查询词典 nitric anhydride

The optimum reaction conditions were: at present of acetic anhydride, a stoichiometric quantity of nitric acid, at room temperature for 40 minutes. Nitration of chlorobenzene gave a,50% yield of mononitro compounds, and an ortho-para isomer ratio 0.20 in product distribution of chlorobenzene mononitration.

结果表明：硅钨酸催化性能较好，催化剂载体以纳米二氧化硅最好，反应条件中醋酸酐用量是主要影响因素；SiW_(12)O_(40)~(4-)／纳米SiO_2催化剂具有强对位选择性：在醋酸酐存在下，氯苯与等当量的硝酸室温下反应40分钟，氯苯一硝化产物中邻／对硝基氯苯异构体的质量比达0.2，产率可达50％。

The nitration of toluene was carried out in the presence of acetic anhydride with CCl4 as solvent, 95% nitric acid as nitrating reagent, and niobic acid calcinated at 300℃ for 3 h as catalyst for 60 min at 40℃.

实验结果表明，当反应温度为40℃，反应时间为60min时，以CCl4为溶剂，以质量分数为95%的硝酸为硝化剂，在醋酐存在条件下，以经300℃焙烧3h后的铌酸作为催化剂，甲苯硝化产物中异构体的邻对比达1.26，较硝硫混酸的1.67显著降低，产物得率达99.3%。

The effects of all kinds of factors, just like calcination temperature of niobic acid catalysts, nitration reaction time, nitration reaction temperature, recovered catalyst, acetic anhydride and concentration of nitric acid were studied by gas chromatography.

研究了催化剂焙烧温度、硝化反应时间、硝化反应温度、有无醋酸存在、硝酸浓度、催化剂的重复使用等因素对甲苯硝化反应影响。

The results show high selectivity when the temperature is controlled at 50 CC , and the nitrated reaction time is 90 mm, toluene is nitrated by using 95% nitric acid as nitrating reagent at the presence of acetic anhydride, 1.0g silicotungstic acid catalyst is calcinated at 300℃ for 1.5h. The o/p (ratio of ortho to paro isomer of toluene nitration) ratio is 0.89 in product distribution of toluene nitration, lower than 1.67 using sulfonitric acid as catalyst. The yield of products is 91.6%.

结果表明，在醋酐存在条件下，以CCl4为溶剂，以质量分数为95%的硝酸为硝化剂，反应温度控制在50℃，反应60 min， 1.0g经300℃焙烧1.5h后的硅钨酸催化剂，对甲苯表现出强的区城选择性，甲苯硝化产物o/p值（甲苯硝化产物邻位和对位异构体的质量比）达0.89，较硝硫混酸的1.67显著降低，产物收率达到91.6%。

Three methods for trimellitic anhydride production including MGC,nitric aid oxidation,and liquid phase oxidation by air were compared.

比较了生产偏苯三酸酐的3种方法：芳香醛水溶液空气氧化法、硝酸氧化法和液相空气氧化法。

Methods: 2ethyl aniline was used as starting material of the synthesis and was processed by acetic anhydride acylation, strong nitric acid nitraction at low temperature, and desacyl synthesis to produce 2ethyl5nitro aniline. The product was then synthesized to 3methyl6nitro1Hindazole by using ringclosing reaction in the presence of NaNO2, and then ethylated to obtain 2,3diethyl6 nitro2Hindazole. The latter compound was then reduced by SnCl2/Hcl to get target compound 2,3diethyl6nitro2Hindazole.

以2乙基苯胺为原料经醋酐酰化、浓硝酸低温硝化及去酰基保护合成2乙基5硝基苯胺，后用亚硝酸钠关环得3甲基6硝基1H吲唑，经硫酸二甲酯甲基化得2，3二甲基6硝基2H吲唑，最后用氯化亚锡将其还原得到目标产物，通过1H NMR确定结构与目标产物一致。

Methods: 2-ethyl aniline was used as starting material of the synthesis and was processed by acetic anhydride acylation, strong nitric acid nitraction at low temperature, and desacyl synthesis to produce 2-ethyl-5-nitro aniline. The product was then synthesized to 3-methyl-6-nitro-lH-indazole by using ring-closing reaction in the presence of NaNO2, and then ethylated to obtain 2, 3-diethyl-6- nitro-2H-indazole. The latter compound was then reduced by SnC12/Hcl to get target compound 2, 3-diethyl-6-nitro-2H-indazole.

以2-乙基苯胺为原料经醋酐酰化、浓硝酸低温硝化及去酰基保护合成2-乙基－5-硝基苯胺，后用亚硝酸钠关环得3-甲基－6-硝基－1H-吲唑，经硫酸二甲酯甲基化得2，3-二甲基－6-硝基－2H-吲唑，最后用氯化亚锡将其还原得到目标产物，通过1HNMR确定结构与目标产物一致。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。