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Effect of oxidized chicken fat on the volatiles formed in arabinose/cysteine model reaction and interaction between oxidized chicken fat and volatile compounds formed in model reaction were investigated.

研究氧化鸡脂对D-阿拉伯糖/L-半胱氨酸模型体系反应所产生挥发性产物的影响,同时对氧化鸡脂和模型体系产物的相互作用进行分析。

Because fatty oil extracted from ascidian contains a relative high concentration of polyunsaturated fatty acid and can be oxidized easily, it is necessary to add appropriate antioxidant in the fatty oil to prevent it from being oxidized.

研究发现,维生素E和中草药荔枝草的乙酸乙酯提取物对海鞘油脂具有很好的抗氧化作用。

In the reaction, some aniline is completely oxidized to CO2 or partially oxidized to carboxylic acid.

在反应中有一部分苯胺被完全氧化或部分氧化成CO2或羧酸,

By using geological and geochemical data, the genetic type of the Silurian asphaltic sandstones in Tarim Basin is investigated and divided as the following:(1)Oxidized asphalt on surface or in shallow-layer is the heavy asphalt crude and solid oxidized asphalt or gilsonite formed by volatilization, oxidization, water washing and biodegradation in oil-layer outcrop area or near earth surface.

通过对地质、地球化学等资料的研究,认为塔里木盆地志留系沥青砂岩有5种成因类型:①表生—浅层氧化沥青是指在油层露头区或油层位于近地表处,由于挥发、氧化、水洗和生物降解等作用而形成的一些焦油状沥青质重油以及固体浅层氧化沥青或硬质沥青。

Moreover,the selective oxidation of primary and secondary alcohols to corresponding carbonyl compounds with the multinuclear copper complexes Cul-Cu4 as catalysts have been conducted using TBHP and O_2/TEMPO,respectively.Among them,the copper complex Cu3 showed the best performance.On the performances of the two classes of oxidants,benzylic and heterocyclic alcohols could be effectively oxidized to carbonyl compounds.Specifically,the secondary alcohols could be effectively oxidized to ketones with excellent selectivity up to 100%in the presence of TBHP and the allylic alcohols could be effectively oxidized to aldehydes in the presence of O_2/TEMPO system.

实验结果还表明,在TBHP或O_2/TEMPO存在下,各配合物催化剂均能使各种取代芳香伯/仲醇以及杂环醇等以不同程度的转化率和选择性转化成相应的醛或酮,其中,配合物Cu3在O_2/TEMPO存在下可使苯甲醇和烯丙醇等以较高转化率和近100%的选择性转化成相应的醛,而对其它芳香醇和脂肪伯/仲醇等的催化性能则较差;在TBHP存在下,配合物Cu3则可使1-苯乙醇和其它仲醇以较高转化率和近100%的选择性转化为相应的酮,但对各类其它伯醇选择氧化的性能相对较差。

In the presence of O〓, peroxyl radicals formed under neutral condition are either directly oxidized to non-aromatic acids, or forms aromatic intermediates, which are further oxidized to non-aromatic acids; peroxyl radicals formed under alkaline conditions are directly oxidized to non-aromatic acids.

有氧状态下的羟基自由基氧化体系中,过氧自由基在氧气的催化作用下既可开环形成有机酸,也可形成4-氯邻苯二酚和对苯二酚,进而氧化开环成有机酸,并最终矿化;碱性条件下的过氧自由基则直接开环降解。

Unoxidated and oxidized wheat stalks were extracted sequentially with CS2, benzene, methanol, acetone and THF, and the extraction solutions were analyzed with GC/MS. The relative contents and compositions of fractional extracts of un-oxidized and oxidized wheat stalks were compared.

采用二硫化碳、苯、甲醇、丙酮和四氢呋喃对未氧化和氧化的麦秆进行分级萃取,比较麦秆各级萃取物的相对含量和组成差异,并对各级萃取物的组成进行GC/MS分析。

Overall, emissivity of both oxidized and unoxidized samples increases with increasing temperature;(2) emissivity of unoxidized sample doesn t change with time. However, emissivity of oxidized sample increases due to the growing oxide layer with time;(3) a stronger effect of alloy composition is evident for oxidized samples.

整体而言,有氧化与无氧化之放射率皆随著加热温度增加而上升;(2)铝合金於开放环境之放射率随加热时间增长而明显上升,但在真空腔体内之铝合金其放射率却不随加热时间增长而改变,因为氧化层会随著时间增加而成长进而造成表面放射率上升;(3)合金成份对放射率的影响在氧化下比无氧化呈现显著的差异。

The interlayer oxidized zone and the concentration of uranium has the typical characters of low temperature geochemical processes. Interlayer oxidized zone can be defined from the bedrock to horizon C under hypergene weathering by such parameters as chemical metamorphosing、index of chemical weathering and index of mineral chemical differentiation.(2)Major elements can be divided into sensitive group、 active、 weak active and inert groups according to chemical metamorphosing parameter and fractional migration potential. For major elements of multivalent in the active group( Fe_2O_3、 FeO) and U, the migration and concentration trend in interlayer oxidized zone is apparent.

层间氧化带形成和铀富集成矿是地下水在低温、常压、开放体系、非平衡状态对围岩长期作用结果,元素含量及其有关地球化学参数在氧化带不同亚带中表现出一定的变化和分布规律,除Fe_2O_3、FeO、Fe_2O_3/FeO外其它元素含量及其参数只在统计学上呈现规律性变化,而不具分带意义,具有典型的低温地球化学作用特点;利用风化作用化学蚀变参数PC值、化学风化指数ICA和矿物化学分异指数ICV将层间氧化带作用界定于表生风化作用的基岩到母质层阶段。

The formal potentials in cyclic voltammograms of these 3+ valence complexes are followed: Co〓-TPPS (-0.08V )>Fe〓TPPS (-0.14V)>Mn〓-TPPS (-0.23V). The electrochemical reaction of Mn〓-TPPS is reversible, and both of Co〓-TPPS and Fe〓-TPPS are quasi-reversible. The standard heterogeneous rate constants of Co〓-TPPS and Fe〓-TPPS were determined to be 1. 4×10〓cm/s and 1.4×10〓cm/s respectively. The rates of electrode reaction are as followed: Mn〓-TPPS>Co〓-TPPS>Fe〓-TPPS, e.i. Mn〓-TPPS is the most easily oxidized by the dissolved oxygen, and Fe〓-TPPS is oxidized slower than Co〓-TPPS. Ni〓-TPPS can not be oxidized. It is considered that oxygen plays an important role in the valence change of central metal atom and the rate of electron transfer in some metalloporphyrins.

三价金属卟啉络合物在循环伏安图上可得到三价到二价的还原和氧化响应,电极电位从大到小排列为:Co〓-TPPS(-0.08V)>Fe〓-TPPS(-0.14V)>Mn〓-TPPS(-0.23V),电极反应可逆性也不相同,Mn〓-TPPS是可逆过程,Co〓-TPPS、Fe〓-TPPS是准可逆过程,实验测得Co〓-TPPS的标准电极反应速率常数ks=1.4×10〓cm/s,Fe〓-TPPS的ks=1.4×10〓cm/s,电极反应的速率从大到小为:Mn〓-TPPS>Co〓-TPPS>Fe〓-TPPS,即Mn〓-TPPS最容易被溶解氧所氧化,Fe〓-TPPS被氧化的速度最慢,Ni〓-TMPyP不能被氧化,因此我们认为溶解氧对金属卟啉中心离子的价态和电子转移速率起着重要作用。

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