查询词典 oxo

Introduction of production process of phenylacetic acid by oxo synthesis

5万吨/年，羰基合成法产能已占国内总产能的60%以上。

The famciclovir was synthesized from purine by a series of steps by Acylation, Decarboxylation, Reduction ,and so on; Derivatives of these intermediates is described from the 6-chloro- 9H- purin-2-amine as raw materials in different conditions when the iodine and bromide were synthesized with the addition of two intermediate 6-bromo-9H-purin-2-amine and 6-iodo-9H-purin-2-amine; There is elaborated from the main part of a acetophenone, urineaminohydrochloride, phenylhydrazine, ethyl acetoacetate as raw material through a series of reactions to synthetic 3-phenyl-4-formylphenyl pyrazole and 5-chloro-3-methyl-1-phenyl-1H-pyrazole-4-aldehyde two pyrazole aldehyde, and then with 2-amino-6-chlorine-9-(2-methicillin-oxo-co-methyl-4-yl) purine reaction of the two new pyrazole purine Schiff bases.

本论文主是采用以鸟嘌呤为原料，经过一系列的酰基化，脱羧，还原等反应作用下最终得到了产物2-氨基-9-(4-乙酰氧基-3-乙酰氧基甲基丁基)嘌呤；其中的中间体衍生物主要是阐述从以2-氨基-6-氯鸟嘌呤为原料通过在不同的条件下进行溴代与碘代分别合成了另外两种中间体2-氨基-6-溴鸟嘌呤及2-氨基-6-碘鸟嘌呤；还有一部分主要是阐述从以苯乙酮，盐酸氨基脲，苯肼，乙酰乙酸乙酯为原料通过一系列的反应先合成3-苯基-4-醛基吡唑及5-氯-3-甲基-1-苯基-1H-吡唑-4-甲醛这两个吡唑醛，然后再与2-氨基-6-氯-9-(2-甲氧羰基丁酸甲酯-4-基)嘌呤反应得到了两个新型的吡唑嘌呤席夫碱

Propionic acid is an important chemical raw materials, due to the lack of domestic technology, the paper is to study low, High activity of ethanol Oxo acid catalyst.

丙酸是一种重要的化工原料，由于国内技术的欠缺，本文旨在研究低要求、高活性的乙醇羰基合成丙酸催化剂。

A new photochromic organic compound of thiosemicarbazone, 4-( p -bromo-α-methylaminothiocarbonyl hydrazonobenzal)-2,5-dihydro-3-methyl-5-oxo-1-phenyl pyrazole, was synthesized and characterized by elemental analyses, IR, 1H NMR spectra, and X-ray single-crystal diffraction analysis.

文章合成了一个新的有机化合物1-苯基-3-甲基-4-对溴苯亚甲基-吡唑啉酮-5 缩甲基氨基硫脲(1)，并分别用元素分析、红外光谱、氢核磁共振及X-射线单晶衍射对化合物的结构进行了确证和表征。

At the initial isolation to the extract from ethyl acetate, tow kinds of crystal a and b with higher purity were found, and the primary components were 98.45%. Quinic acid and 69.34% L-Proline, 5-oxo-, methyl ester.

在乙酸乙酯部分进行初次分离时，还得到了两种纯度较高的晶体a和b，经GC-MS分析可知其主要成份分别为98.45%奎宁酸和69.34%的5-脯氨酸甲酯。

Comparing with chitin and starch, the thermal stability of the sulphated polysaccharide Hal-A and heparin is lower. The results of TG- IR analysis demonstrate that Hal-A is decomposed into CO_2, H_2O, alcohols, oxo-compounds etc and remains mainly contain Na_2SO_4 and carbon.

与淀粉、肝素、甲壳素和半乳糖的热分析比较，含有硫酸酯的鲍鱼多糖和肝素热稳定性较低，含氨基的甲壳素最高，这反映出不同基团对多糖热稳定性的影响。

In the first part, the prototropic hydroxy-oxo tautomerisms of 2 (1H)- pyridones/2-hydorxypyridines, one of the most important model systems in molecular biology, have been investigated with self-consistent reaction field method based on continuum model. The influence of the nature and position of substituent groups, the existence of intramolecular hydrogen bonding and tautomeric competition between 2-hydroxy and 4-hydroxy on the tautomeric equilibria have also been examined.

第一部分，首先从溶剂敏感的异构化性质入手，用基于连续介质的自洽反应场理论方法对一类重要的生化模型体系—2（1H）-吡啶酮／2-羟基吡啶互变异构体系进行了研究，系统地考察了取代基性质、取代基位置、分子内氢键的形成以及互变异构竞争的存在对异构化平衡的影响。

The results obtained form theoretical calculations indicate that the hydroxyl-tautomer predominate in the gas phase or nonpolar solvents, while in solvents of high dielectric constant, the tautomeric equilibria is shift in favor of the oxo-tautomer can be mainly ascribed to the polarization effects.

结果表明，2（1H）-吡啶酮类化合物在极性溶剂中表现出与气相或非极性溶剂中截然不同的的优势结构主要是由于各异构体分子极性上的差异引起的。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

But the yields decreased to 71~37％ in n-propanol, i-propanol and i-butanol, with another trimeric byproduct 1-oxo-13c-(2-naphthyloxy)-1, 13c-dihydro-dibenzo xanthenes (29) increasing up to 30％ yield.

而在正丙醇、异丙醇和异丁醇中二苯并咕吨4~6的产率下降至71~37％，另一个二聚体副产物1-氧代-13c-（2-萘氧基）-1，13c-二氢-二苯并-咕吨（29）的含量增加，产率可达30％。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。