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College of Environment and Energy Engineering, Beijing Polytechnic University, Beijing 100022, China )Abstract The phosphoryl N → O migration reaction and ester exchange reaction on phosphorus of phosphoserine with methyl alcohol involving hexa-coordinate phosphorus intermediate 3 had been studied by MNDO method.

用MNDO方法对磷酰化丝氨酸仿生化反应机理中所形成的六配位磷中间体(3)可能的3个异构体的结构及其反应活性进行了研究。

The phosphoryl N→O migration reaction and ester exchange reaction on phosphorus of phosphoserine with methyl alcohol involving hexa-coordinate phosphorus intermediate 3 had been studied by MNDO method. The three isomers structures of 3 were discussed in detail based on the calculation results.

谭波用MNDO方法对磷酰化丝氨酸仿生化反应机理中所形成的六配位磷中间体(3)可能的3个异构体的结构及其反应活性进行了研究。

Aqueous solution of methyl orange was used to explore the photocomposition efficiency of TiO〓 nanowire arrays.

光催化性能测试表明:氧化钛纳米丝阵列的光催化性能优于氧化钛纳米膜的。

By comparing the data of the photopolymerization of methyl methaerylate at 30℃ with those of benzoyl peroxide initiated polymerization at 60℃,it clearly shows that primary radical termination is more important at lower temperature than at higher temperature.

比较甲基丙烯酸甲酯在30℃的光引发聚合和在60℃的过氧化苯甲酰引发聚合的数据,可以看出,初级自由基的终止效应在低温时更为重要。

The response to single compound: To both females and males, the compounds that elicit larger responses of adults are benzaldehyde, benzene acetaldehyde, hexanol,β-phenyl ethyl alcohol, benzyl alcohol, cyclohexanol and eugenol. Phytol, 2-methyl-cyclohexanone and β-caryophyllene reveal to have weaker activity.

对单一化合物的反应:两种昆虫,不论是雌蛾还是雄蛾,能引起较强EAG反应的化合物均为苯甲醛、苯乙醛、正己醇、β-苯乙醇、苯甲醇、环己醇和丁香酚,植醇、2-甲基环己烷和β-石竹烯仅能引起微弱的EAG反应。

Thereinto, the content of eucalyptus oil was the most with 27.20%, the next was Terpinen-4-OL (21.27%), N-methyl-laurotetanine (6.32%), Hepladecanoic acid (4.33%), Phytol (3.53%), Ether linoleic acid (3.45%), 2,6-dimethyl-2,6-octadiene (2.96%) and so on.

其中,含量最高的是桉油(27.20%),其次是松油烯-4-醇(21.27%)、N甲基山鸡椒痉挛碱(6.32%)、十七烷酸(4.33%)、叶绿醇(3.53%)、乙醚基亚油酸(3.45%)、2,6-二甲基-2,6-辛二烯(2.96%)等。

We have exchanged the methyl group of the piperazine ring at 3-position of rifapicin to other new groups.

我们主要是将连接在利福平3位上的哌嗪环末端氮上的甲基换成其它基团,这些新连接的基团都与一些最近报道的抗菌活性比较强的新化合物的结构中所包含的基团相似或相同,并测试了这些化合物抗结核杆菌的活性,结果显示了他们大部分都保持了与利福平相当的抗菌活性,其中衍生物81的抗菌活性是利福平的十倍,具有进一步开发的价值。

The title compound C_(27)H_(23)FN_(4)O_(2)C_(2H_(5)OH was obtained by the reaction of 1-phenyl-3-methyl-5-pyrazolone with 2-fluorobenzaldehyde in ethanol in the presence of piperidine under microwave irradiation and recrystallization from ethanol.

标题化合物C27H23FN4O2(C2H5OH)是由2分子1-苯基-3-甲基-5-吡唑啉酮和1分子2-苯甲醛微波辐射4 m in,用乙醇重结晶得到。

The other for: safrole, sassafras oil, safrole different 82 yuan / kg; 1 - phenyl -2 - propanone 2,500 yuan / kg; 3.4 dioxane methylene diphenyl -2 - propanone 7200 yuan / ton; Piperonal 1,000 yuan / kg; N-acetyl-o-amino benzoic acid 11500 yuan / ton; anthranilic acid 15,500 yuan / ton; Phenylacetate 15,000 yuan / ton; acetic anhydride 9900 yuan / ton; trichloromethane 4100 yuan / ton ; anhydrous ether 8500 yuan / ton; piperidine 58000 yuan / ton; methyl ethyl ketone 10,000 won / ton; sulfate 1,200 yuan / ton; hydrochloride 400 yuan / ton; ethanol 4200 yuan / ton.

另供:黄樟素、黄樟油、异黄樟素82元/公斤;1-苯基-2-丙酮2500元/公斤;3.4 亚甲基二氧苯基-2-丙酮7200元/吨;胡椒醛1000元/公斤;N-乙酰邻氨基苯酸11500元/吨;邻氨基苯甲酸15500元/吨;苯乙酸15000元/吨;醋酸酐9900元/吨;三氯甲烷4100元/吨;无水乙醚8500元/吨;哌啶58000元/吨;甲基乙基酮10000元/吨;硫酸1200元/吨;盐酸400元/吨;无水乙醇4200元/吨。

In the second part of this dissertation, we studied the stereoselectivity of the Pictet-Spengler reaction of D-tryptophan methyl ester with piperonal and the synthesis of tadalafil.

在本论文的第二部分,我们研究了D-色氨酸甲酯和胡椒醛发生Pictet-Spengler反应的立体选择性和他达那非的合成。

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Finally, according to market conditions and market products this article paper analyzes the trends in the development of camera technology, and designs a color night vision camera.

最后根据市场情况和市面上产品的情况分析了摄像机技术的发展趋势,并设计了一款彩色夜视摄像机。

Only person height weeds and the fierce looks stone idles were there.

只有半人深的荒草和龇牙咧嘴的神像。

This dramatic range, steeper than the Himalayas, is the upturned rim of the eastern edge of Tibet, a plateau that has risen to 5 km in response to the slow but un stoppable collision of India with Asia that began about 55 million years ago and which continues unabated today.

这一引人注目的地域范围,比喜马拉雅山更加陡峭,是处于西藏东部边缘的朝上翻的边框地带。响应启始于约5500万年前的、缓慢的但却不可阻挡的印度与亚洲地壳板块碰撞,高原已上升至五千米,这种碰撞持续至今,毫无衰退。