查询词典 monomer

The preparation method comprises monomer synthesis and polymer synthesis. The polymer synthesis is that cyclopentadienyl sodium monomer is added into metallic cobalt complex-triphenyl phosphorus cobalt chloride under strict oxygen-free and water-free conditions, and then double inner alkyne or outer alkyne conjugate monomer is added in, and after reaction, the precipitation, filtering, abstersion and vacuum-drying are carried out, the large molecules polymer containing cyclopentadienyl cobaltocenium organometallic cobalt is obtained.

制备方法，包括单体合成和聚合物的合成，聚合物的合成是在严格无氧无水条件下，在金属钴配合物三-三苯基磷氯化钴，加入环戊二烯钠单体，随后加入双内炔或双外炔共轭单体，反应后沉淀，过滤，洗涤，真空干燥，得到含环戊二烯茂钴有机金属钴的大分子聚合物。

EPDM (ethylene propylene diene monomer) rubber development improved rapidly in recent years, applied widespread in the industry.

中文摘要 EPDM (ethylene propylene diene monomer)橡胶近年来由於发展迅速，进而广泛的被工业界所应用。

The copolymerization compound comprises based on a proportioning ratio by weight: 25-99 percent ethylene aromatic series monomer; 0-30 percent olefinic undersaturation nitrile monomer; 1-50 percent olefinic dibasic acid ramification monomer.

这种共聚组合物按重量百分比包含：25至99％的乙烯基芳香族单体；0至30％的烯属不饱和腈类单体；1至50％的烯属二元酸衍生物单体。

The effects of different factors on the laser-induced graft polymerization on the PET surface were analyzed, and the mechanisms were discussed. The factors were: 1 Monomers with smaller molecules resulted in better modification than polymeric monomers. Acrylamide monomer was chosen as hydrophilic modifier finally; 2 Higher concentration of the monomer solution favored the graft reaction; 3 With the increasing laser fluence, the surface hydrophilicity of PET films increased at first, then decreased. More laser pulses led to a more hydrophilic surface; 4 Benzophenone as a photosensitizer hindered the graft polymerization; 5 The homopolymer retardant of ammonium iron sulfate hexahydrate in a proper concentration retarded the formation of homopolymers and promotes the graft copolymerization; 6 The solvent of monomer solution also affected the graft reaction. Different solvents functioned in different ways. Ethanol can promote the graft reaction because of the activity of hydrogen in its structure; 7 pH value of the monomer solution affects the polymerization rate, and a lower pH value was favorable to the graft reaction.

这些影响因素的作用分别为：1小分子单体的表面改性效果好，确定以丙烯酰胺为亲水性改性单体；2较高的单体溶液浓度有利于接枝反应；3激光能量密度增大，薄膜表面亲水性先显著增强，后又减弱；激光脉冲次数越多，改性后表面亲水性越强；4光敏剂BP对PET表面接枝聚合反应有阻碍作用；5适当浓度的均聚物抑制剂六水合硫酸铁铵能减少单体均聚物的生成，促进接枝聚合；6单体溶液的溶剂也影响接枝聚合的反应进程，不同溶剂的影响作用原理不同，含较活泼氢的乙醇能促进接枝反应；7溶液pH值影响单体聚合速率，pH值较低有利于接枝反应。

According to the weight percent, the copolymer composition comprises: 25 percent to 99 percent of the vinyl aromatic monomer; 0 percent to 30 percent of the en-unsaturated nitrile monomer; 1 percent to 50 percent ene dicarboxylic acid derivative monomer.

这种共聚组合物按重量百分比包含：25至99％的乙烯基芳香族单体；0至30％的烯属不饱和腈类单体；1至50％的烯属二元酸衍生物单体。

The main contribution of this paper is summarized as follow:1 Copolymer acrylate resin including hydroxyl, carboxylic and amina(-NH_2) is a new type of antifogging system and ahydrophi- lic antifogging constituents which is not found before.2 Water-soluble acrylate resin hydrophilic antifogging coating material is a new-type environmental protection material which takes ethanol as solvent and whose pastiness is adjusted by deionized water.3 The quality rate of accessory soft monomer ethyl acrylate and accessory hard monomer butyl methacrylate is 6 to 4, the quality rate of functional monomers in all monomers is 20 percent, the quality rate of MAA in the functional monomers is 22 percent, the quality rate of β-hydroxyl ethyl acrylate in the functional monomers is 8 to 10 percent and the remainder of functional monomer is acrylic acid.4 Cross-linking agent methylol acrylamide belongs to self-cross-linking system.

本文的主要贡献概述如下： 1 含有亲水羧基、羟基和氨基(-NH_2)丙烯酸共聚树脂是一种新型高效的防雾体系，用的亲水防雾组分是前所未有的。 2 以乙醇为溶剂制得水溶性丙烯酸树脂具有很好的水溶性能和防雾性能，只需加入去离子水就可以调节它的粘度，是一种新型的环保型防雾材料。 3 辅助软单体丙烯酸乙酯和辅助硬单体甲基丙烯酸甲酯最佳配比为质量比6∶4；官能单体占单体总量的20%，甲基丙烯酸占官能单体总量10～15%，甲基丙烯酸β-羟乙酯占官能单体总量的8～10%，剩下的为丙烯酸。

In this thesis, monomer with unsaturated double bond was firstly synthesized byreacting acryloyl chloride with bifunctional monomer. Such synthesized monomer ormonomer with initial unsaturated double bond was used to prepare linear polymericmaterials by free radical polymerization. A series of new degradable space polymerswith acylamino bond were subsequently synthesized using diisocyanate as thecross-linker.

本文首先通过丙烯酰氯和双官能团单体反应引入不饱和双键，或者直接使用具有不饱和双键的单体，通过自由基聚合得到含有活泼羟基或氨基的线型高分子聚合物，再用二异氰酸酯作为交联剂交联，从而合成了一系列基于酰胺键的新型可降解高分子体型聚合物。

The resin composition for a platable substrate of the present invention comprises 100 parts by weight of a resin composition comprising 10 to 60% by weight of a graft copolymer prepared by graft polymerization of a rubbery polymer (A1) and a monomer component (A2) containing an aromatic alkenyl compound monomer unit and a vinyl cyanide compound monomer unit and 40 to 90% by weight of the other polymer provided that the total amount of the components (A and is 100% by weight, and 5 to 40 parts by weight of a phosphate ester flame retardant having a molecular weight of more than 326 or 2 to 40 parts by weight of a red phosphorus flame retardant.

本发明涉及一种镀覆基材用树脂组合物，其特征在于，该树脂组合物是在100质量份的树脂组合物中，混合5～40质量份的分子量超过326的磷酸酯系阻燃剂或2～40质量份的红磷系阻燃剂形成的物质，其中树脂组合物由10～60质量％的接枝共聚物和40～90质量％的其它聚合物组成(A+＝100重量％，接枝共聚物通过在橡胶质聚合物(A1)上接枝聚合含有芳香族烯烃化合物单体单元和氰化乙烯基化合物单体单元的单体成分(A2)得到。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

The present invention discloses a polycarboxylic acid copolymer which is obtained by copolymerization of monomer components comprising a polyalkyleneimine unsaturated monomer (A2) and an unsaturated carboxylic acid monomer, the polyalkylene glycol unsaturated monomer (A2) having an oxyalkylene group bonded to a polyhydric alcohol residue, and the monomer component containing an unsaturated monocarboxylic acid monomer.

公开了一种多元羧酸共聚物，它是通过单体组分共聚制得的，所述单体组分包括聚二醇不饱和单体(A2)和不饱和一元羧酸单体，所述聚二醇不饱和单体(A2)具有使氧化烯基结合到多元醇残基上的结构，所述多元醇残基平均每个分子具有不少于3个羟基。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。