查询词典 oxidation-reduction

A selective and mild PS-DIB/ionic-liquid immobilized 2, 2, 6, 6-tetramethyl-piperidin-4-ol-N-oxyl catalytic oxidation procedure of alcohols to the corresponding aldehydes and ketones in ionic liquid BF4 at room temperature was developed. The oxidant PS-DIB was prepared via the iodation and acetylation of polystyrene resin. For the preparation of the ionic-liquid immobilized TeMPO catalyst, 4-(2, 2, 6, 6-Tetramethyl-1-oxyl-4-piperidoxyl)butyl bromide was first synthesized from TeMPO and 1, 4-dibromobutane.

将聚苯乙烯树脂先碘化再乙酰基化，制得了负载型二乙酰氧碘苯作为氧化剂。2， 2， 6， 6-四甲基－N-氧自由基哌啶醇与1， 4-二溴丁烷反应生成4-溴丁氧基－2， 2， 6， 6-四甲基－哌啶－1-氧化物，再与N-甲基咪唑发生季铵化反应，生成的溴化季铵盐与四氟硼酸钠进行离子交换制得氟硼酸型2， 2， 6， 6-四甲基－N-氧自由基哌啶负载离子液体。

A selective and mild PS-DIB/ionic-liquid immobilized TEMPO catalytic oxidation procedure of alcohols to the corresponding aldehydes and ketones in ionic liquid BF4 at room temperature was developed. The oxidant PS-DIB was prepared via Iodation and acetylation of polystyrene resin. For the preparation of the ionic-liquid immobilized TEMPO catalyst, 4-(2,2,6,6-Tetramethyl-1-oxyl-4-piperidoxyl)butyl bromide was first synthesized from 2,2,6,6-tetramethyl-piperidin-4-ol-N-oxyl and 1,4-dibromobutane.

将聚苯乙烯树脂先碘化再乙酰基化，制得了负载型二乙酰氧碘苯(diacetoxyiodo polystyrene，PS-DIB)作为氧化剂。2，2，6，6-四甲基-N-氧自由基哌啶醇(2，2，6，6-tetramethyl-piperidin-4-ol-N-oxyl，TEMPO)与1，4-二溴丁烷反应生成4-溴丁氧基-2，2，6，6-四甲基-哌啶-1-氧化物，再与N-甲基咪唑发生季铵化反应，生成的溴化季铵盐与四氟硼酸钠进行离子交换制得氟硼酸型2，2，6，6-四甲基-N-氧自由基哌啶负载离子液体TEMPO-IL。

Using Agilent 8453 ultraviolet-visible spectrophotometer, the affecting factors were studied on the kinetic processes in iodometry involved in the volatilization of iodine and the oxidation of iodide ion by dissolved oxygen, in particular such as the shape of the vessel, the volume of the solution tested, the concentration of KI and the temperature and the acidity of tested solution.

利用紫外－可见分光光度仪测量了I2挥发、I在酸性介质中被溶解氧氧化的动力学过程，着重研究了容器形状、溶液体积、KI浓度、温度等因素对I2挥发速率的影响以及溶液酸度与I氧化反应速率的关系。

A generator of electricity using chemical energy directly by ionization and oxidation of the fuel.

通过燃料电离和氧化，直接将化学能转换成电能的发生器。

CO forms CO2 by oxidation and does not ionize.

二氧化碳也不会电离。

The oxidation of β-ionone with molecular oxygen over Au/ZSM-5 was studied.

详细探讨了不同载体、氧化剂、溶剂、反应温度和反应时间对β-紫罗兰酮氧化反应的影响。

Then,the oxidation ofβ-ionone catalyzed by CMPS-Co_2 has been performed,andβ-ionone was oxidized to 4-oxo-β-ionone as the main product,and the influence of a series of different conditions for the reaction was also investigated.

首先将催化剂CMPS-Co_2应用于β-紫罗兰酮的催化氧化，主要得到4-氧代-β-紫罗兰酮，并考察了不同反应条件对β-紫罗兰酮选择性氧化的影响。

The procedure of oxidation of β-ionone by sodium chlorate was studied using gas chromatography-mass spectrometry to analyze the reaction products. And their structures were characterized by IR, MS, 1HNMR and EA.

采用GC-MS方法分析反应产物，对氯酸钠氧化β-紫罗兰酮的反应工艺进行研究，并探讨温度、时间、反应物配比和溶液的pH值对反应的影响。

A series of L-histidine Schiff bases that include Sal-His (H2L^1), Br-Sal-His(H2L^2), NO2-Sal-His (H2L^3) and their Cu complexes were synthesized, and the catalytic behavior of Schiff-base-Cu for the oxidation of β-ionone to 4-oxo-β-ionone as well as the effects of substitutents on these properties were examined.

合成了芳环上含不同取代基的Schiff碱配体（水杨醛缩组氨酸(H2L^1)、5-溴水杨醛缩组氨酸(H2L^2)、5-硝基水杨醛缩组氨酸(H2L^3)及其铜配合物，研究了其作为催化剂应用于催化分子氧氧化β-紫罗兰酮制备4-氧代－β-紫罗兰酮中的行为。

This article inspects the curing product the oxidized exothermic reaction active influencing factor, catches fire from the theory and the experimental result analysis iron pyrites oxidation exothermic initiation with explosion accident's reason, thus proposed that prevents the oil quality storage tank to catch fire with the detonation measure.

本文考察硫化产物的氧化放热反应活性的影响因素，从理论和实验结果分析硫铁化物氧化放热引发着火和爆炸事故的原因，从而提出防止油品储罐着火和爆炸的措施。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。