查询词典 methyl-glyoxal
- 与 methyl-glyoxal 相关的网络例句 [注:此内容来源于网络,仅供参考]
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Cinnabarinus at 150 mg/L.The influences on bioactivity of substituted pyrazole and pyrimidine were discussed respectively: pyrazoles substituted with phenyls at 3 position had higher activity than thiophen and compounds with R_1=methyl had higher activity than that with R_1= hydrogen, pyrimidines substituted with methyl at 2 (R_3) and 5 (R_3) position and phenyl at 6 position were most active.
本论文对吡唑及嘧啶取代基对活性的影响分别进行了讨论,可知:吡唑3位为取代苯基的化合物杀菌活性优于取代噻吩的,吡唑4位(R_1)为甲基的杀菌活性高于R_1为氢的活性;嘧啶的2位(R_3)为甲基,5位(R_1)为甲基,6位为无取代基的苯基时活性最好。
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In pH 5.3-6.8 Britton-Robinson buffer medium, Cefotaxime sodium can react with HgCl2 to form 1:1 anionic chelate, which can further react with basic triphenylmethane dye such as crystal violet, methyl violet, ethyl violet, brilliant green, iodine green, methyl green and malachite green to form ternary ion-association complexes. As a result, the resonance Rayleigh scattering spectrum was enhanced greatly.
在pH为5.3~6.8的Britton-Robinson缓冲溶液中,头孢噻肟钠与HgCl2形成摩尔比为1:1的螯合阴离子,它能进一步与结晶紫、甲基紫、乙基紫、亮绿、碘绿、甲基绿和孔雀石绿等碱性三苯甲烷类染料反应形成三元离子缔合物,导致共振瑞利散射的显著增强。
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A series of methyl 2,7,7-trimethyl-5-oxo-4-aryl1,4,5,6,7,8- hexahydroquinoline -3-carboxylate were synthesized by the reaction of aromatic aldehydes,dimedone and methyl acetoacetate using ammonium acetate as catalyst in glycol under microwave irradiation with 82%~98% yields in 4~6 min.
微波辐射下以芳醛、达咪酮、乙酰乙酸甲酯为原料,乙二醇为溶剂,醋酸铵为催化剂合成了一系列2,7,7-三甲基-5-氧代-4-芳基-1,4,5,6,7,8-六氢喹啉-3-羧酸甲酯化合物,反应时间4~6 min,产率82%~98%。
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A set of laser monitoring observation system to be used for measure the solubility with a high speed, which is programmed heating apparatus , have designed. The solubility of 1,2-cyclohexanediol were measured in water, methyl acetate, acetic ester, propyl acetate, butyl acetate, methyl acrylate, ethyl acrylate, acetoacetic ester at different temperature.
另外,还建立了一套带激光监视系统,可以控制升温速率的溶解度测定实验装置,测定了反式-1,2-环己二醇在水、乙酸甲酯、乙酸乙酯、乙酸丙酯、乙酸丁酯、乙酰乙酸乙酯、丙烯酸甲酯、丙烯酸乙酯和甲基丙基酮等9个二元体系中的溶解度。
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DFT were carried out to optimize the conformational isomers with minimum energies. Peak separations in the methyl and azomethine signals were also found to originate from the rotation hindrance of the N-N bond. After N'-acylideneacetohydrazides were converted to 1, 3, 4-oxadiazole compounds, the proton signal of the methyl group appeared as a single peak.
端甲基质子和次甲基质子信号裂分也来源于N-N键旋转受阻。N'-苄基酰腙通过缩合反应转变成1,3,4-二唑化合物,消除了甲基空间取向的差异,其信号变为单峰。
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E. methyl jasmonate +methyl salicylate, MeJA +cis-hexenal, MeJA +trans-hexenal, MeJA +benzothiazole, and then the induced activities of three defensive enzymes including peroxidase, polyphenol oxidase and phenylalanine ammonia lyase were measured.
以1年生合作杨扦插苗为试验材料,利用茉莉酸甲酯分别与水杨酸甲酯、顺式己烯醛(cis-hexenal)、反式己烯醛(trans-hexenal)和苯骈噻唑混合的4种挥发物熏蒸合作杨叶片,检测过氧化物酶、多酚氧化酶及苯丙氨酸解氨酶3种防御酶的活性变化。
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In this paper, eleven benzothiazole derivatives such as N, N, N′, N′-tetra (2-benzothiazolyl) methyl-1, 2-ethanediamine,(2-benzothiazolyl) methyloxy benzene, 2,4-dichloro( 2-benzothiazolyl) methyloxy benzene, O-di(2-benzothiazolyl) methyloxybenzene, P-di(2-benzothiazolyl) methyloxy benzene, 3-(2-benzothiazolyl) pyridine were synthesized by means of conventional method or MWI technology and a single crystal of di (2-benzothiazolyl ) methyl ether was obtained.
本文分别用常规合成法和微波辐射法合成了N,N,N′, N′-四(2-苯并噻唑基)甲基-1,2-乙二胺、(2-苯并噻唑基)甲氧基苯、2,4-二氯-(2-苯并噻唑基)甲氧基苯、邻-二(2-苯并噻唑基)甲氧基苯、对-二(2-苯并噻唑基)甲氧基苯、3-(2-苯并噻唑基)吡啶等11 个苯并噻唑类化合物并得到二(2-苯并噻唑基)甲基醚单晶。
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In this thesis,the AM1,MNDO,MINDO/3(mainly AM1)and INDO/S-CI semiempirical MO methods were used toinvestigate the excited-state intramolecular protontransfer reactions of salicylic acid derivatives—salicylic acid,methyl salicylate,salicylaldehyde,o-hydroxyaceto-phenone,salicylamide and 3-hydroxy-picolinamide (6 conformers and 2-3 anion species);2-(2'-hydroxy-5' methylphenyl) benzotriazole(4 conformers),2-(2' hydroxyphenyl) benzimidazole (3 conformers and 3anion species),Bis-2,5-(2-benzoxazolyl)hydroquinone(3 conformers),2-(2'-hydroxyphenyl)benzothiazole(2conformers) and 7-azaindole dimer (2 conformers).Theinvestigations were described as follows.Geometry optimization,relative stability andhydrogen bonding energy First,for sylicylic acid derivative molecules,the AM1,MNDO and MINDO/3 methods were used toinvestigate ground-state geometry optimization,energies,relative stabilities and hydrogen-bondingenergies on the five kinds of the molecules(designing 6 conformers and 2-3 anion species).Comparing with experimental data,the optimizedgeometry,the order of stability,the hydrogen-bonding energies and the distances between O-O in O-H..O hydrogen bonds by AM1 method were in agreementwith the experimental data,however,the C-C bondlengths optimized by MNDO and MINDO/3 were longer,C-O and O-H bond lengths were shorter;for C-N bondlengths,the results opitimized by MNDO method werethe same as those by AM1 method,nevertheless the C-Nbond lengths given by MINDO/3 method were muchshorter.For some sylicylic acid derivatives(e.g.methyl salicylate,salicylamide),the order ofstabilities on the conformers given by MNDO andMINDO/3 methods were not in agreement with theexisting conformers deduced by experimental methods,and the hydrogen bonding energies calculated by MNDO.and MINDO/3 methods were smaller.Second,the studyon the other systems found that the optimizedgeometry of the proton-transfered product with INDOmethod could not be obtained,only could theoptimized geometry of reactant be obtained,and thecalculated hydrogen bonding energies were greater.Many results of calculation indicated that the studyon the excited-state intramolecular proton transferreaction system using AM1 method was suitable andreliable.
本论文用AM1、MNDO、MINDO/3(主要是AM1)和INDO/S-CI半经验分子轨道方法对水杨酸衍生物系列——水杨酸、水杨酸甲酯、水杨醛、O-羟基乙酰苯酮、水杨酰胺和3-羟基吡啶酰胺(6种异构体和2-3种阴离子);2-(2'-羟基-5'-甲基苯基)苯并三〓唑(4种异构体);2-(2'-羟基苯基)苯并咪唑(3种异构体和3种阴离子);2,5-二间氮杂氧茚氢醌(3种异构体);2-(2'-羟基苯基)间〓杂硫茚(2种异构体)和7-〓吲哚二体(2种异构体)的激发态分子内质子转移反应在以下几个方面进行了较系统的理论研究:几何构型优化和相对稳定性及氢键能首先以水杨酸衍生物系列分子为例,用AM1、MNDO和MINDO/3方法考察了5种分子(每种分子设计6种异构体和2-3种阴离子)的基态几何构型优化,能量、相对稳定性和氢键能计算,通过和实验数据进行比较,AM1方法给出的优化几何构型、稳定性次序、氢键能和O—H。。。O氢键的0—0距离与实验数据吻合最好,MNDO和MINDO/3方法优化的C-C键长偏长,C-O键和O-H键长偏短;对于C-N键长,MNDO和AM1优化结果差别不大,而MINDO/3给出了过短的C-N键长,MNDO和MINDO/3方法给出的有些水杨酸衍生物分子(如水杨酸甲酯和水杨酰胺)异构体的稳定性次序和实验上推测的可存在异构体结果不一致,MNDO和MINDO/3方法给出的氢键能偏低,对其他体系的研究发现INDO方法常常不能得到质子转移产物的优化几何构型,只能得到反应物的优化构型,并且估算的氢键能偏高,大量的计算结果表明AM1方法对本论文研究的激发态分子内质子转移反应体系是适宜和可靠的。
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In addition ,nine new O,O-dialkyl-[α-(1,3,4,6-tetraacetyl-2-deoxy-β-D-glucoamino)-p-methyl benzlidene] phosphonatesand eight O,O-dialkyl-α-(2-deoxy-D-glucoamino)-p-methyl benzylidene phosphonates were prepared. The 〓 and〓 spectra of Ⅰ-Ⅴ compounds indicated clearly that each of Ⅰ-Ⅴ compounds contains two diastereo-isomers.
我们对非对映异构体的分离方法进行了研究,并分离得到了五个单一构型的异构体〓、〓、〓、〓和〓,培养出了〓、〓和〓三个异构体的单晶,通过X-射线衍射分析,确定了〓、〓和〓三个异构体的绝对构型,反应过程中引入的手性原子的构型均为R构型。
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Methyl Sartortuoate and Methyl isosartortuoate are two tetracyclic tetraterpenoids isolated from the sarcophyton tortuosum tixier-durivalt by Chinese scientists. Biogenetically, it could be regarded as a Diels-Alder combination of two cembrenoids, i.
扭曲肉芝甲酯和异扭曲肉芝甲酯是中国科学家从南中国海扭曲肉芝软珊瑚中分离到的一种四环四萜化合物,从生源角度考虑,可能由两个西松烷型二萜化合物经Diels-Alder反应组装而成。
- 推荐网络例句
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Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.
然而现在,所有的孩子都要在综合学校继续学习,所以这次考试只是决定他们将要学习哪些课程。
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Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .
城区的迅速扩大在很多情况下侵占了宝贵的可耕地,使人们普遍认识到发展不能以牺牲农业为代价。
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Detailed Intrinsic Reaction Coordination calculations were carried out to guarantee the optimized transition-state structures being connected to the related tautomers.
同时,做了详尽的内禀反应坐标计算,以保证所得到的过渡态连接相应的始末异构体。