查询词典 n-tridecane

Using pyridine-2, 6-dicarboxylic acid as starting material, a novel ligand N^2, N^6-bis(3-methyl-pyridine-2-yl)-pyridine-2, 6-dicarboxamide was synthesized, which contained multidentate and large conjugative system.

以吡啶－2，6-二甲酸为原料，合成含有多个共轭体系多齿配体N^2，N^6-二（3-甲基吡啶）－2-取代吡啶－2，6-二甲酰胺；同时制备它与稀土离子Tb和Eu的配合物，并培养出单晶。

Attributed to the lubricant-effect of flexible LCPB,cold crystallization was observed in stereoblock PB.Bd-Ip block copolymersHTPB-b-PI,C-(PI-b-HTPBn,C-n,and PI-b-HTPB -b-PI and Bd-St block copolymersHTPB-b-PS,C-(PS-b-HTPBn,C-n, and PS-b-HTPB-b-PS containing crystallizable HTPB were well synthesized,the microstructures and properties of the copolymers were investigated in detail.

通过与异戊二烯或者苯乙烯共聚，合成了含高反式聚丁二烯的丁二烯-异戊二烯嵌段共聚物包括HTPB-b-PI，C-(PI-b-HTPBn，C-n和PI-b-HTPB-b-PI和丁二烯-苯乙烯嵌段共聚物包括HTPB-b-PS，C-(PS-b-HTPBn，C-n和PS-b-HTPB-b-PS，对嵌段共聚物的结构和性能进行了系统的研究。

Attributed to the lubricant-effect of flexible LCPB,cold crystallization was observed in stereoblock PB.Bd-Ip block copolymersHTPB-b-PI,C-(PI-b-HTPBn,C-n,and PI-b-HTPB -b-PI and Bd-St block copolymersHTPB-b-PS,C-(PS-b-HTPBn,C-n, and PS-b-HTPB-b-PS containing crystallizable HTPB were well synthesized,the microstructures and properties of the copolymers were investigated in detail.

加热器通过与异戊二烯或者苯乙烯共聚，合成了含高反式聚丁二烯的丁二烯-异戊二烯嵌段共聚物包括HTPB-b-PI，C-(PI-b-HTPBn，C-n和PI-b-HTPB-b-PI和丁二烯-苯乙烯嵌段共聚物包括HTPB-b-PS，C-(PS-b-HTPBn，C-n和PS-b-HTPB-b-PS，对嵌段共聚物的结构和性能进行了系统的研究。

In spite of this, the preparation of thiol-end functionalized PMMA was achieved by introducing a short block of polystyrene after the RAFT polymerization of MMA.Third, RAFT technique was applied to design and synthesize some well-defined poymers. Five monomers, lauryl methacrylate,(N,N-dimethylamino)ethyl methacrylate, poly methyl ether methacrylate, 4-(4\'-cyanobiphenyl-4-yloxy) butyl methacrylate and 2-ethyl methacrylate were chosen to RAFT homopolymerization or copolymerizations mediated by cumyl dithiobenzoate.

RAFT方法在具有特定结构聚合物的设计与合成上的应用，在机理研究的基础上，本论文选择五种不同结构的甲基丙烯酸酯类单体：lauryl methacrylate，(N，N-dimethylamino)ethyl methacrylate，polymethyl ether methacrylate，4-(4'-cyanobiphenyl-4-yloxy)butyl methacrylate和2-ethyl methacrylate，用CDB调控RAFT聚合的方法设计合成了一些特定结构的聚合物，详细而深入地研究了它们的均聚、共聚动力学，发现了双硫酯并非在聚合反应初期就全部转化，而是随着反应进行逐步消耗，这与理想的活性聚合体系有很大差别。

To establish a method for determination of cyclopentadiene,dimethylformamide and N-methylpyrrolidone simultaneously in isoprene by GC.

用毛细色谱法建立异戊二烯中各组分定性分析方法及环戊二烯，N-甲基吡咯烷酮，N，N-二甲基甲酰胺的测定方法。

In the second part of the thesis, we discussed a L-proline-catalyzed direct Aldol reaction between L-amino acid-derived N,N-dibenzyl -amino aldehydes 15 and acetone, cyclopentanone or hydroxyacetone, which afforded (-amino--hydroxy- or (-amino-,(-dihydroxy-ketones in good to excellent yields (up to 94%) and diastereoseletivities (up to 94.9%).

发现许多情况下，反应的产率和de值超过90%。接着，在碱性条件下，我们将L-亮氨酸衍生的N，N-二苄基--氨基醛15g与羟基丙酮反应得到的主要产物(，-二羟基-γ-氨基酮171d与次溴酸钠反应，得到了具有抗肿瘤活性的天然产物PM-94128的氨基酸片断184。

Synthesis of Antidote of N-Dichloroacetyl-2-methyl-1-oxa-4-aza-spiro-4.4-nonane BI Hong-mei, ZHANG Jin-yan, LIANG Ying, SHEN Yong (College of Arts and Sciences Heilongjiang August First Reclamation University, Daqing 163319, Heilongjiang, China) Abstract: N-Dichloroacetyl-2-methyl-1-oxa-4-aza-spiro-4.4-nonane was synthesized by one pot method with isopropanolamine, cyclopentanone and dichloroacetyl chloride. The optimum reaction conditions obtained are as follows:the proportion in moles of the above materials is 1∶1∶1.2, reaction solvent is toluene, reaction temperature is -15 to -10 ℃,reaction time is 3 h, under the optimum condition, the yield of the compound is 50.0%.

除草剂解毒剂N-二氯乙酰基-2-甲基-1-氧杂-4-氮杂-螺[4.4]壬烷的合成毕洪梅，张金艳，梁英，沈勇(黑龙江八一农垦大学文理学院，黑龙江大庆 163319)摘要：以33%的氢氧化钠水溶液为缚酸剂，异丙醇胺、环戊酮和二氯乙酰氯为原料，采用&一锅法&合成了N-二氯乙酰基-2-甲基-1-氧杂-4-氮杂-螺[4.4]壬烷，采用正交实验法得到最佳反应条件：反应原料摩尔比为1∶1∶1.2，苯作溶剂，反应的温度为-15 ℃~-10 ℃，搅拌时间为3 h，产率达到50.0%。

Firstly, dicyclopentyldichlorosilane, a reaction intermediate, was prepared under the optimal conditions of a reaction pressure range of 1.0-1.2 MPa, a n/n of 1.16, a reaction temperature range of 85-95℃, a catalyst dosage of 1.2 g, an isooctyl alcohol dosage of 2.3 g and a reaction time range of 6-7 h. The conversion of cyclopentene and the yield of DCPDCS were 96.2% and 88.9%, respectively.

首先研究了合成DCPDCS的最佳工艺条件：反应压力1.0~1.2 MPa，n/n= 1.16/1.00，反应温度85~95 C，催化剂用量1.2 g，异辛醇用量2.3 g，反应时间6~7 h，环戊烯转化率可达96%以上，DCPDCS收率可达88%以上。

After SBF solution cultivation for some days, the Ca/P coating was very easily deposited on the porous surface that was constituted of cystiform polygon made up with irregular nanometer circles like honeycomb. The energy spectrum showed that n/n atom ratio is about 1.61:1 which is very similar to that of HA and human bone. The active surface of the porous titanium after acid-alkali treatment and SBF solution condition which calcium-phosphorus ions was supersaturated induced the formation of Ca/P deposition layer.

SBF溶液培养后发现沉积层由蜂巢状多边形胞状物组成，这些胞状物是由网状纳米环无规则排列构成，能谱测定钙、磷元素原子比n／n约为1.61∶1，与HA和人骨中的钙磷原子比很接近；通过对沉积机理的分析，认为微孔钛的活性表面和SBF溶液过饱和离子浓度的环境造成了液相中钙磷盐的沉积。

First,the determinant is regarded as a function of or- der n and denoted by D;Second,the determinant is expanded by row or by column,then the relation in both of Dand subdeterminants will be examined in details to set up certain a recursion,generally speaking,it must be a homogenous or a non homogenous recursion;fi- nally the coefficients of the general solution are found out with the aid.

给出了用递归关系方法求任意 n 阶行列式的值的一般方法：首先，把已知的 n 阶行列式看作为阶数 n 的一个函数，记为 D；其次，按行或按列展开这个行列式，并仔细观察存在于余子式及 D里的关系，建立关于 D的某一递归关系，此关系总为一个齐次的或非齐次的递归关系；最后，借助于 D(0)、D(1)和D(2)等求出递归关系的通解的系数。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。