查询词典 methyl-glyoxal

Firstly, 3-ethylthiobutanal was prepared from crotonaldehyde reacting with ethanehiol in triethylamine with high yield. Secondly, methyl acetoacetate was converted to 6-ethylthiohept-3-en-2-one by three steps via hydrolysis, condensation with 3-ethyltio-butanal and dehydration, then 6-ethylthiohept-3-en-2-one was cycloco ndensed with dimethyl malonate by Michael addition and Claisen condensation, followed by saponification and decarboxylation to give the intermediate of 5-(2-ethylthiopropyl)-cyclohexane-1,3-dione.

首先，以巴豆醛与乙硫醇为原料，在三乙胺的催化作用下高收率制得3-乙硫基丁醛；然后从乙酰乙酸甲酯出发，通过碱水解、与3-乙硫基丁醛缩合、脱水三步反应合成6-乙硫基-3-烯-2-庚酮，接着6-乙硫基-3-烯-2-庚酮与丙二酸二甲酯通过Michael加成和Claisen缩合成环，再通过皂化和脱羧反应生成中间体5-[2-丙基]-1，3-环己二酮；再与丙酸酐反应丙酰化，最后与0-3-氯-2-丙烯基羟胺肟化，得到目标化合物烯草酮。

Condensation of cinnamaldehyde with methyl crotonate in the presence of alcohol-flee potassium methoxide gives,after hydrolysis,p-phenyl-benzoic acid in low yield.Its structure has been ascertained by direct comparison with an au- thentic sample.

桂皮醛与α-丁烯酸甲酯在催化剂去醇的甲氧基钾影响下进行反应，得到低产率的对-苯基-苯甲酸，共结构经用已知方法所得同样的酸直接加以比较而确定。

A novel planar chiral diferrocenylimine-diols 6 was synthesized by the condensation of R, S(subscript p-1-(2-diphenyl hydroxyl methyl) ferrocenylethylamine [R, S(subscript p-4] with phthaldehyde in anhydrous ethanol, and was crystallographically characterized.

通过R，S(下标 p-1-（2-二苯基羟甲基）二茂铁乙胺[R，S(下标 p-4]和对苯二甲醛在无水乙醇中的缩合反应合成了一种新型平面手性双二茂铁亚胺二醇化合物6，并经X-射线衍射分析它的晶体结构。

In spite of this, the preparation of thiol-end functionalized PMMA was achieved by introducing a short block of polystyrene after the RAFT polymerization of MMA.Third, RAFT technique was applied to design and synthesize some well-defined poymers. Five monomers, lauryl methacrylate,(N,N-dimethylamino)ethyl methacrylate, poly methyl ether methacrylate, 4-(4\'-cyanobiphenyl-4-yloxy) butyl methacrylate and 2-ethyl methacrylate were chosen to RAFT homopolymerization or copolymerizations mediated by cumyl dithiobenzoate.

RAFT方法在具有特定结构聚合物的设计与合成上的应用，在机理研究的基础上，本论文选择五种不同结构的甲基丙烯酸酯类单体：lauryl methacrylate，(N，N-dimethylamino)ethyl methacrylate，polymethyl ether methacrylate，4-(4'-cyanobiphenyl-4-yloxy)butyl methacrylate和2-ethyl methacrylate，用CDB调控RAFT聚合的方法设计合成了一些特定结构的聚合物，详细而深入地研究了它们的均聚、共聚动力学，发现了双硫酯并非在聚合反应初期就全部转化，而是随着反应进行逐步消耗，这与理想的活性聚合体系有很大差别。

The results showed that the solubility of Jatropha curcas L. seed oil in methanol in creased at the presence of methyl esters, which could enhance mass transfer.

结果表明，脂肪酸甲酯的存在可有效提高麻疯树籽油在甲醇中的溶解度，因此可在一定程度上改善传质效果

The article proposed a method of the gas chromatographic determination for methyl cyanoacetate and intermidiates.

提出了用 6 。5 %吐温+ 5 。5 %邻苯二甲酸二壬酯涂于 10 2白色硅烷化担体上的不锈钢色谱柱，对氰乙酸甲酯合成的中间体和产品进行定量分析，取得较满意的效果。

Continuous distillation processes including three-tower,four-tower and five-tower for separation of methyl cyanoacetate were proposed to replace the conventional batch distillation process.

针对氰乙酸甲酯传统的间歇精馏分离过程，提出了连续精馏分离氰乙酸甲酯的三塔、四塔和五塔工艺流程，并对3种分离流程进行工艺分析，确定了连续精馏五塔分离工艺。

Photoinduced Electron Transfer [2+2] Cycloaddition Reactions ofBenzannelated Isoquinolin-1-ones with Electron Deficient Alkenes Photoinduced [2+2] cycloaddition reactions of 11H-benzoxazolo[3,2-b]isoquinolin-11-one 8 and 11H-benzothiazolo[3,2-b]isoquinolin-11-one 13 with electron deficient alkenessuch as acrylonitrile, methyl acrylate, dimethyl fumarate and dimethyl maleate afforded a group of polycyclic isoquinoline derivatives bearing cyclobutane moieties ingood to excellent yields and resulted in the Schenck isomerization of the alkenes.

3苯并增环异喹啉-1-酮与缺电子烯烃的光诱导电子转移[2+2]环加成反应 11H-苯并恶唑[3，2-b]异喹啉-11-酮8和11H-苯并噻唑[3，2-b]异喹啉-11-酮13与缺电子烯烃如丙烯腈，丙烯酸甲酯，富马酸二甲酯及马来酸二甲酯的光诱导[2+2]环加成反应以高产率给出一系列含有环丁烷结构单元的多环异喹啉衍生物并导致烯烃的Schenck异构化作用。

With cyclohexyl methyl dimethoxy silane as external donor,isotacticity of polymer turned to be more adjustable.

结果表明，使用环己基-甲基-二甲氧基硅烷，聚合物的等规度可调性好

Two asymmetric photochemical reactions were investigated in such medium: photochemical reduction of phenyl cyclohexyl ketone and photoelectrocyclization of tropolone methyl ether.

虽然固相光化学反应的手性诱导取得了可喜的进展，但对底物和诱导剂的要求比较苛刻，使其适用范围非常有限。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。