查询词典 methyl group

65 The methyl group on the benzene ring greatly facilitates the nitration of toluene.

苯环上的甲基使甲苯非常易于硝化苯环上的甲基使甲苯非常易于硝化。

It shows that some organic liquids, which have higher dielectric constant, small viscosity, and methyl group bound directly with high negative charge atom, are appropriate carbon source for deposition DLC films.

介电常数比较高的、粘度小的、甲基基团直接与极性基团连接的有机介质是合适的液相沉积类金刚石薄膜的碳源。

Molecular conformation calculations were made for two possible conformers(eclipsed and staggered with respect to the methyl group)of the compound Calculated results show that:the stable conformer of pyruvic acid is the eclipsed one;The BLYP/6-31G* and scaled HF/6-31G* frequencies correspond well with each other and with available experimental assignment of the normal vibrational modes.

结果表明：在丙酮酸分子的两种构象中，重叠式比较稳定*B3LYP计算得到的构型参数与实验结果比较一致；在振动频率的计算中，BLYP未标度力场所计算的非CH3伸缩振动基频预测值和实验值的平均绝对偏差为10.4cm-1；而HF标度力场的平均绝对偏差为17.9cm-1。

Not only the hydrogen atom of hydroxyl but also the hydrogen atom of the methyl group can transfer to the N atom of heterocycle.

不但甲醇分子羟基上的H可以作为供体质子，而且甲基上的H也可以作为供体质子而转移到芳香环的杂原子N上。

We have exchanged the methyl group of the piperazine ring at 3-position of rifapicin to other new groups.

我们主要是将连接在利福平3位上的哌嗪环末端氮上的甲基换成其它基团，这些新连接的基团都与一些最近报道的抗菌活性比较强的新化合物的结构中所包含的基团相似或相同，并测试了这些化合物抗结核杆菌的活性，结果显示了他们大部分都保持了与利福平相当的抗菌活性，其中衍生物81的抗菌活性是利福平的十倍，具有进一步开发的价值。

In addition in the complexes, Ar atom has apparent obstruction to the internal rotation of the methyl group.

另外，在复合物内部，Ar原子对甲基氟苯中的CH3内转动有明显的阻碍作用。

A-Methylnaphthalene contains a methyl group, which is a strong donor group, so the reaction of a-methylnaphthalene with C14 AOS acid had a higher conversion of aromatic than did the reaction of benzene with C14 AOS acid. After alkylaryl sulfonic acid is formed, it will continue to react with another AOS acid to rapidly produce dialkylaryl disulfonic acids owing to the electron- donating effect of the long alkyl chain in the alkylaryl sulfonic acid molecule.

a-Methylnaphthalene包含一个甲基集团，这是一个强大的捐赠团体，所以 a-methylnaphthalene反应出了与C14酸更高的转换的反应比苯与C14活性氧酸。alkylaryl磺酸为后形成，它将继续与另一出酸 dialkylaryl disulfonic迅速产生的电子-酸捐赠的长期效果在alkylaryl烃链磺酸分子。

As our studies showed, silylation of mesoporous molecular sieves with alkoxysilane was an usual method of linking desired organical groups. However, as a result, the a lot of silanol groups still existed on the surface of mosoporous molecular sieves after silylation, which maybe affect the interface property and its catalystic activity. Based on this consideration, a novel method was proposed that a mixture of trichlorosilanes was used to silylate mesoporous molecular sieves, introducing both the further reactive group and hyhrophobic methyl group in one pot.

正如研究表明，通过硅氧烷与介孔分子筛表面的硅羟基反应是常见的键连有机基团的方法，但表面仍会剩余较多的硅羟基，硅羟基的存在会严重影响到介孔分子筛表面性质及催化活性，为此笔者提出采用混合的三氯化硅烷一步硅烷化介孔分子筛，在孔道内同时引入可进一步功能化的氯丙基或氯苄基和疏水性的甲基。

In chapter 5,several novel fluorescent dyes based on perylene tetracarboxylic diimides were prepared by a catalytic nucleophilic addition of an activated methyl group to carbonyl group.

第四章：以无水氯化锌为催化剂，将含活泼甲基的2-甲基喹啉连接到PDI单元的酰亚胺N的位置，合成了两个含PDI单元和硼氟荧光体单元的新颖荧光染料。

In general, they are synthesized by using chemistry oxidant to oxidize methyl group of aromatic compound into the aldehyde group.

其生产方法一般采用化学氧化剂氧化甲基化合物的方法，即采用化学氧化剂氧化甲基化合物得到芳香族醛类。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。