查询词典 nitrobenzene

From the photophysical behaviors of 1, 3, 4-triaryl-2pyrazoline compound (TPP16) at low temperature, it can be considered that the twisted configuration between pyrazoline ring and the non-substituted phenyl group on the position 1 is the fluorescence configuration of conjugated system Ⅰ, and the twisted configuration between pyrazoline ring and P-nitrobenzene group is fluorescence configuration of conjugated system Ⅱ.

研究了1，3，4-三芳基-2-吡唑啉化合物TPP16在低温时的发光情况，发现：在低温77K下，共轭体系Ⅰ(苯基-N1-N2＝C3-苯基)在非极性溶剂中不发荧光，在极性溶剂中有较强荧光发射；而共轭体系Ⅱ(N1-N2＝C3-C4＝对硝基苄叉)在非极性溶剂或极性溶剂中均有荧光发射，表明N1所联取代基与吡唑啉环相扭曲的构象是共轭体系Ⅰ的发光构象，而对硝基苄叉与吡唑啉环相扭曲的构象是共轭体系Ⅱ的发光构象。

The active stability and amount of the catalyst were studied and the influential factors ,such as solvent, temperature and pressure were investigated,and then the optimal process parameters were given∶Raney∶ethanol∶3,4-methylene-dioxy nitrobenzene is 0.15∶6∶1;the reaction temperature is 40℃;the hydrogenation pressure is 0.45～0.50 MPa;the stir velo...

对催化剂用量和活性稳定性进行了研究，讨论了溶剂用量、温度、压力等因素对加氢反应的影响。结果表明最佳工艺参数为：雷尼镍∶乙醇∶3，4 亚甲二氧基硝基苯=0.15∶6∶1，反应温度40℃，氢压0.45～0.50MPa，搅拌速度450r/min，反应至不再吸氢为止，产品收率在97%以上，纯度为98%。

The synthetic product was proved by IR and MS. The translation ratio of nitrobenzene was about 90%by titrating amino group value. The selectivity of p-aminophenol was 80%.

合成产品通过IR、MS确认其结构，并通过滴定氨基值计算出硝基苯的转化率为90％左右，产品的选择性达80％。

The osteogenic differentiation markers were determined by para position Nitrobenzene phosphoric acid and Alizarin Red S staining.The expressions of CBFA1 and VEGF mRNA in BMSCs were detected by RT-PCR.

采用改良MTT法测定含药血清对P2代BMSCs增殖的影响；用对硝基苯磷酸法和茜素红S染色定量法对BMSCs分化为成骨细胞的标志物进行测定。

We have synthesized 4,4'-dinitro-3 4''-dimethyl triphenylamine,(1), in 84% yield in an one-step condensation process between 3,4-dimethyl aniline and 4-fluoro-nitrobenzene. After the auto-oxidation of (1) and the subsequent hydrogenation of the nitro-groups, an AB2 type triphenylamine polyimide intermediate bearing two amine groups and one acid-anhydride group each on individual phenyl ring,{AB2 PI Intermediate}, was prepared successfully. The yields of the autoxidation and the hydrogenation steps are 81% and 90% respectively.

中文摘要本研究以3，4-二甲苯胺及4-氟硝基苯为原料，经一步骤缩合反应得到产率为84 %之4，4'-二硝基-3&，4&-二甲基三苯胺(1)，由(1)经自氧化法后再以氢化法还原硝基，成功地制备出带有二胺基与一羧基的三官能基之AB2型三苯胺中间体(AB2型PI中间体)，自氧化反应与氢化法的产率各为81%及90%。

There are three different nucleophilic reagent respectively reaction with m-dinitrobenzene ramification at distint alkaline term:With the nitrobenzene 、 m-nirtobenzenesulfone sodium salt 、 2.4-dinitro chlorobenzene 、 m-dinitrobenzene for bottom thing, benzyl cyanide、 benzyl chloride、 benzyl chloropyridine、is a nucleophilic reagent reaction for under the different term proceeds a series reaction. At the same time ,discuss about the impact factor to nucleophilicity such as the number of attract electron group、 ability of attract electron and the nucleophilic substitution reaction part.

设计了三类不同的亲核试剂分别与活化芳环在不同的碱性条件下发生反应：以苄基氰、苄基氯化吡啶为亲核试剂，以硝基苯、间二硝基苯、间硝基苯磺酸钠、2，4-二硝基苄基氯为底物进行亲核取代反应；并且对亲核试剂的体积效应、溶剂效应对亲核性影响，底物上吸电子基团的数目、吸电子能力对亲电性的影响，以及亲核取代反应的发生部位受哪些因素影响进行探讨。

The engine ran on a special mixture of methyl alcohol (63%), benzene (16%), ethanol (12%), acetone (4.4%), nitrobenzene (2.2%), avgas (2%), and ether (0.4%) with MW (methanol-water) injection for charge cooling and as an anti-detonant.

特别混合物燃料为引擎运转提供动力，甲醇(63%)，苯(16%)，对氨基苯甲酸二(12%)，丙酮(4.4%)，硝基苯(2.2%)，飞机用燃料(2%)和乙醚(0.4%)，以100W充电冷却射入并作为抗爆剂。

The nano-ionic liquid containing metal complex could be an effective catalyst for oxidative carbonylation of amines to carbamates and disubstituted ureas and for synthesis of unsymmetric ureas from amines and nitrobenzene, in which turn over frequencies exceeded 10000mol/mol/h.

以该系列纳米离子液体为催化剂高效的实现了胺类化合物催化氧化羰化制备氨基甲酸酯和二取代脲（转化频率＞10000mol/mol/h）以及胺与硝基苯通过一氧化碳羰化制备不对称脲的过程。

A chiral phase transfer catalyst, N-benzyl quinine bromide, was synthesized from natural chiral compound. And 2,5-bimethyl-4-(3-nitrobenzene)-1,4-bihydrogenation pyridine-3--4-methyl formate (viz. nitrendipine) was synthesized by this chiral phase transfer catalysis, and characterized by elemental analysis, infrared spectrum,1H nuclear magnetic resornace, and X-ray single-crystal diffraction.Key words: ammonium; chiral phase transfer catalyser; crystal structure

通过对天然手性物质进行修饰合成手性相转移催化剂N-苄基溴化奎宁，并对目标分子2，5-二甲基-4-(3-硝基苯)-1，4-二氢吡啶-3-甲酸乙酯-5-甲酸甲酯进行不对称催化合成，并通过红外光谱和核磁共振氢谱对化合物进行了表征，用X射线单晶衍射法测定了该化合物的晶体结构。

Although goethite adsorbed most of Fe in solution, the adsorbed Fe had no reductive activity for nitrobenzene.

针铁矿虽然吸附的Fe量最多，但没有还原活性。

I can not make it blossom and suits me

我不能让树为我开花

When temperatures are above approximately 80 °C discolouration of the raceways or rolling elements is a frequent feature.

当温度高于 80 °C 左右时，滚道或滚动元件褪色是很常见的特征。