查询词典 methyl-phenoxide

Parameters based on chemical shift indicate that methyl is a substituent with electron-withdrawing inductive effect and poor electron-donating conjugative effect. Perhaps its conjugative effect is on critical point. Methyl is electron-withdrawing for benzene relative to H. Otherwise, methyl has strong p-position and weak o-position orientation effect.

化学位移值表示的诱导效应参数表明甲基具有吸电子诱导效应，经校正后的化学位移值表示的共轭效应参数表明甲基具有微弱的给电子共轭效应，甚至其共轭效应有可能正处于给电子和吸电子的临界状态，总之相对于氢原子，甲基具有吸电子效应。

Dibutyltin maleate,dioctyltin maleate,N-phenyl maleimide, N-(p-chlorophenyl) maleimide,N-(p-nitrophenyl) maleimide with unsaturated groups were synthesized using dibutyltin oxide,dioctyltin oxide,maleic anhydride, aniline,p-chloroaniline,p-nitroaniline as raw materials,respectively.Then dibutyltin male,ate/styrene bipolymer,dibutyltin maleate/styrene/methyl acrylate terpolymer,dibutyltin maleate/styrene/N-phenyl maleimide terpolymer ,dibutyltin maleate/styrene/N-(p-chlorophenyl) maleimide terpolymer ,dibutyltin maleate/styrene/N-(p-nitrophenyl) maleimide terpolymer ,dioctyltin maleate/styrene biopolymer,dioctyltin maleate/styrene/methyl acrylate terpolymer,dioctyltin maleate/styrene/ N-phenyl maleimide terpolymer,dioctyltin maleate/styrene/ N-(p-ehlorophenyl) maleimide terpolymer[P(DOTM/St/NC1PMI)],dioctyltin maleate/styrene/N-(p-nitrophenyl) maleimide terpolymerwere synthesized using DBTO,DOTO,PMI,N-p-ClPMI,N-p-NOPMI,styrene and methyl acrylate as monomers,respectively.

再以DBTO，DOTO，PMI，N-p-ClPMI，N-p-NOPMI，苯乙烯，丙烯酸甲酯等为单体，合成了马来酸二丁基锡/苯乙烯二元共聚物{P}，马来酸二丁基锡/苯乙烯/丙烯酸甲酯三元共聚物{P}，马来酸二丁基锡/苯乙烯/N-苯基马来酰亚胺三元共聚物{P(DBTM/St/NPMI)}，马来酸二丁基锡/苯乙烯/N-对氯苯基马来酰亚胺三元共聚物{P(DBTM/St/NClPMI)}，马来酸二丁基锡/苯乙烯/N-对硝基苯基马来酰亚胺三元共聚物{P(DBTM/St/NNOPMI)}，马来酸二辛基锡/苯乙烯二元共聚物{P}，马来酸二辛基锡/苯乙烯/丙烯酸甲酯三元共聚物{P}，马来酸二辛基锡/苯乙烯/N-苯基马来酰亚胺三元共聚物{P(DOTM/St/NPMI)}，马来酸二辛基锡/苯乙烯/N-对氯苯基马来酰亚胺三元共聚物{P(DOTM/St/NClPMI)}，马来酸二辛基锡/苯乙烯/N-对硝基苯基马来酰亚胺三元共聚物{P(DOTM/St/NNOPMI)}。

The main components were myristic acid (19.37%), palmitic acid methyl ester(7.56%), lascorbic acid 2,6dihexadecanoate(6.27%), 8,11octadecadienoicacid methyl ester(5.22%), heptadecane(4.82%), lauryl ethoxylate(2.98%), 2isopropyl5methyl1heptanol (2.62%), tetracosanoic acid methyl ester(2.12%),2ethyl2methyltridecanol (2.08%), et al.

其化学成分主要为肉豆蔻酸(19.37%)，棕榈酸甲酯(7.56%)，2，6十六烷基1抗坏血酸酯(6.27%)，8，11十八碳二烯酸甲酯（5.22%），十七烷（4.82%），十二烷基乙氧基醚（2.98%），2异丙基5甲基1庚醇(2.62%)，二十四烷酸甲酯（2.12%），2乙基2甲基十三醇（2.08%）等。

N-(6-methyl-2-pyridine)-amino-methylene-diethyl malonate was produced by condensation reaction of 2-amino-6-methyl pyridine with ethoxymethylene diethyl malonate under optimal conditions that n(2-amino-6-methyl pyridine)∶n(ethoxymethylene diethyl malonate) is 1∶1.3, reacting time 45 min and temperature 130 ℃,the yield of this reaction was 96%,which was 6% higher than that of literature.

在250℃的反应温度下，分别以二苯醚、石蜡油和邻苯二甲酸二乙酯为热载体进行成环反应，得到4-氧-7-甲基-1，8-萘啶-3-羧酸乙酯的收率分别为88.6%、56.3%和61.2%，确定二苯醚为最佳热载体，并发现反应温度对产率的影响最大，原料配比次之，反应时间基本无影响。

Cycloserine was produced using L-serine methyl ester hydrochloride as raw material. L-serine methyl ester hydrochloride was chloridized with phosphorus pentachloride to afford 2-amino-3-chloride propanic acid methyl ester hydrochloride, which was cyclized with hydroxylamine in the presence of alkali to give cycloserine.

以L-丝氨酸甲酯盐酸盐为原料制备了环丝氨酸。L-丝氨酸甲酯盐酸盐和五氯化磷在氯仿溶剂中进行氯代反应生成2-氨基-3-氯丙氨酸甲酯盐酸盐，后者和羟胺在碱性溶液中发生环合反应得到环丝氨酸。

Chiral 3 methy 1,4 butanediol and its derivatives are the important intermediate of synthesis of chiral smectic liquid crystal polyesters and chiral natrual products with biological activity. In the paper, a new efficient route of 3 methyl 1,4 butanediol and its two derivatives, 2 methyl 4 tetrapyranyloxy 1 butanol and 2 methyl 4 tetrapyranylbutanal, was described, and the target products were synthesized by employing asymmetric hydroboration oxidation improved.

手性2－甲基－1，4－丁二醇及其衍生物是合成各种手性近晶型液晶材料以及手性天然生物活性物质的重要中间体，以3－甲基－3－丁烯－1－醇为原料利用改进的不对称硼氢化－氧化反应，成功地合成了－2－甲基－1，4－丁二醇以及其2种手性衍生物：－2－甲基－4－四氢吡喃氧基－1－醇和－2－甲基－4－四氢吡喃氧基丁醛。

Results The mixing, loading and storing processes of the construction, might generate lots of occupational hazards, including toluene, dimethylbenzene, trimethylbenzene, isopropanol, butyl alcohol, propanol, methyl methacrylate, butyl acetate, methyl isobutyl ketone, methyl ethyl ketone, acetic ether, nitro-cotton, n-hexane, n-heptane, carbinol, ethanol, ethyl propionate, diisobutyl ketone, glycol ether, isoamyl acetate, 2,4-toluene diisocyanate, isophorone, noise, power frequency electric fields.

结果 该项目在混兑生产和装卸、仓储过程中，可能产生的职业病危害因素主要有甲苯、二甲苯、三甲苯、异丙醇、丁醇、丙醇、甲基丙烯酸甲酯、乙酸丁酯、甲基异丁基甲酮、丁酮、乙酸乙酯、硝化棉、正己烷、正庚烷、甲醇、乙醇、乙酸丙酯、二异丁基甲酮、乙二醇乙醚、乙酸异戊酯、2，4甲苯二异氰酸酯、异佛尔酮、噪声、工频电场。

The source and formation mechanism of methyl carbamate in liquor covered the followings:①methyl carbamate formed by spontaneous chemical reaction of carbamide and methanol in fermented and undistilled alcoholic beverage;②in alcohol produced by grains as raw materials, cyanide precursor of grains formed into cyanate during fermentation and distillation, which further developed into methyl carbamate in alcohol.

白酒中氨基甲酸甲酯的来源和形成机理主要有：①在已发酵的和未蒸馏的酒精饮料中尿素和甲醇自发的化学反应生成氨基甲酸甲酯；②以谷物为原料生产的酒精中，氨基甲酸甲酯形成的途径来源于谷物的氰化物前体在发酵和蒸馏时反应形成的氰酸盐，氰酸盐在酒精中转化为氨基甲酸甲酯。

In solvent and under the action of certain catalyst, anilino methyl siloxane is reacted to obtain solid cage anilino methyl sesquisiloxane octamer acid salt; and through filtering, washing, precipitation and reaction with amine desalting agent, cage anilino methyl sesquisiloxane octamer is finally prepared.

本专利提供了一种笼型八聚苯胺甲基倍半硅氧烷的制备方法，苯胺甲基硅氧烷在一定溶剂和催化剂作用下反应，过滤得到笼型八聚苯胺甲基倍半硅氧烷酸式盐固体，经过洗涤、沉淀，再与胺类脱盐剂作用，最终制得笼型八聚苯胺甲基倍半硅氧烷。

Disposal on methyl orange solution by two kinds of nanometer sized iron oxyhydroxides:α-FeOOH and β-FeOOH in visible light showed that methyl orange solution decolored by 90% by FeOOH/H2O2 system.And phenyl in methyl orange molec...

用2种纳米氧氢氧化铁针铁矿，正方纤铁矿处理偶氮染料分子甲基橙溶液，在自然光下，FeOOH/H2O2体系能使甲基橙溶液脱色率达90%，并且能将甲基橙分子中的苯环部分打开。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。