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Finally, the cytotoxic and antibacterial activities of the oxamido-bridged binuclear complexes were studied in vitro.. This dissertation consists of three sections as follows:1. The crystal structure of a oxamide dinitrate,(1) [H_4dmaeoxd](NO_3)_2 H_2dmaeoxd = N,N\'-bis[2-ethyloxamide, has been obtained. The diversity of complexes with different structures is carried out by successful synthetic strategy of controlling species of metal ions, counter anions, pH values and solvents in the course of synthesis. Four dinuclear complexes bridged by trans-dmaeoxd2-: [Cu_2_2](ClO_4)_2 (2), [Cu_2_2](ClO_4)_2 (3),、[Cu_2(Me_2phen)_2](ClO_4)_2 (4), [Cu_2_2(H_2O)_2] (5); Four dinuclear complexes bridged by cis-dmaeoxd2-: [NiNi_2](ClO_4)_2 (6), [CuNi_2](ClO_4)_2·2CH_3OH (7), [CuZn_2]-(ClO_4)_2·2H_2O (8), [Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9); three 1-D polynuclear complexes: [Cu_2]_n·nH_2O (10), [Cu_2(H_2O)_2-]_n·4nH_2O (11), [Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12); one 2-D polynuclear complex,[Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n).2nH_2O (13); the others: [VO(H_2O)]·2H_2O (14), [Zn_2_4](ClO_4)_2·H_2O (15), [Cu_2]·2DCM (16) have been synthesized and characterized by X-ray single crystal diffraction, elemental analysis, IR spectra.
本论文主要包括以下三部分:一、合成得到了一个草酰胺配体硝酸盐的单晶结构,[H_4dmaeoxd](NO_3)_2 (1);通过调控金属离子的种类、端基配体、抗衡阴离子、溶剂、pH值等条件定向合成了四个反式草酰胺桥联双核铜配合物:[Cu_2_2](ClO_4)_2 (2)、[Cu_2_2](ClO_4)_2 (3)、、[Cu_2(Me_2phen)_2](ClO_4)_2 (4)、[Cu_2_2(H_2O)_2] (5);四个顺式草酰胺桥联同/异双核配合物:[NiNi_2](ClO_4)_2 (6)、[CuNi_2](ClO_4)_2·2CH_3OH (7)、[CuZn_2]-(ClO_4)_2·2H_2O (8)、[Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9);三个一维聚合物: [Cu_2]_n·nH_2O (10)、[Cu_2(H_2O)_2-]_n·4nH_2O (11)、[Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12);一个二维聚合物: [Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n)。2nH_2O (13);单核钒配合物[VO(H_2O)]·2H_2O (14)、草酸根桥联双核锌配合物[Zn_2_4](ClO_4)_2·H_2O (15)、美洛西康铜配合物[Cu_2]·2DCM (16),利用元素分析、摩尔电导、红外光谱、电子光谱和单晶X-射线衍射对上述所得化合物进行了结构表征,探讨了结构影响因素,并研究了其超分子结构。
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With the Greater Flamingo Phoenicopterus roseus, it is one of two Old World flamingo species.
与大火烈鸟Phoenicopterus roseu一样,小火烈鸟也是这两种旧世界(非洲在地理区划上属于旧热带界,欧洲是古北界)火烈鸟的一种。
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Three, broad market prospects: first, Photinia fraseri in the use of color can be used for shrubs, spherical shape, can also be used as small trees, and in the use of one-upmanship; Second, through the winter can also be pruned to ensure that their color bright red, made up for the lack of winter less than the red line of trees, and the hi-yang-resistant semi-shade, with high light adaptability, strong or weak; Third, the wide range of applications, and strong adaptability, excellent viewing, making the market capacity Photinia fraseri great Photinia fraseri Application of ecological diversity will add an excellent landscape tree species.
三、广阔的市场前景:其一红叶石楠在用途上可作灌木色块、球状造型,也可作为小乔木用,在用途上胜人一筹;其二,通过修剪冬天也可保证其叶色红色亮丽,弥补了冬天缺少红色系列树木的不足,且其喜阳耐半荫,具有较高的光线强弱适应性;其三,广泛的应用性,强大的适应性,优秀的观赏性,使红叶石楠的市场容量极大,红叶石楠的应用将给多样性的生态园林添上一个优秀的树木品种。
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The unusual animal, called Phronima, is one of the many strange species recently found on an expedition to a deep-sea mountain range in the North Atlantic.
这种与众不同的动物名为&Phronima&,是最近在北大西洋深海山脉进行探险时发现的众多怪异物种中的一个。
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Called Phronima, this unusual animal is one of the many strange species recently found on an expedition to a deep-sea mountain range in the North Atlantic.
这种与众不同的动物名为&Phronima&,是最近在北大西洋深海山脉进行探险时发现的众多怪异物种中的一个。
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Phyllanthus emblica is one of the dominant species distributed in dry-hot valleys of southwestern China. Besides its function in ecology, environment and reforestation, it is also an important medicinal plant.
余甘子是我国西南干热河谷地带的优势植物,也是一种重要的药用经济植物,对其遗传多样性进行研究对生态环境的建设和恢复有着重要意义。
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Furthermore, phylogenetic analysis also indicated that all the sequences from the same species were clustered to one group.
系统发育分析发现,来源于同一种内的2条序列都被聚为一个类群。
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One gene chip for detecting four species of Phytophthora at same time was the first reported in the world, which has wide applying future.
该方法也是国内外首次利用一张芯片,同时对四种植物病原真菌进行检测的研究报道,其应用前景十分广阔。
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Picea mongolica, which is a characteristic and one of the first afforestation tree species in Inner Mongolia, plays a great role at the vegetation recovery in the desertfied areas.
沙地云杉是内蒙古赤峰地区与锡林浩特的局部地段所特有乡土树种之一,也是沙地造林的首选树种之一,对于恢复沙化土地植被具有重要的意义。
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Herb category are: Codonopsis, Platycodon, Ma Dou Ling, Zhimu, Polygonum multiflorum, Ligustrum lucidum, Speranskia grass, licorice, huangling, such as one hundred species of Bupleurum.
药草类主要有:党参、桔梗、马斗铃、知母、何首乌、女贞子、透骨草、甘草、黄苓、柴胡等一百余种。
- 推荐网络例句
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This one mode pays close attention to network credence foundation of the businessman very much.
这一模式非常关注商人的网络信用基础。
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Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.
扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。
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There is no differences of cell proliferation vitality between labeled and unlabeled NSCs.
双标记神经干细胞的增殖、分化活力与未标记神经干细胞相比无改变。