查询词典 metal-organic

The bonds of early transition metal monoxides are stronger than those of later transition metal monoxides.

这也说明了对于d轨道未半满的早周期过渡金属来说，d电子易于参与成键生成高氧化价态分子。

It was found that earlytransition metal monoxides ScO, TiO and VO do not form noble gas complexes, whilethe late transition metal monoxides coordinate one noble gas atom in forming thelinear NgMO(M=Cr, Mn, Fe, Co, Ni) complexes.

对于前过渡的ScO，TiO和VO分子，它们的9σ，1δ和4π价分子轨道能量很高，不能有效地与稀有气体原子形成络合物，而对于后过渡金属一氧化物则可以配位一个稀有气体原子形成直线型的NgMO(M=Cr，Mn，Fe，Co，Ni)络合物。

The 3d transition metal monoxides coordinate one noble gasatom in forming the linear NgMO(M=Cr, Mn, Fe, Co, Ni; Ng=Ar, Kr, Xe) complexes.(3) The group VB metal oxides MO_2 and MO_4 coordinate two and one noble gasatoms in forming the MO_2_2 and MO_4(M=V, Nb, Ta; Ng=Ar, Kr, Xe)complexes.

3第VB族金属二氧化物与两个稀有气体原子形成的MO_2_2(M=V，Nb，Ta；Ng=Ar，Kr，Xe)络合物，其四氧化物与一个稀有气体原子形成的MO_4(M=V，Nb，Ta；Ng=Ar，Kr，Xe)络合物。

Complexes 7-12, 16, 22 and 23 are dimeric molybdatesor dimeric tungstates, the central metal with citrate or malate in a molar ratio of 1:1. Theanions of these complexes have two metal atoms and two ligands. Each ligand acts as atridentate fashion via theirα-alkoxy,α-carboxy andβ-carboxy groups coordinated to eachmetal atom. Complex 13 is a monomeric molybdate. The citrate ligand coordinates tomolybdenum with itsα-alkoxy,α-carboxy andβ-carboxy groups in a tridentate mode.

其配阴离子中都含有2个金属原子和2个配体，且配体均以α-烷氧基、α-羧基和β-羧基氧与中心金属三齿配位。13是单核柠檬酸钼配合物，柠檬酸也以α-烷氧基、α-羧基和β-羧基氧与钼三齿配位。17和21分别为苹果酸钼、柠檬酸钨单核配合物，其中苹果酸、柠檬酸配体均以α-烷氧基氧和α-羧基氧与金属双齿配位。

The Mn exhibits the remarkable different nature compared with the other metal ions in the first transition metal series.

3Mn表现出与第一过渡系其它金属显著不同的性质，在对应的化合物中，存在着独特的金属与配原子间的静电相互作用。

The ligand was used to prepare for a series of its transition metal complexes by the replacement reaction with metal salts.

并用该杂原子大环配体与过渡金属的盐进行置换反应，合成了相应金属：Ni、Cu、Co、Zn和Cd的大环配合物。

A series of transition metals, transition metal oxides and composite metal oxides were investigated as catalysts for phenol hydroxylation. Twelve new types of phenol hydroxylation catalysts with good activity and application prospect were reported.

考察了一系列过渡金属氧化物、复合金属氧化物及金属作为苯酚羟基化作用催化剂的反应性能，筛选出12种具有良好活性与应用前景，尚未见文献报道的苯酚羟基化新型催化剂。

SPI has an experienced team of metal stamping specialists and toolmakers who specialize in precision metal stamping parts especially in the industry of HDD,Consumer Electronics,Mobile Phone and Automotive Electronics.

苏州铭峰精密机械有限公司拥有在精密金属冲压及模具制造领域经验丰富的专业技术团队，特别是在硬盘，移动电话，汽车电子系统的精密冲压元件领域。

And 17 were capable of detecting specific metal ions by showing dramatic enhancement of fluorescence. In contrast with 15 and 17, the fluorescence signals of 13 and 14 were inefficiently altered by metal ions. Hence, 15 and 17 were further investigated with detailed 1H-NMR, UV-vis, and fluorescence titrations.

其中，15和17对特定金属离子有明显的侦测能力，混合后萤光强度会大幅增强，但13及14与金属离子混合后，萤光讯号的改变幅度不如15及17的显著，因此我们只对15和17进行详细的1H-NMR、UV-vis及萤光光谱的滴定。

The dissolution rate of platinum sheaths and thimbles is known to be proportional to the exposed metal surface area; and the leakage current through the metal to tank ground, and inverselyproportional to the frequency of the power mains.

铂金套管和嵌套管的分解率有一个常用的比例适合裸露的金属表面区域；泄露电流穿过金属到储槽容器，相反地有一个电源有频率有一个合适的比例。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐