查询词典 nitro-pentaerythrite

The invention relates to a method for preparing arylamine compounds by the catalytic hydrogenation of arene nitro compounds in a H2O-CO2 system, wherein H2O-CO2 is taken as reaction medium, and the arylamine compounds are prepared by the selective hydrogenation of the arene nitro compounds at a low temperature(between 25 and 100 DEG C), and the catalytic process is controllable, highly efficient and green.

本发明涉及H 2 O-CO 2 体系中芳烃硝基化合物催化加氢制备芳胺类化合物的方法。以H 2 O-CO 2 为反应介质，由芳烃硝基化合物低温(25-100℃)选择性加氢制备芳胺类化合物的可控、高效、绿色催化过程。

The maximal absorption wavelength of the nitro-stilbene derivatives with an ether bond exhibited approximate 30 to 40 nm bathochromic shift compared to that of nitro-stilbene dyes with an ester bond.

相对于酯键而言，通过醚键连接的对硝基二苯乙烯类分子的最大吸收波长有一个大约30至40 nm的红移现象。

It's found that the aromatic dinitro compounds can be monoreduced to nitroanilines in high selectivity, aromatic nitro compounds and muti-cycle aromatic nitro compounds can be quantitively reduced to the corresponding amine by selenium catalyst with CO/H2O in polar aprotic solvents under atmospheric pressure using medical inorganic bases as co-catalysts.

在实验的基础上提出了对硒催化CO/H_2O还原芳香硝基化合物机理的一些粗浅认识。

First, 5-nitro-1 and 4-naphthoquinone are prepared through nitration and oxidization of naphthalene, and then through reduction of nitro into amide, diazotisation of the amide and hydro-lytic action of diazo salt, the juglone is made.

萘经过硝化、氧化生成5-硝基-1，4萘醌，然后硝基还原成氨基、氨基重氮化、重氮盐再水解，最终用新方法制得胡桃醌。

The first synthetic route uses 1,2,4-trimethoxybenzene and chloroacetonitrile in forming 2,4,5-trimethoxy-a-chlor-acetophenone under the anhydrous condition, then the intermediate condensates with papaverine forming the core pyrro[2,l-a]isoquinoline, followed by formation and lactonization to form the lactone ring. The second synthetic route uses prepared aldehyde with prepared ethyl nitroacetate by Knoevenagel condensation to obtain 2-Nitro-3-(2,4,5-tris-methoxy-phenyl)-acrylic acid ethyl ester and 2-Nitro-3-(2,4,5-tris-benzyloxy -phenyl)-acrylic acid ethyl ester etal intermediates. The lamellarin skeleton could arise from condensation of the papaverine and these intermediates by Michael reaction, the ester group is provided for subsequent lactonization. The third synthetic route uses coumarin or indan-l,3-dione derivatives and papaverine to form lamellarin under basic conditions.

第一条路线首先从1，2，4-三甲氧基苯出发与卤乙腈作用合成卤代芳酮中间体，然后与罂粟碱反应合成开链片螺素，最后经乙酰化、去保护、成内酯环得到片螺素；第二条路线由制备的芳醛和制备的硝基乙酸乙酯经缩合得到2-硝基-3-芳基丙烯酸乙酯，然后由该中间体与罂粟碱反应，在完成关环的同时也引入酯基，最后去保护、成内酯环得到片螺素；第三条路线是由香豆素或茚二酮出发，经溴代后的中间体与罂粟碱反应，得到片螺素的基本框架。

The results of batch experiments showed that the anaerobic biodegradation kinetics of 2-CNB and 4-CNB by granular sludge were follwed by first-order reaction. The nitro groups of 2-CNB and 4-CNB were more easily attacked by electron than chlorines and they were reductively biotransformed to amino groups under anaerobic conditions. The acclimated anaerobic granular sludge, which could dechlorinate 4-chloroanline to aniline, showed that it had the ability of para-dechlorinating. The anaerobic biodegradating on pathway of 2-CNB and 4-CNB were suggested as follows:AbstractIn ZVI(zero-valent iron, Fe0)-reduction system, the nitro groups of 2-CNB and 4-CNB were reductively transformed to amino groups.

2分批试验结果证明，颗粒污泥降解2-CNB和4-CNB遵循一级动力学，在厌氧条件下，CNB发生序列的硝基还原与脱氯作用，苯环上的硝基比氯原子更容易受到亲电子攻击，发生还原反应生成氨基；所获得的颗粒污泥具有对位脱氯活性，可使4-CA进一步脱氯形成苯胺。2-CNB和4-CNB厌氧降解的建议性途径为： ZVI(Zero-valentiron)对2-CNB和4-CNB的作用主要是将苯环上的硝基还原为氨基；在ZVI与污泥共还原转化体系中，ZVI对氯代硝基苯的硝基转化具有一定的促进作用，但因ZVI对中间产物的吸附特性，终产物形成速率趋慢。

Aniline and nitro-benzene in air and water can be identified by nitro and phosphor detector with large diameter capillary in quantitative analysis method.

采用大口径毛细管色谱柱和氮磷检测器建立了水及空气中苯胺及硝基苯的定量分析方法，线性范围0 ~ 80μg /L，检测下限1μg /L，重现性好，结果令人满意。

The mechanism of dioxygen oxidation of NTS to DNS in alkali solution under mild condition was inquired into. The result showed that the key step in the preparation of DNS from NTS was the formation of 4-nitro-2-sulfobenzyl anion as a result ionization of NTS in strong alkali and then oxidization to 4-nitro-2sulfobenzyl radical by activated dioxygen.

探讨了在温和条件下于碱的水溶液中氧气液相氧化4-硝基甲苯-2-磺酸制取4，4'-二硝基二苯乙烯-2，2'-二磺酸的反应机理，发现4-硝基甲苯-2-磺酸在碱作用下发生离子化生成4-硝基-2-磺酸基苄基阴离子，然后被活化的分子氧氧化成4-硝基-2-磺酸基苄基自由基是反应的关键步骤。

Synthetic nitro-musks are used in the most wide area recently and industrial crystallization is the most important process to separate solid mixtures such as perfumes. In order to develop new crystallization process to separate synthetic nitro- musks, the phase equilibrium of musk ketone, musk xylene and 1,3-dimethyl-2, 4- dinitro-5-tert- butyl benzene were studied.

合成硝基麝香是用量最大的合成麝香而工业结晶是分离香料等固体产品的重要方法，为了开发麝香体系结晶分离新工艺，本文首先研究了酮麝香、二甲苯麝香和1，3-二甲基-2，4-二硝基-5-叔丁基苯的相平衡关系。

For the first three months of pregnancy, women should try to avoid perming hair, perming agents due to the nitro-containing compounds and alkaline hydrogen peroxide; especially hair dyes containing nitro-, amino-aromatic compounds, may affect fetal development, resulting in severe fetal deficiency occurred.

对于怀孕头三个月的妇女，应尽量避免烫发染发，因烫发剂中含碱性的硝基化合物和过氧化氢；特别是染发剂含有硝基、氨基的芳香族化合物，会影响胎儿的发育，严重的导致胎儿发生缺陷症。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。