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The results of the experiments show that substituted aryl ethers that containing nitro group (-NO2) are easy to take place nucleophilic substitution in the alkaline medium and then aryl etherbond is cleaved.

实验结果表明,含-NO_2的取代芳基醚,在碱性溶液中,易发生亲核取代反应,从而使芳醚键断裂。

Experimental results show that the different substituted location and different substituted group on benzene cycle would result in the diversity of reduction properties of substituted aryl nitrobenzene. Substituted nitrobenzenes with withdrawing group will be reduced at more positive potential, while those with repelling group will be reduced at more negative potential. In addition, the reduction potential of nitro group of o-nitrobenzene shifts more negative due to the effect of space resistance.

结果表明,芳族硝基化合物在苯环上的取代基位置不同以及在相同位置上取代基的种类不同均可使各芳族硝基化合物的电还原性能发生较大差异:吸电子取代基在电还原过程中电位较正,推电子取代基的电还原电位较负:邻位取代基在反应过程中由于空间位阻效应,苯环上的硝基在电还原时电位往负方向移动。

The present work aims to investigate and develop a series of coumarin dyes containing nitro or amino benzimidazole group for the polyester and nylon fabrics and so on.

本实验主要目的乃针对聚酯、尼龙等织物制备出一系列含有硝基或胺基苯并咪唑基团之黄色萤光染料。

He Nitro Circus crew is a group of tight-knit, highly-skilled, adrenalin-addicted friends always take the action "to 11" with the hammer down.

ravis和他的疯子团队全天无休地为我们上演这些"特技",绝无冷场,只有快,更快,快完蛋。。。

The results indicate that the type and number of the substituents affect the toxicity of these compounds directly. A nitro group substitution increases the toxicity of the compounds, and on the contrary, an amido group substitution decreases their toxicity. For multi-nitrobenzenes, the toxicity of the o - or p -substituted nitrobenzene is bigger than that of the m -substituted one.

苯环上取代基的类型、数目和取代位置直接影响到标题化合物的毒性大小,强吸电子基如硝基会降低 Q -NO2和 E LUMO大小,使化合物毒性增强,且邻对位硝基取代的毒性高于间位取代;相反,给电子基团氨基的存在则会使化合物的毒性降低。

Diamino-3,5-dinitropyridine and 2,6-diamino-3,5-dinitropyridine-1-oxide was reacted with aqueous ammonia and KMnO4 under different conditions. Substitutions in the 4 position to the nitro group were obtained with high yields: 2,4,6-triamino-3,5-dinitropyridine (81.5%) and 2,4,6-triamino-3,5-dinitropyridine-1-oxide (85.4%).

以氨水为胺化剂,KMnO4为氧化剂,在不同反应条件下实现2,6-二氨基-3,5-二硝基吡啶和2,6-二氨基-3,5-二硝基吡啶-1-氧化物4位的氧化胺化反应,目标化合物2,4,6-三氨基-3,5-二硝基吡啶和2,4,6-三氨基-3,5-二硝基吡啶-1-氧化物的收率分别达到81.5%和85.4%。

The static theoretical indexs(the Mulliken bond population, the gap of the front line orbit energy and the net charge of the nitro group) and kinetic theoretical indexs illustrate pyrolysis mechanism and are correlated with experimental impact sensitivity.

以静态指标(键集居数、前线轨道能级差和硝基上净电荷)和动态理论指标阐明了热解引发机理,关联了实验撞击感度。

Two classes of specific binding sites in the polymer matrix were investigated by Scatchard analysis, which indicated that two kinds of complexes between functional monomers and templates were formed before the polymerization process. Comparing with the structure of TNT and acrylamide, one kind of complex between TNT and acrylamide was strongly charge-transfer complexing interaction by p-πcomplex between electron-rich amino group of acrylamide and electron-deficiecy-benzene ring of TNT, the other was hydrogen bonding interaction between amino group (-NH_2) of acrylamide molecule nitro group (-NO_2) of TNT.

Scatchard分析结果表明,在TNT印记聚合物微球中存在两类结合位点,这表明在聚合反应之前,TNT与功能单体丙烯酰胺分子之间存在两种不同类型的作用力而自组装成两类的模板分子-功能单体复合物,一类可能是由于富电子的丙烯酰胺和缺电子的TNT的苯环通过p-π配键而形成的电荷转移复合物,另一类可能是由于丙烯酰胺的胺基与TNT的硝基之间的氢键作用而形成的复合物。

The structural parameters of PNHAAs, such as the the maximum N-NO2 bond length, the least N-N Mulliken population, the least negative charge on the nitro group (QNO2) and OB100, were studied to predict their relative stability or sensitivity (the easiness for initiating a detonation, high sensitivity means low stability).

通过研究PNHAAs的结构参数,如N-NO2最大键长、N-NO2键的最小Mulliken集居数、-NO2所带最小负电荷、氧平衡,预测了10个标题物的相对稳定性或感度(起爆的难易程度。感度越高,化合物的稳定性越低)。

We described that the nitro group is a stronger electron withdrawing and meta activating characters than the imide group, the amino and hydroxy are both electron donating groups and had ortho, para activating characters. The methyl group might have a steric hindrance effect in this reaction. Our results indicated that methyl group at the ortho position of the amino group on the benzene ring, the steric hindrance effect became stronger.

另一方面,由产率上的结果来看,可以得知硝基为强力的拉电子基团,会减少邻位和对位胺基的电子密度比间位多;而氢氧基与胺基是供电子基团,会增加邻位和对位胺基的电子密度比间位多;甲基取代对反应则只有立体障碍的影响,而且与反应的氨基成邻位存在下影响最大。

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