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The Pd-Cu/C catalysts were shown to have the face centered cubic crystal structure. This could indicate that the addition of Cu shortened the Pd-Pd distances in the crystal lattice, and therefore –HO(subscript 2ads) and O-O could be better adsorbed on the surface of the catalyst. When NaBH4 was used as the reducing agent, and the atomic ratio of Pd to Cu was 3:1, the resulting catalysts had an average particle size of 3. 4nm and showed the best catalytic performance. The electrochemical active surface are a of Pd3Cu/C was 38.9m^2/gPd and the oxidation reduction reaction activity of the Pd3Cu/C catalyst was much higher than that of the Pd/C catalyst. The electrochemical activity of the Pd3Cu/C catalyst was comparable to that of a commercial Pt/C catalyst.

结果表明:催化剂中Pd与Cu的物质的量之比与预设值相近,Pd和Cu基本被全部还原;Pd-Cu/C催化剂为面心立方结构,元素铜的加入使催化剂的Pd-Pd间距缩小,从而HO(下标 2 ads)和OO键能更好地吸附在催化剂金属表面;当采用NaBH4为还原剂,Pd与Cu物质的量比为3:1时,催化剂(Pd3Cu/C)的平均粒径为3.4 nm,催化剂的催化性能最好,电化学活性表面积EAS达到38.9平方公尺/gPd,电化学性能较Pd/C催化剂有很大提高,接近Pt/C商用催化剂。

The surface appearance and hygroscopicity of ADN after coating were analyzed by SEM and weighing method. Results show that a kind of floccule of PU is formed on the surface of ADN, which makes the hygroscopicity of ADN after coating less than that before coating evidently. When coated ADN is exposed in the atmosphere for 30 days with the RH less than 60%, the hygroscopicity of coated ADN is only 0.136% and does not increase with the increasing of exposure time.

用扫描电镜和称重法分析了包覆后ADN的表面形貌和吸湿性,结果表明,聚氨酯黏合剂在ADN表面形成絮状的包覆膜,使包覆后ADN的吸湿率明显小于包覆前ADN,在相对湿度60%以下,包覆后ADN在空气中暴露30天时吸湿率仅0.136%,吸湿率不随时间增加。

It was found that Pd-Co/active carbon catalyst was the optimal catalyst, and Pd-Co/γ-Al2O3 was also good, but silica and kieselguhr were not proper carriers for the object reaction, because of their stronger surface acidity, which could result in the formation of polymer, jammed the micro pores of catalyst, and then resulted in its deactivation. Addition of Bi, Ce and Cu promoters could not improve the activity of catalyst, but La and Ba promoter could enhance the activity of catalyst apparently, and the Co was the best promoter, especially Co was impregnate in advance. It was attributed to that the pre-impregnated Co may occupy the micro pores of active carbon, and cover some bad functional groups on the surface of catalyst, so that the active and selectivity of catalyst could be enhanced obviously.

研究结果表明,Pd-Co/活性炭催化剂是目标转移加氢反应的最适宜催化剂,Pd-Co/γ-Al203效果也较好,而硅胶和硅藻土由于表面酸性较强,容易造成生成聚合物而堵塞催化剂微孔、使催化剂迅速失活;此外,添加Bi、Ce、Cu等助剂时对活性并无改善作用,而添加La和Ba助剂时可使Pd的催化活性有所提高,效果最好的是Co助剂,尤其是先浸渍Co的Pd-Co/C催化剂,原因是Co占据了活性炭的微孔、覆盖了某些对目标反应不利的官能团,使其活性和选择性都有较大幅度的提高。

Antibacterial function of body wall was conducted by the following way: microorganism was directly resisted through the change of cuticle, such as incrassation of up-cuticle protuberance and increasing length of micro-floccus in the up-cuticle dissociation surface; exudation function of large granular orthochromatic mucous cells and reticulation mucous cells in the epidermis could be enhanced when the Eisenia fetida was induced by E. coli. Moreover, the mucus that contained compound substance of mucopolysaccharide and protein could make the bactericidal function or dilute the microorganism on the surface of earthworm, which could protect earthworm from invasion of microorganism; the content of neutral mucopolysaccharide of antibacterial function could be increased according with the exudation increment of small granular proteinaceous cells in the epidermis, which could resist bacteria invading into the epidermis of earthworm.

结果表明:蚯蚓的体壁主要是通过以下途径来抗细菌的侵袭:一是通过角质层的变化(如上胶层突起的增厚、上角层游离面中微绒毛的变长等)直接抵抗微生物的入侵;二是增加表皮中大颗粒粘液细胞和网状细胞的分泌功能,分泌出大量含有粘多糖蛋白液体复合物的粘液,在蚯蚓体表对细菌进行稀释或者起到直接杀菌的作用;三是通过增加小颗粒蛋白细胞的分泌作用,在蚯蚓的表皮中分泌出更多的抵抗疾病的中性粘多糖,从而抵抗进入蚯蚓体表内的细菌。

These OPN can be seen as a chemotatic factor to guide prosoma osteoclast to migrate to the surface of the bone, and mediate it to combine with the integrin on the surface of osteoclast so to promote the resorption of bone.

骨吸收可以看做机械压力造成的系列分子事件的结果,骨桥蛋白作为一种主要的蛋白参与骨吸收与骨改建这两种过程。

Paper publishes materials that are used by anlistatig is a tetravalent salt toxicchemical on the surface of the paper, in low humidities quadrivalent salt water from the air, to reduce the material surface resistance.

纸类承印质料所用的抗静电剂是一栽四价盐的冻学品涂在纸暗不天上后,在矮湿度下四价盐从氛围洋汲取水分,使堵住质料暗不天的电阻减小。

AT89C51 single-chip microcomputer is used as the test and control core of the intelligent robot in this design,which detects the black line and barrier on the surface of road with infrared photoelectric sensor,and detects iron piece beneath the surface of road with metal sensor,and measures range with photoelectric yard measure,tests and judges the garage position with photoresistor,and also dynamically controls rotating direction and speed of motor by PWM(Pulse-Width Modulation) technique.

本设计以AT89C51单片机作为智能机器人的检测和控制核心,采用红外光电传感器检测路面黑线及障碍物,使用金属传感器检测路面下金属铁片,应用光电码盘测距,用光敏电阻检测、判断车库位置,利用PWM技术动态控制电动机的转动方向和转速。

The geometries of the silver/sulfur clusters Ag 〓 in gas phase and Ag 〓 on the surface of the silver bromide surface were modeled by the Density Functional Theory , ZINDO/1 and molecular mechanism.

利用密度泛函,ZINDO/1和分子力学的方法模拟了气相中的Ag〓团簇构型和溴化银颗粒表面上的Ag〓的构型。

The Surface composition of grafted PET fiber was characterized by ATR-FTIR. THE results showed that there were no obvious differences between ungrafted and graft PET fiber in the spectra ,except that the typical peak of-OH in 3100cm~(-1) appeared in both Citric acid treated PET fiber and Acrylic acid treated PET fiber indicated citric acid and acrylic acid had been successfully grafted on the surface of PET fiber.

对样品的接枝效果进行红外光谱表征,发现无论是经过丙烯酸接枝处理,还是柠檬酸接枝处理,处理前后纤维的红外吸收光谱图都没有明显的区别,说明接枝前后纤维的主体性质没变,但是,二者在3100cm~(-1)处都出现了羟基的特征吸收峰,说明柠檬酸和丙烯酸都已经接枝上了PET纤维表面。

The results show that the bioceramic coating contains such bioactive phases as hydroxyapatite and tricalcium phosphate during laser cladoping. And the interlaced flake structure and micropores of about 0.5~2 μm in size exist on the surface of accidented gradient bioceramic coating, suitable to grow new bone along with the surface and micropore.

结果表明:激光熔覆复合涂层中生成了羟基磷灰石和磷酸三钙等生物活性相,凹凸不平的表面出现网络交错的片状结构和微孔(孔径为0.5~2 μm),有利于新骨沿着表面及内部连通微孔攀附生长。

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