查询词典 multidentate

Considering the functions of metal-organic frameworks and the synthesis conditions, we designed and synthesized six metal-organic frameworks based on rare earths by choosing multidentate organic carboxylate ligand, H3CTC, and using mild solvent vapor conditions.

在丰富金属金属有机骨架材料合成化学和结构化学的同时，为该材料的定向合成和性质开发积累了有价值的实验事实。

Experimental results showed that the CuL complex had five-membered and six-membered rings containing two M—O,and one M—N bonds and that the ligand was of a multidentate one.

对其结构进行元素分析、摩尔电导率、紫外吸收光谱、红外吸收光谱、荧光光谱及电化学表征，结果表明，配合物同时含有2个M─O和1个M─N键形成的五元环和六元环，HL为多齿配体。

Although multidentate heteroatomic could catalyse high selectivity of α-olefin such as 1-hexene and 1-octene,these ligand usually use expensive co-catalyst such as MAO,so it hardly has broad application in α-olefin field.

但由于多齿杂原子配体一般需由价格相对昂贵的烷基铝氧烷，特别是MAO的活化才可进行高效催化反应，因此长期以来多齿型配体难以得到广泛应用。

Considering the functions of metal-organic frameworks and the synthesis conditions, we designed and synthesized six metal-organic frameworks based on rare earths by choosing multidentate organic carboxylate ligand, H3CTC, and using mild solvent vapor conditions.

在第二章中，我们利用半刚性的多齿有机羧酸配体——1，3，5-环己三酸与稀土金属元素合成了七个三维具有开放骨架结构的金属有机骨架晶体材料，由于稀土元素在光学和磁学方面的特殊性能，所获得的金属有机骨架材料不仅具有较好的吸附和储存性质，而且拥有金属中心赋予的独特的光学和磁学性能。

In the paper, the multidentate carboxylic acid ligands were used to combine with Cd, resulting in the three dimensional MOCPs single crystals—C12H16CdN2O8, with a low temperature hydrothermal synthesis method. The sample was characterized with IR spectra to affirm the organic groups in the frameworks, single-crystal X-ray diffraction to determine the crystal structure and composition of the frameworks, N2 adsorption isotherms at low temperature to measure the specific surface area and pore size distribution, and with TGA/DGA analysis to scale the thermal stability. Furthermore, the dissolution property and the photocatalytic activity of MOCPs under the ultraviolet ray condition were explored.

本文用低温水热合成法，用多齿羧酸配体异烟酸和Cd配位合成出[Cd(C6H4O2N)2(H2O)4]∞三维晶体并进行了表征：采用红外光谱法确认骨架中的有机官能团；用单晶X射线衍射分析法测定MOCPs的晶体结构，并确定其骨架的组成；通过低温氮气吸附等温线测定了其比表面积和孔径分布；以热重分析和差热分析测定材料骨架的热稳定性；测定了晶体的溶解性能；最后以亚甲基蓝为目标降解物，对[Cd(C6H4O2N)2(H2O)4]∞的光催化活性及亚甲基蓝的氧化动力学进行了探索(来源：A2444BC论文网www.abclunwen.com)。

E., monodentate,bidentate and complicated multidentate chain-structured or web-structured CIPs.

利用曲线拟合技术对其光谱的ν1-SO峰进行分峰，获得了不同湿度下ZnSO4微液滴中各组分的量化信息：高湿度时，液滴中主要包含自由的水合SO；随着湿度降低，自由SO逐渐向单齿、双齿接触离子对转化，并在湿度为66%和34%时分别达到其最大值；继续降低湿度，复杂的链状或网状接触离子对逐渐成为液滴中的主要成分。

Using pyridine-2, 6-dicarboxylic acid as starting material, a novel ligand N2,N6-bis(3-methyl- pyridine-2-yl)-pyridine-2, 6-dicarboxamide was synthesized,which contained multidentate and large conjugative system.

摘 要：以吡啶-2， 6-二甲酸为原料，合成含有多个共轭体系多齿配体N2，N6-二(3-甲基吡啶)-2-取代吡啶-2， 6-二甲酰胺；同时制备它与稀土离子Tb和Eu的配合物，并培养出单晶。

ATRP initiation systems consist of organic chloride initiators (RCl, RBr or aryl sulfonyl chloride, etc.), transition-metal catalysts in lower oxidation state Cu(I, Fe, Ru, Ni, etc. and organic electronic-donating ligands (2,2'-bipyridine―bipy or bpy, PPh3, multidentate ligand compound 1,1,4,7,7-pentamethyldiethylenetriamine, etc.).

普通ATRP引发体系包括引发剂主要为氯或溴化物，芳基磺酰氯；低价过渡金属卤化物如Cu， Fe，Ru，Ni等；有机配体如2，2'-联吡啶，PPh3，脂肪族多元胺等。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。