sodium erythorbate, and 0.1% EDTA cupric salt had the best oxygen scavenging efficiency. On the 1st and 10th day, the oxygen removed rate of the film was 0.02 and 0.065 mg/cm2/day, respectively, from 300 ml water.

脱氧膜主要为高分子聚合物、可被氧化之物质与催化剂之组合,本研究利用脱氧膜在水中的脱氧量及脱氧速率为指标,发现以聚乙烯加上4%异抗坏血酸钠与0.1% EDTA螯合铜离子盐类所制备之脱氧膜,具有较佳的脱氧效能,在300ml水中,储存第一天及第十天分别可达到0.02及0.065 mg/cm2/day之脱氧速率。

The test results showed that when the cycle water flow was 65m^3/h and the oxygen flow was 1, 2,……, 10L/min, the relationship between the dissolved oxygen and oxygen flow in the water was y=0.1009χ^2+0.0594χ+5.9588 (r=0.9927). According to the mass balance principle, the maximum oxygen utilization rate of oxygen cone was calculated at 84.56%. Under the condition of the maximum oxygen utilization rate of oxygen cone, according to the rate of Nile tilapia oxygen consumption, the number of oxygen cone was projected in industrialized fish farming system. It provided the basis for oxygen supply system design in industrialized fish farming system.

结果表明,在循环水流量为65 立方公尺/h,水温24.5℃,氧气流量为0, 1, 2,……,10 L/min的条件下,溶氧与氧气流量回归方程为y=0.1009χ^2+0.059 4χ+5.958 8(r=0.9927);根据物料平衡原理,推算出氧气锥的最大氧气利用率为84.56%;在最大氧气利用率的条件下,依照尼罗罗非鱼的耗氧率计算模式,推算出工厂化养鱼系统需配置氧气锥的台数。

The observed EMF values of oxygen concentration cell coincided withtheoretical values perfectly, indicating that the ceramics were purely oxide-ionicconductors with oxygen ion transference number of 1 under oxygen atmosphere over thewhole temperature range. The electrochemical oxygen permeation rates determined were inaccordance with the theoretical rates calculated from Faradays law, verifying directexperimentally that the oxide-ionic nature of the conduction under oxygen atmosphere. Athigh oxygen partialpressure range pO_2=10~(-5~10~5 Pa, they were almost pure ionicconductors, which was consistent with the result by means of oxygen concentration cell.Whereas at low oxygen partial pressure range pO_2=10~(-5~10~(-15)Pa, the samplesexhibited mixed ionic and electronic conduction.

结果表明,氧浓差电池电动势的实测值与理论值吻合得很好,氧离子迁移数为1,表明该系列样品在该温度下氧气气氛中为纯氧离子导体;氧泵实验结果进一步证实了该系列样品在氧气气氛中为纯氧离子导体;在氧分压pO_2=10~(-5)~10~5 Pa的高氧分压气氛中,电导率与氧分压变化基本无关,表明在该氧分压范围样品为纯离子导体,这与氧浓差电池电动势测定结果相吻合:在低氧分压为10~(-5)~10~(-15) Pa范围,总电导率随氧分压降低而稍有升高,表明在该氧分压范围样品为氧离子与电子的混合导体。

In chapter three the performance and structure of components of oxygen probe were especially investigated. The Cr-Cr〓O〓 powder was overcome by treatments. The reason of occurrence of thermal peaks on the EMF curves was explained. A water glass based cement which high temperature insulation was around 10MΩ within 10 seconds at 1600℃ was developed for the use of oxygen probe. The effects of tip end thickness of ZrO〓 tube and amount of reference electrode on response time and thermal equilibrium in oxygen probe were investigated. The optimum tip end thickness of ZrO〓 tube and amount of reference electrode addition were determined. It is found that the heat transfer in oxygen galvanic cell is the rate limiting-step in the response process. The national oxygen probe WOS Ⅱ type was designed and manufactured. By three batches of industrial tests its specification reached the level of American Celox Ⅱ type oxygen probe.

在第三章中分别从参比电极、高温绝缘水泥、插接件等组元入手,着重分析了其性能和结构,开发出了适合于钢液定氧用的Cr-Cr〓O〓参比电极,解决了Cr-Cr〓O〓参比电极高温产生收缩问题,解释了电动势曲线产生峰值的原因;开发了适合于定氧测头使用的水玻璃基耐火水泥,其高温绝缘电阻在1600℃,10秒以内为10MΩ左右;同时对ZrO〓管头部厚度、参比电极量对响应时间的影响以及定氧测头中的热平衡进行了研究,得出了合适的ZrO〓管头部厚度和参比电极加入量,确定了氧浓差电池中的传热是响应过程的限速步骤;设计制造了国产WOSⅡ型定氧测头,进行了三次现场定氧测试,其技术指标达到了美国Celox型定氧测头的水平。

The results indicated that, when dissolved oxygen concentration varied from 6 mg/L to 9 mg/L, turbots in nano-metre pure oxygen system were higher on growth, survival rate and feed conversion efficiency than those of air system; A farming trial was conducted to determine growth difference of turbot between pure oxygen and air system. Length growth, weight growth, survival rate and FCE were better in nano-metre pure oxygen system than air system. The results suggested that nano-metre pure oxygen was better than aeration in turbot farming system when dissolved oxygen concentration was from 6~9 mg/L.

结果表明,微米纯氧Ⅰ组大菱鲆的体重增长、成活率、肥满度及饵料转化率高于机械增氧组;微米纯氧Ⅱ组各指标低于机械增氧组。7个月的大规模生产试验(800 m2水面,溶解氧6~9 mg/L)表明,采用微米纯氧气泡增氧养殖大菱鲆,各测定指标均显著高于机械增氧,可以加快大菱鲆生长,提高成活率和饵料转化率。

HA can generate much reactive oxygen under the sunlight. When there are many reductants, e.g.

在光照条件下,HA可以产生大量的活性氧(Reaetive oxygen SPeeies,ROS)。

Biochemical oxygen demand is one of the most important parameters characterizing the organic pollution of wastewater and widely used in the fields of water quality monitoring and the evaluation of the wastewater treatment efficiency.

生化需氧量(biochemical oxygen demand,BOD)作为表征水体中种类繁多的有机污染物的集合参数,在水质评价、污染监测以及废水处理厂的运行分析等方面发挥着重要作用。

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