查询词典 micelles

At the same temperature, k〓 in the reversed micelles was always less than k＇〓 in the buffer. According to the thermodynamic analysis for inactivation of penicillin amidase in the reversed micelles, the free energy of activation was increased by 2. 71%, while the entropies and enthalpies of activation were decreased, corresponding to 63. 9% and 76. 9% of that in pure buffer respectively.

由热力学分析可知，青霉素酰化酶在AOT/异辛烷反胶团中的热失活过程，与水溶液中相比，活化自由能△G〓增加了2.71％，而活化熵△S〓和活化焓△H〓分别减小为原来的63.9％、76.9％，从而使酶热稳定性平均提高了2～4倍。

The results show that the decay of retinol and retinyl acetate are much faster in anionic micelles than that in cationic micelles and neutral micelles(TX-100), which indicate that the decay is carried out by the protonation of retinol or retinyl acetate first, then one molecular water or acetic acid is lost to produce the carbonium ion, which release the proton followed to generate the anhydroretinol.

数据显示，维生素A及其乙酸酯在阴离子胶束溶液SDS中的衰变速度要远大于在阳离子胶束溶液CTAB和中性胶束溶液TX-100中的衰变速度。

After the click reaction of the SCL micelles and azide-terminus PNIPAM homopolymer, the novel PNIPAM-functionalized SCL micelles with pH-responsive cores and outer thermosensitive coronas were prepared, which was investigated act as excellent candidate of nanosized drug delivery vehicles. Finally, two types of novel shell cross-linked micelles in aqueous solution were prepared from these remarkable PMEO_2MA-b-P(DMA-co-QDMA)-b-PDEA triblock copolymers by cross-linking the inner P(DMA-co-QDMA) shell of micelles upon the addition of diazide tetra derivative in the presence of copper catalyst using click chemistry.

另外，还可以使用溴丙炔对ATRP聚合出的PMEO_2MA-b-PDMA-b-PDEA三嵌段的中间PDMA嵌段进行部分季胺化，这样可以利用两端叠氮化的四甘醇来交联由PMEO_2MA-b-PDMA-b-PDEA在不同条件下形成的两种分别以PMEO_2MA或PDEA为核的胶束，从而实现了从同一个聚合物直接在水溶液中得到两种内核不同敏感的壳交联胶束。

Finally, two types of novel shell cross-linked micelles in aqueous solution were prepared from these remarkable PMEO_2MA-b-P(DMA-co-QDMA)-b-PDEA triblock copolymers by cross-linking the inner P(DMA-co-QDMA) shell of micelles upon the addition of diazide tetra derivative in the presence of copper catalyst using click chemistry.

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The diagrams indicate that microemulsions can only be formed with a certain Combination of SDS and n-bulanol. A stretch of microemulsion domain changing continuously from direct micelles to bicontinuous structures and to reverse micelles exists when the surfactant to cosurfactant ratio is comparatively low, while the direct micelle area is separated from the reverse micelle area by a mesomorphic medium when the surfactant to cosurfactant ratio is comparatively high.

结果表明：只有当SDS与正丁醇配比在一定范围内才形成微乳状液；当SDS含量较低时，存在由正胶束经过双连续结构到逆胶束的大片微乳状液区；当SDS含量较高时，正胶束和逆胶束微乳状液之间被液晶相所分割。

When the solution was heated to the temperature above the LCST, hydrogen-bonding interactions between the water molecules and the PEGMA segments on the surface of the micelles were destroyed and the multimolecular micelles joined together to form the even larger aggregates driven by the increasing intermicellar hydrophobic interaction.

通过UV-Vis和DLS研究发现，温度升至LCST时，胶束表面的亲水基团与水分子间的氢键作用被破坏，疏水基团相互作用加强，大胶束与大胶束缔合形成更大的聚集体，发生温度响应行为。

The antioxidative action may involve trapping the initiating radicals generated by AAPH in the bulk water phase, trapping the initiating radicals generated by DBHN in the surface of the micelles, inhibiting the propagating lipid peroxyl radicals on the surface of micelles and regenerating α-tocopherol by reducing the α-tocopheroxyl radical.

茶多酚的抗氧化机理可能涉及到在水相中捕获链引发自由基R00·和在胶束表面捕获链引发自由基t-BuO以及在胶束表面捕获链增长自由基LOO和在胶束表面与α-生育酚自由基反应从而再生α-生育酚。

The knowledge obtained here as well as the new morphologies identified provide useful information for future rational design and synthesis of novel multicompartment micelles.5. A superstrong segregation regime theory model for core-corona micelles and core-shell-corona micelles is developed.

这些信息对将来合理设计和合成新型多隔段胶束提供了指导。5、建立了用于描述核-冠胶束和核-壳-冠状胶束的超强分凝形式理论模型。

In this study, nonionic surfactant sorbitan trioleate (Span 85) was modified with Cibacron Blue F-3GA to become an affinity surfactant (CB-Span 85) and to form affinity-based reversed micelles while dissolved in hexane. Since the CB molecule possesses a specific conformation that mimics nicotinamide adenine dinucleotide, it can bind strongly and specifically to a wide range of nucleotide-dependent enzymes such as dehydrogenases and kinases. Moreover, high protein transfer efficiency in the reverse micelles can be easily achieved by controlling the ionic strength of the aqueous phase.

本实验使用非离子型界面活性剂Span 85与蓝色染料分子Cibacron Blue F-3GA结合，形成具有亲和性的界面活性剂 CB-Span 85，由於CB染料分子具有与NAD+相似的结构，可与含核苷酸部位的蛋白质具有亲和力，将CB-Span 85溶於有机溶剂形成反微胞相，可有效的提高反微胞的选择率，可以只控制离子强度来调节蛋白质进出反微胞的效率。

The sizes of the self-assembly micelles of the amphiphilic block copolymers and the effects werestudied by dynamic light scattering and UV-visible spectrophotometer. The micelle sizes werelargely influenced bythe hydrophobic chain content in the copolymer, the properties of the solvent and the copolymer concentration in the organic phase. The morphology of the micelles was investigated by transmission electron microscopy. Theresults showed that the micelles appeared spheres with inner core and outer shell. The critical association concentrations were determined by pyrene monomer fluorescence probe technology. The degradability of copolymer was studied by the loss of the intrinsic viscosity in the degradation process. The results indicated that the degradation rate of PECL was slower thanthat of PELLA and PEDLLA. The stability of the copolymer micelle dispersion was examined by measuring the critical flocculation concentration, which gradually decreased with increasing the content of thehydrophobic chain in the copolymer. The rheological results showed thatthe viscosity ofthe micelle dispersion with higher content of PEG segments was firstly decreased and then increased with the increasingthe temperature. Otherwise, the variation of viscosity was irregular. The viscosity of the micelle dispersion increased with the increase of the electrolyte (Na 2SO 4) concentrations. Polymer micelles paclitaxel was prepared by self-emulsification/solvent evaporation method and solid dispersion technique with amphiphilic block polymers as the carrier material.

运用动态光散射和紫外分光光度计研究了两亲性嵌段共聚物自组装胶束的粒径及其影响因素，结果表明，自组装胶束的形成机理受制备方式的控制，胶束的粒径随着共聚物相对分子质量或疏水嵌段相对分子质量和有机相中共聚物浓度的增大而增大，随着有机溶剂的水溶性的增强而减小；采用透射电镜观察胶束的形态结构，发现胶束呈具有核壳结构的均匀球形；采用芘荧光探针法测两亲性嵌段共聚物的临界聚集浓度；通过降解过程中共聚物特性粘度的变化研究两亲性共聚物的降解性能，发现与PELLA和PEDLLA的相比，PECL 降解速率较慢；随着共聚物中疏水嵌段含量的增大，纳米分散液的稳定性逐渐下降；PEG含量高的PEDLLA纳米分散液随着温度的升高，纳米分散液的粘度先下降然后增大，反之，没有规律性，且随着电解质Na 2SO 4浓度的增大，体系粘度增大。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失