查询词典 negative catalyst

In this paper, two assemblies of special test equipments have been designed and fabricated by authors in our laboratory: namely Catalyst Molding Process Analyzer and Catalyst Mechanical Process Tester. These new skills are developed for the dynamic studies on whole mold forming process and crushing process of Fe-Cr WGHS catalyst pellet. Based on the orthogonal experimental design, the effects of some factors during the forming process of solid catalyst, such as predensification proportion, calcination time, calcination temperature and content of graphite on the mechanical strength of catalyst pellets are systematically examined, and the molding conditions have been optimized. Based on the experimental data, the relationship between catalyst density and forming pressure are educed, and the physical significances of some related parameters are described. The parameter of macro scopic elastic moduls has been suggested to character the mechanical properties of molding catalyst. The effects of molding pressure on mechanical properties of catalyst pellets are discussed, and results show that there exists a optimal molding pressure for the ideal mechanical properties: when over-high or over-low pressure is applied, the specific surface area and side crushing strength of catalyst pellets will decreased. The "rebound effect" will be undermined by the unsuitable pressure maintain process, resulting in the apparent decrease of mechanical strength of catalyst pellets.

本研究通过自行设计制造的催化剂模压成型过程分析仪（Catalyst Molding Process Analyzer， CMPA）和催化剂力学性质测试仪（Catalyst Mechanical Properties Tester， CMPT），以Fe-Cr系高温变换催化剂片剂为研究对象，对成型过程和受压破碎过程提供了全过程动态研究的新手段；本研究利用正交实验设计方法考察了固体催化剂成型过程中诸因素（包含预密致比例、煅烧时间、煅烧温度和石墨含量等）对催化剂成型体强度的影响，并对成型条件进行了优化；根据实验结果，关联确定了固体催化剂成型过程中的密度－压力关系式，并对方程中诸因子的物理意义进行了描述；提出了一种利用宏观弹性模量来表征成型催化剂的力学性质的方法；研究讨论了成型压力对催化剂成型体强度性质的影响，结果表明：对于催化剂成型体的强度和比表面性质，成型压力存在着一个最佳值，过高的成型压力会导致比表面积和侧压强度的降低；不适当的成型压力的维持时间会破坏&压力回弹&作用，造成催化剂成型体的机械强度明显降低。

The results show that the decalescence of catalyst bed affects the process of hydrogen peroxide catalytic decomposition greatly. If the catalyst bed is preheated or made up of materials with low thermal conductivity, that influence can be depressed. At the same time, the response characteristic of catalyst bed and the efficiency of catalytic decomposition can be improved. The low frequency pressure instability of catalyst bed occurs because of the coupling of catalytic decomposition and supplying. The decomposition plane pushes all the way through the catalyst bed during pressure oscillations, causing unreacted liquid hydrogen peroxide to be exhausted from the bed and leading to the appearance of liquid hydrogen peroxide channeling. Consequently, how to prevent or at least limit this channeling is the key to eliminate the pressure instability of catalyst bed. It was found that adding clapboard to the catalyst bed can depress the pressure instability efficiently.

结果表明催化剂床及催化剂的吸热对过氧化氢分解过程影响很大，对催化剂床进行预热或采用热导率低的材料制造催化剂床等措施，可以降低催化剂床壁面吸热对催化分解过程的影响，提高催化剂床的响应特性和催化分解效率；催化剂床的低频不稳定是催化分解过程与供应系统耦合产生的，催化剂床气体界面的波动过程中，液体过氧化氢穿透催化剂床形成过氧化氢液体通道，过氧化氢液体通道的产生和扩大是催化剂床不稳定的主要原因，也是消除催化剂床不稳定的关键，试验中在催化剂床内加入分流板成功地抑制了催化剂床的低频不稳定。

It was found that Pd-Co/active carbon catalyst was the optimal catalyst, and Pd-Co/γ-Al2O3 was also good, but silica and kieselguhr were not proper carriers for the object reaction, because of their stronger surface acidity, which could result in the formation of polymer, jammed the micro pores of catalyst, and then resulted in its deactivation. Addition of Bi, Ce and Cu promoters could not improve the activity of catalyst, but La and Ba promoter could enhance the activity of catalyst apparently, and the Co was the best promoter, especially Co was impregnate in advance. It was attributed to that the pre-impregnated Co may occupy the micro pores of active carbon, and cover some bad functional groups on the surface of catalyst, so that the active and selectivity of catalyst could be enhanced obviously.

研究结果表明，Pd-Co/活性炭催化剂是目标转移加氢反应的最适宜催化剂，Pd-Co/γ-Al203效果也较好，而硅胶和硅藻土由于表面酸性较强，容易造成生成聚合物而堵塞催化剂微孔、使催化剂迅速失活；此外，添加Bi、Ce、Cu等助剂时对活性并无改善作用，而添加La和Ba助剂时可使Pd的催化活性有所提高，效果最好的是Co助剂，尤其是先浸渍Co的Pd-Co/C催化剂，原因是Co占据了活性炭的微孔、覆盖了某些对目标反应不利的官能团，使其活性和选择性都有较大幅度的提高。

Generally, instrumental rumination helped to reduce negative mood, emotional-focused rumination worsened negative mood, and meaning-searching rumination increased the duration of negative mood. Moreover, in the period of severely and long-term negative mood status, instrumental rumination seemed to maintain the duration of positive mood, emotional-focused rumination still worsened negative mood, and meaning-searching rumination seemed to prolong the duration of negative mood. Besides, in the period of negative mood episode, instrumental ruminative had no effect on mood fluctuation, emotional-focused rumination deteriorated and extended negative mood, and meaning-searching rumination had harmful effect on the negative mood but still had borderline effect on the positive mood.

整体平均来说，功用性反刍有助於负向情绪的缓解、情绪焦点反刍会增强负向情绪感受、意义寻找反刍则是增加负向情绪维持的时间；若当天处在长期又严重情绪不佳日子中时，功用性反刍似有维持正向情绪的效用、情绪焦点反刍则是恶化当天的负向情绪强度、意义寻找反刍则有延长当天负向情绪时间的趋势；若连续处在长期且严重情绪不佳的日子中，功用性反刍对情绪变化并无影响、情绪焦点反刍则是延长且恶化此时期的负向情绪状态、而意义寻找反刍不但会影响负向情绪的状态，似也会有助於此时期的正向情绪状态。

The fiber length has only little influence on the basic density within the growth rings, and significant correlation at 0.01 levels was found between the basic density and the fiber length among the different rings. Only slight negative correlation was found between the basic density and the fiber width within the growth rings, but significant positive correlation at 0.01 levels was indicated between the basic density and the fiber width among the growth rings, contrary to that of fiber length. It was demonstrated that significant positive correlations at 0.01 levels between the basic density and fiber double wall thickness, fiber length to width ratio and double wall thickness to diameter ratio, significant negative correlations at 0.01 levels between the basic density and fiber diameter and diameter to width ratio, only slight negative correlation between the basic density and fiber width both in the same growth rings and among the different growth rings. No significant correlation was found between the basic density and the vessel morphological features, nor was the tissue proportion in the same growth rings. But among the different rings, it was found there was significant positive correlation at 0.01 levels between the basic density and the fiber proportion among the different rings, and significant negative correlation at 0.01 levels between the basic density and vessel-elements proportion and ray proportion, only slight negative correlation between the basic density and the parenchym proportion. Significant or no significant negative correlation was found between the basic density and the microfibril angle in the same growth rings, but significant negative correlation was found between the basic density and the microfibril angle among the different growth rings.

生长轮内纤维长度对基本密度的影响不大，而在不同生长轮间纤维长度与基本密度达极显著正相关，纤维宽度与此相反，同一生长轮内纤维宽度与基本密度极显著负相关，不同生长轮间只有微弱负相关；基本密度与纤维双壁厚、长宽比、壁腔比在生长轮内和生长轮间均呈极显著正相关，而与胞腔直径、腔径比均呈极显著负相关，仅与纤维宽度呈微弱的负相关；导管形态对基本密度的影响不显著；同一生长轮内组织比量对基本密度的影响也不显著，但不同生长轮间基本密度与纤维比量呈极显著正相关，与导管比量和木射线比量呈极显著负相关，与轴向薄壁细胞比量仅呈不显著负相关；生长轮内基本密度与微纤丝角呈显著或不显著负相关，但在生长轮间这种负相关达到极显著水平。

the 160 women judoists are tested for mental fatigue and personality tests, and the paper tries to reveal their situation of mental fatigue, personality characteristics, and the relationship between them.it is analyzed that chinese elite judoists have no severe mental fatigue; judoists' negative evaluation on emotional/physical exhaustion and sport increase significantly one week before competition than two months; among personality factors, excitability predicts the decrease of achievement and emotional/physical exhaustion reliably on negative; the stability predicts sport on negative; tension predicts emotional/physical exhaustion on positive; adaption and anxiety in dimension personality predicts in positive both in the decrease of achievement and emotional/physical exhaustion and internal extraversion does them in negative; health personality in applied dimension personality predicts in negative in the decrease of achievement, emotional/physical exhaustion and negative evaluation of sport when mental fatigue, stability and sensitivity predicts the decrease of achievement in negative; only internal extraversion in dimension personality predicts the decrease of achievement and emotional/physical exhaustion in positive.

摘 要：以160名女子柔道运动员为被试，进行运动员心理疲劳以及人格测试，并尝试揭示女子柔道运动员的心理疲劳状况、人格特征以及二者之间的关系。分析得出：我国优秀柔道运动员心理疲劳程度并不严重；运动员在临赛前一个星期较赛前二个月情绪/体力耗竭以及运动的负评价显著提高；人格因素中的兴奋性对成就感的降低以及情绪/体力耗竭两维度均有可靠的负向预测作用；稳定性对运动的负评价维度具有可靠的负向预测作用；紧张性对情绪/体力耗竭有可靠正向预测作用；次元人格中适应与焦虑对成就感的降低以及情绪/体力耗竭均有可靠正向预测作用，内外向性对成就感的降低、情绪/体力耗竭以及运动负评价都有可靠负向预测作用。应用性次元人格中健康者的人格对运动员心理疲劳的对成就感的降低、情绪/体力耗竭以及运动负评价均有可靠的负向预测作用；稳定性、敏感性对临赛前成就感的降低维度的变化有可靠的负向预测作用；次元人格中只有内外向性对临赛前成就感的降低以及情绪/体力耗竭维度的变化有可靠的正向预测作用。

The Pd-Cu/C catalysts were shown to have the face centered cubic crystal structure. This could indicate that the addition of Cu shortened the Pd-Pd distances in the crystal lattice, and therefore –HO(subscript 2ads) and O-O could be better adsorbed on the surface of the catalyst. When NaBH4 was used as the reducing agent, and the atomic ratio of Pd to Cu was 3:1, the resulting catalysts had an average particle size of 3. 4nm and showed the best catalytic performance. The electrochemical active surface are a of Pd3Cu/C was 38.9m^2/gPd and the oxidation reduction reaction activity of the Pd3Cu/C catalyst was much higher than that of the Pd/C catalyst. The electrochemical activity of the Pd3Cu/C catalyst was comparable to that of a commercial Pt/C catalyst.

结果表明：催化剂中Pd与Cu的物质的量之比与预设值相近，Pd和Cu基本被全部还原；Pd-Cu/C催化剂为面心立方结构，元素铜的加入使催化剂的Pd-Pd间距缩小，从而HO(下标 2 ads)和OO键能更好地吸附在催化剂金属表面；当采用NaBH4为还原剂，Pd与Cu物质的量比为3：1时，催化剂(Pd3Cu/C)的平均粒径为3.4 nm，催化剂的催化性能最好，电化学活性表面积EAS达到38.9平方公尺/gPd，电化学性能较Pd/C催化剂有很大提高，接近Pt/C商用催化剂。

Progress in research of catalyst deactivation in ethylbenzene dehydrogenation was reviewed.Active phase of the catalyst was briefly analyzed.Five main reasons for the catalyst deactivation were discussed,including coke deposition,loss and redistribution of potassium promoter,change in oxidation state of iron,structural transformation of the catalyst,and the catalyst poisoning.

对乙苯脱氢制苯乙烯催化剂失活的研究进展进行了综述，分析了催化剂的活性相，分别探讨了积碳、钾的流失与重新分布、Fe3+的还原、催化剂物理结构的变化和中毒等5个因素对催化剂失活的影响及其失活机理，其中，钾的流失和Fe3+的还原是造成催化剂失活的重要因素。

Based on the studies of moderate temperature isomerization catalysts carried out by domestic and foreign researchers, the paper systematically discussed the influence of a variety of factors in process of commercial preparation on the performance of catalyst which applied Pd as its metal component and HM as its acid carrier. The paper also explored the deactivated reasons of catalyst and its regenerating measure. Preparation of mordenite and scaled up production of catalyst, stability of catalyst was demonstrated in a 100kt/a commercial plant. The findings provide important basis for preparing Pd isomerization catalyst and industrial application.

本文在国内外学者对中温异构化催化剂及工艺研究的基础上，以钯作为金属组份，氢型丝光沸石作为酸性载体，系统研究了工业制备过程中各种因素对催化剂性能的影响，以及催化剂失活的原因及再生方法，进行了丝光沸石及催化剂的放大生产，并在10万吨/年工业装置上考察了催化剂的稳定性，为制备载Pd异构化催化剂及工业应用提供了重要依据。

A process for partial conversion and low-temp transform of CO in the synthetic ammonia plant where coal is used to generate gas features that the Fe-Mo catalyst for partial conversion of CO, anti-poisoning agent and Co-Mo catalyst for low-temp conversion are used and the temp of semi-water gas is controlled to 200-260 deg.C at entering anti-poisoning layer, and 150-250 deg.C at the segments of said Co-Mo catalyst layer, and lower than 300 deg.C at bed layer to prevent high-temp reversal of sulfurizing reaction and make the catalyst activity optimal. Its advantages are long service life of catalyst, low system resistance, saving energy and convenient operation.

本发明是中小合成氨厂以一种CO部分转化抗毒保护层配低温变换的工艺，涉及煤造气合成氨厂0.6～2.0MPa半水煤气变换工艺流程，该工艺用铁－钼CO部分转化催化剂、抗毒剂，配钴－钼低变催化剂，半水煤气进入部分转化抗毒层温度为200～260℃，进钴－钼低变催化剂各段温度为150～250℃，床层温度控制在300℃以内，避免高温下反硫化反应发生，保护催化剂活性处最佳状态，寿命延长、系统阻力小、节汽、节电，具有比其他变换工艺更好地节能效果，操作方便，有效生产时间长，经济效益显著等特点。

The circulation, consumption and reproduction of the trilogy have not only testified to its historical significance and literariness, but also invested it with new meanings.

该三部曲的流通、消费与再生产不仅验证了其历史意义及文学性，而切还赋予它以新的意义。

If he thought that he could buy me off, he would be wrong.

如果他认为他可以收买我，那他就大错特错了。