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Bis-(2-oxo-2-phenyl-ethyl) trithiocarbonate(TTC2) were synthesized with anion-exchange resin for the first time.

首次用阴离子交换树脂法合成了S,S′-二三硫代碳酸酯(TTC2)。

It was thought that appropriate amount of(superscript 2+) and small amount of vanadic oxide species segregating from the primary and the secondary structures of the oxo-anions have an impact on the reaction performance.

适宜量的(上标 2+)物种以及离析出来的少量V2O5物种可能均对催化剂的性能有贡献。显然,钒在不同位置的价态变化以及形态的不同,会导致催化性能的相应改变。

In the process, 2, 4-difluoroaniline is used to carry out ammoniated reaction. Then through a series of similar reactions, the important intermediate of temafloxacin, which is called 7-chloro-6-fluoro-1-(2, 4-difluorophenyl)-1, 4-dihydro-4-oxo-3-quinoline acid, is gained.

与环丙沙星和二氟沙星类似,用2,4-二氟苯胺进行胺化反应,再进行一系列类似的反应,制得合成替马沙星的关键中间体7-氯-6-氟-1-(2,4-二氟苯基)-1,4-二氢-4-氧代喹啉-3-羧酸。

85 And 119486/79. They are a novel type of antibiotic having both the wide antibacterial spectrum and high safety of penicillin and cephem antibiotics belonging to beta -lactam antibiotics, as well as the potent antibacterial activity and high beta -lactamase stability of carbapenem antibiotics.Sodium-(5R, 6S)-6-[-1-hydroxyethyl]-7-oxo-3- [-2-tetrahydrofuryl]-4-thia-1-azabicyclo [3.2.0] hept-2-ene-2-carboxylate 5/2 hydrate (faropenem sodium, hereinafter referred to as compound 1) is currently used as an oral drug for various infectious diseases and is reported to show potent antibacterial activity against not only methicillin-sensitive Staphylococcus aureus, Streptococcus pyrogenes and Streptococcus pneumoniae but also gram-positive bacteria for which conventional beta -lactam drugs have proved ineffective such as penicillin-resistant pneumococci, oral staphylococci and enterococci, also showing a wide antibacterial spectrum covering gram-negative bacteria such as Haemophilus influenzae and anaerobic bacteria such as the genus Bacteroides, which activity is due to its novel skeleton penem ring (Kagaku Ryoho no Ryoiki The Field of Chemotherapy, Vol.

他们是一种新型的抗生素都具有广泛的抗菌谱和高度的安全青霉素和cephem抗生素,属于β-内酰胺类抗生素,以及作为强大的抗菌活性和高β-内酰胺酶稳定的碳青霉烯类antibiotics.sodium -( 5 R , 6 S )-6 -[ - 1 -羟乙基] - 7 -氧- 3 - [ - 2 - t etrahydrofuryl] - 4 -硫杂- 1 -氮杂双环[ 3 。2.0]庚- 2 -节能- 2 -羧酸5 / 2水合物(法罗培南钠,以下简称为化合物1 )是目前用来作为口服药物,为各种传染病和报道,以显示强大的抗菌活性,不仅对甲氧敏感的金黄色葡萄球菌,链球菌pyrogenes和肺炎链球菌,但也克阳性菌为常规β-内酰胺类药物已证明无效,如青霉素耐药pneumococci ,口腔葡萄球菌和肠球菌,也显示出广泛的抗菌谱,包括革兰阴性菌如流感嗜血杆菌和厌氧菌如属杆菌,这活动是由于其新颖的骨架青霉烯环((化学ryoho没有ryoiki领域的化疗),第13卷,第10号,第74-80 , 1997年)。

All synthetic methods of the μ-oxo-bismetallo- tetraphenylporphyrins are comprehensively discussed, involving the two-step method, the chromatographic column method, the one-step method, the auto-oxidation method and the one-pot method developed by our group.

重点介绍了μ-氧代四苯基双核金属卟啉的合成方法,即两步合成法、柱色谱分离法、一步合成法、自氧化法以及本课题组最新开发的一锅法。其中一步合成法和自氧化法由于具有适用范围广、收率高等优点,将成为μ-氧代四苯基双核金属卟啉的主要合成方法。

Objective: To synthesize 2-benzyloxy-5-fluoro-4-oxo-pyrimidine-3-butyric acid ethyl ester, the key intermediate in the synthesis of fluorouracil derivatives.

目的:合成氟尿嘧啶类衍生物合成中的关键中间体2-苄氧基-5-氟-4-嘧啶酮-3-丁酸乙酯。

One compound is identified as the title compound 2-benzyloxy-5-fluoro-4-oxo-pyrimidine-3-butyric acid ethyl ester, and the other one is its formula isomer.

通过IR谱确证一个化合物是目标物2-苄氧基-5-氟-4-嘧啶酮-3-丁酸乙酯,另一化合物是它的同分异构体。

Ten N-[2,4-disubstituted-5-(3-methy-2,6- di-oxo-4-trifluoromethyl-1,2,3,6-tetrahydropyrimidin-1-yl)phenyl]imides were designed and synthesized. Their structures were confirmed by 1H NMR, IR, HPLC/MS and elemental analysis.

设计并合成了10个未见文献报道的N-[2,4-二取代-5-(3-甲基-2,6-二氧-4-三氟甲基-1,2,3,6-四氢嘧啶-1-基)苯基]酰亚胺类化合物,其化学结构经1H NMR, IR, HPLC/MS和元素分析表征。

The asymmetric reduction of prochiral P-oxo ester, aromatic ketone and aliphatic ketone to its corresponding chiral alcohol by yeast cells were studied respectively in this work when ethyl 4-chloro-3-oxobutyrate, acetophenone and 2-octanone were as the model substrates.

本文以4-氯乙酰乙酸乙酯、苯乙酮和2-辛酮分别为β-羰基酯、芳香酮和脂肪酮的模型底物,研究了利用活性酵母细胞催化这三类前手性酮不对称还原合成相应手性醇的反应特性。

In the first part, rhodium acetate catalyzed 1, 3-dipolar reactions of 1-diazo-2-oxo-propylphosphonates with nitriles was studied.

在催化量的醋酸铑作用下,1-重氮-2-羰基丙基膦酸酯与芳香腈顺利进行反应,而对脂肪腈的反应则很复杂,没有得到预期产物。

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This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。

There is no differences of cell proliferation vitality between labeled and unlabeled NSCs.

双标记神经干细胞的增殖、分化活力与未标记神经干细胞相比无改变。