查询词典 methyl salicylate

Comparing with the result of methyl iodide in intense laser field, some differences are observed:(1) at the same laser field intensity, the highest charged fragment ion of methyl bromide was Br(superscript 3+), lower than I(superscript 6+) of methyl iodide;(2) the dehydrogenation channel was observed in the multiphoton dissociation or Coulomb explosion of methyl bromide, but was not observed in the case of methyl iodide;(3) HBr(superscript +) was observed, but there was no similar channel in the case of methyl iodide;(4) for methyl bromide, the valid charge distance of Coulomb explosion increases with the product of p and q; while in the case of methyl iodide, the distance remained almost the same;(5) the producing channel of CH(superscript + subscript m)(m=0, 1, 2) is different from the ionization-dissociation of methyl iodide in which the stepwise dissociation of CH3(superscript +) was thought to be the main channel, CH(superscript + subscript m)(m=0, 1, 2) of methyl bromide are mainly from the products of the direct dissociation of the dehydrogenated parent ions instead of the stepwise dissociation of CH3(superscript +).

与碘甲烷在强场中的实验结果对比发现：(1)在相同的激光场强下，碘甲烷电离解离的最高价碎片离子为I(上标 6+)而溴甲烷为Br(上标 3+)；(2)溴甲烷质谱中存在母体离子的脱氢产物CHBr和CHBr(上标 2+)，而对于碘甲烷，没有检测到这些通道，C-I键首先断开；(3)质谱中存在H^79Br和H^81Br，而碘甲烷的电离解离中不存在HI产物；(4)溴甲烷库仑两体爆炸的有效电荷间距随着两碎片电荷乘积的增大而增大，而对于碘甲烷此间距几乎不随电荷乘积变化；(5)CH(m=0， 1， 2)的主要生成通道可能与碘甲烷不同，不是来自CH3的顺序脱氢，而是来自脱氢母体离子的直接解离。

Their structures were characterized by IR, 1H NMR, of which 4-chloro- 2-methyl-7-(2-bromoethoxy) isoflavone, 2, 4\'-dimethyl-7-(2-bromo-ethoxy)isoflavone and 2-methyl-7-(2-bromoethoxy) isoflavone are rarely reported so far.4\'-chloro-2-methyl-7-(3-bromopropoxy)isoflavone, 2, 4\'-dimethyl-7-(3-bromo- propoxy) isoflavone, 2-methyl-7-(3-bromopropoxy) isoflavone, 4\'-methoxy-2-methyl-7-(3-bromopropoxy) isoflavone and 4\'-hydroxy-2-methyl-7-(3-bromopropoxy) isoflavone were gained by reacting 7-hydroxy-2-methyl isoflavone derivatives with 1, 3-dibromo- propane, respectively.

第三章(来源：73ABC论文网www.abclunwen.com)在丙酮溶液中以K_2CO_3为碱，使溴乙氧基异黄酮和溴丙氧基异黄酮与咪唑偶合，以较高的产率合成出10种目标化合物：2-甲基-4′-氯-7-2-(1-咪唑基乙氧基异黄酮、2，4′-二甲基-7-2-(1-咪唑基乙氧基异黄酮、2-甲基-7-2-(1-咪唑基乙氧基异黄酮、2-甲基-4′-甲氧基-7-2-(1-咪唑基乙氧基异黄酮、2-甲基-4′-羟基-7-2-(1-咪唑基乙氧基异黄酮、2-甲基-4′-氯-7-3-(1-咪唑基丙氧基异黄酮、2，4′-二甲基-7-3-(1-咪唑基丙氧基异黄酮、2-甲基-7-3-(1-咪唑基丙氧基异黄酮、2-甲基-4′-甲氧基-7-3-(1-咪唑基丙氧基异黄酮、2-甲基-4′-羟基-7-3-(1-咪唑基丙氧基异黄酮，经IR、~1H NMR、~(13)C NMR、元素分析等对其结构进行了表征，10种目标产物均未见文(来源：ABC论文cccccc网www.abclunwen.com)献报道。

Methyl phenyl glyoxylate was prepared firstly by reaction of 2-methyl benzoyl chloride with NaCN. The reaction of 2-methyl phenyl glyoxylate with methanol gave the target product methyl 2-methyl phenyl glyoxylate. An improved 3 step synthetic method of methyl 2-methyl phenyl glyoxylate was studied. The optimization conditions were presented.

以2-甲基苯甲酸为原料，酰化后与氰化钠反应生成2-甲基苯甲酰腈，经甲酯化生成2-甲基苯甲酰甲酸甲酯，改进了三步合成2-甲基苯甲酰甲酸甲酯的方法，并对反应时间、反应温度等影响因素进行了优化，确定了合成反应中的最优化条件。

At the same time, with reference to the conditions of synthesis of methyl ester of salicylic acid, we combined ethyl ester of salicylic acid, salicylic acid-n-butyl, isobutyl salicylate, amyl salicylate, isoamyl salicylate and salicylic acid benzyl ester,besides, experimented the possibility for series of ester synthesis catalyst with Sodium bisulfate as a catalyst .

同时参照水杨酸甲酯的合成条件合成了水杨酸乙酯、水杨酸丁酯、水杨酸异丁酯、水杨酸戊酯、水杨酸异戊酯和水杨酸苄酯，实验了以硫酸氢钠为催化剂合成系列酯的可能性。

Our study show that 9, 11-Octadecadienoic acid, methyl ester is the highest content of organic acid ester components in non-hydrocarbon fraction, higher content of 6-Octadecenoic acid, methyl ester reflects mainly terristrial source input, higher content of pentadecane acid, 14-methyl, methyl ester or Heptadeeanoic acid, 16-methyl, methyl ester shows mainly aquatic source input.

原油和岩石抽提物非烃中有机酸酯类化合物的有机地球化学研究报道很少，系统研究发现非烃有机酸酯中9，11-十八二烯酸甲酯含量最高，而次高峰的丰度可用作生源判识，陆源母质输入多的样品次高峰为6-十八单烯酸甲酯，水生母质供给多者次高峰为14-甲基十五烷酸甲酯或16-甲基十七烷酸甲酯。

Results the resolution and linearity of eucalyptol, camphor, synthetic borneol, menthol, methyl salicylate, cinnamaldehyde and eugenol were good with the recovery rate of eucalyptol at 98.7 %(rsd=1.1 %) camphor at 99.0 %(rsd=1.0 %), synthetic borneol at 99.4 %(rsd=0.8 %), menthol at 99.7 %(rsd=0.4 %), methyl salicylate at 99.6 %(rsd=0.5 %), cinnamaldehyde at 99.5 %(rsd=0.8 %), eugenol at 99.5 %(rsd=0.9 %), respectively.

结果在该色谱条件下桉油精、樟脑、冰片、薄荷脑、水杨酸甲酯、桂皮醛、丁香酚的分离度和线性关系良好，平均回收率（n＝6）分别为98.7 %（rsd＝1.1 ％）、99.0 %（rsd＝1.0 ％）、99.4 %（rsd＝0.8 ％）、99.7 %（rsd＝0.4 ％）、99.6 %（rsd＝0.5 ％）、99.5 %（rsd＝0.8 ％）、99.5 %（rsd＝0.9 ％）。

In this thesis,the AM1,MNDO,MINDO/3(mainly AM1)and INDO/S-CI semiempirical MO methods were used toinvestigate the excited-state intramolecular protontransfer reactions of salicylic acid derivatives—salicylic acid,methyl salicylate,salicylaldehyde,o-hydroxyaceto-phenone,salicylamide and 3-hydroxy-picolinamide (6 conformers and 2-3 anion species);2-(2'-hydroxy-5' methylphenyl) benzotriazole(4 conformers),2-(2' hydroxyphenyl) benzimidazole (3 conformers and 3anion species),Bis-2,5-(2-benzoxazolyl)hydroquinone(3 conformers),2-(2'-hydroxyphenyl)benzothiazole(2conformers) and 7-azaindole dimer (2 conformers).Theinvestigations were described as follows.Geometry optimization,relative stability andhydrogen bonding energy First,for sylicylic acid derivative molecules,the AM1,MNDO and MINDO/3 methods were used toinvestigate ground-state geometry optimization,energies,relative stabilities and hydrogen-bondingenergies on the five kinds of the molecules(designing 6 conformers and 2-3 anion species).Comparing with experimental data,the optimizedgeometry,the order of stability,the hydrogen-bonding energies and the distances between O-O in O-H..O hydrogen bonds by AM1 method were in agreementwith the experimental data,however,the C-C bondlengths optimized by MNDO and MINDO/3 were longer,C-O and O-H bond lengths were shorter;for C-N bondlengths,the results opitimized by MNDO method werethe same as those by AM1 method,nevertheless the C-Nbond lengths given by MINDO/3 method were muchshorter.For some sylicylic acid derivatives(e.g.methyl salicylate,salicylamide),the order ofstabilities on the conformers given by MNDO andMINDO/3 methods were not in agreement with theexisting conformers deduced by experimental methods,and the hydrogen bonding energies calculated by MNDO.and MINDO/3 methods were smaller.Second,the studyon the other systems found that the optimizedgeometry of the proton-transfered product with INDOmethod could not be obtained,only could theoptimized geometry of reactant be obtained,and thecalculated hydrogen bonding energies were greater.Many results of calculation indicated that the studyon the excited-state intramolecular proton transferreaction system using AM1 method was suitable andreliable.

本论文用AM1、MNDO、MINDO/3（主要是AM1）和INDO/S-CI半经验分子轨道方法对水杨酸衍生物系列——水杨酸、水杨酸甲酯、水杨醛、O-羟基乙酰苯酮、水杨酰胺和3-羟基吡啶酰胺（6种异构体和2-3种阴离子）；2-（2'-羟基-5'-甲基苯基）苯并三〓唑（4种异构体）；2-（2'-羟基苯基）苯并咪唑（3种异构体和3种阴离子）；2，5-二间氮杂氧茚氢醌（3种异构体）；2-（2'-羟基苯基）间〓杂硫茚（2种异构体）和7-〓吲哚二体（2种异构体）的激发态分子内质子转移反应在以下几个方面进行了较系统的理论研究：几何构型优化和相对稳定性及氢键能首先以水杨酸衍生物系列分子为例，用AM1、MNDO和MINDO/3方法考察了5种分子（每种分子设计6种异构体和2-3种阴离子）的基态几何构型优化，能量、相对稳定性和氢键能计算，通过和实验数据进行比较，AM1方法给出的优化几何构型、稳定性次序、氢键能和O—H。。。O氢键的0—0距离与实验数据吻合最好，MNDO和MINDO/3方法优化的C-C键长偏长，C-O键和O-H键长偏短；对于C-N键长，MNDO和AM1优化结果差别不大，而MINDO/3给出了过短的C-N键长，MNDO和MINDO/3方法给出的有些水杨酸衍生物分子（如水杨酸甲酯和水杨酰胺）异构体的稳定性次序和实验上推测的可存在异构体结果不一致，MNDO和MINDO/3方法给出的氢键能偏低，对其他体系的研究发现INDO方法常常不能得到质子转移产物的优化几何构型，只能得到反应物的优化构型，并且估算的氢键能偏高，大量的计算结果表明AM1方法对本论文研究的激发态分子内质子转移反应体系是适宜和可靠的。

When used in combination with methyl salicylate, menthol enhances the penetration of the methyl salicylate.

当与水杨酸甲酯结合使用时，薄荷醇可增强水杨酸甲酯的渗透性。

It was also found that at experimental concentrations there was no regularity for the change of activity of copper salicylate encapsulated in negatively charged liposomes, and copper salicylate encapsulated in liposomes with more negative charges could promote the dismutation of superoxide anion free radicals, however, so could copper salicylate encapsulated in liposomes with fewer negative charges only in lower concentrations.

并发现在实验浓度范围内，负电性脂质体包裹的水杨酸铜，活性变化无规则，且荷负电量多的脂质体包裹的水杨酸铜促进超氧自由基的歧化，而荷负电量少的脂质体仅在低浓度区对超氧的歧化表现为促进作用。

In the study of UV absorbing test, polyhydroxy substituted N-benzoylserotonin derivatives (compound 1-10) shows better ability to absorb UV and shows wider range of absorbing UVB than control group, octyl salicylate. With respect to octyl salicylate, octyl salicylate can abosorb the highest wavelength up to 306 nm under UVB (wavelength ranges 280 nm ~320 nm), and the ε is 4.03 × 103 ㎝-1M-1. However, the ε of polyhydroxy substituted N-benzoylserotonin derivatives (compound 1-10) under 306 nm range 4.14 × 103 ~ 11.45 × 103㎝-1M-1. It is reasonable that the compounds in this study can not only absorb the individual wavelength amoung the wavelenght of UVB, but also absorb wider range of wavelength.

在紫外线可见光吸收测试结果显示，相较於对照组水杨酸辛酯在UVB波长(280 ~ 320 nm)范围最大吸收波长为306 nm，其莫耳吸收系数为4.03 × 103 ㎝-1M-1，而多羟基取代之N-色洛冬宁苯甲醯胺衍生物（化合物1 ~ 10）在306 nm的莫耳吸收系数介於4.14 × 103 ~ 11.45 × 103㎝-1M-1，其吸收紫外线的效果皆优於对照组水杨酸辛酯，且其在UVB波长的范围吸收波长的光谱也较宽广，可知每个化合物并非只是对UVB波长范围内的单一波长有吸收度，而是对UVB波长范围具有较宽广的光谱吸收。

Putt your way through 36 fun-filled holes of minigolf on 3D designed courses with elevated greens, bunkers, bridges and water hazards, among other crazy obstacles.

您的推杆方式，通过36个有趣的填孔迷你的三维设计的课程，以提升绿党，掩体，桥梁和水的危害，除其他疯狂的障碍。

Some participles can be used either as attributes or as predicatives.

有些分词既可当定语用，也可当表语用。