查询词典 metal carbonyl

In the fourth chapter, four new complexes of hydrazide of podophyllic acid with transition metals have been prepared. Elemental analysis, molar conductivity, IR,〓 NMR and TG-DTA were used to characterize them. The results show that general formula of the complexes is M〓(n=0 or 2). The ligand is linked through the carbonyl oxygen and the terminal nitrogen of the hydrazide base to the transition metal ions in bidentate mode.

第四章 合成了四种鬼臼酰肼的过渡金属配合物，通过元素分析、摩尔电导、红外光谱、核磁共振氢谱和热重-差热对配合物进行了表征，研究结果表明，配合物的组成为M〓（n=0或2），配体是通过羰基氧和肼基上的端氮以双齿形式与金属离子配位的。

IR analysis of Leersia Hexandra Swart biomass revealed the presence of carboxyl, amide, hydroxyl and carbonyl groups, which are responsible for biosorption of the metal ion.

结果表明，该吸附是单分子吸附的伪二级动力学过程，吸附过程包含两个步骤： Cr离子通过静电作用富集在干粉材料表面，随后干粉表面存在的功能配位官能团会与Cr发生化学作用。

The conventional pinacol coupling of carbonyl compounds was carried out by using metals or metal compounds as mediators under condition of anhydrous organic solvents.

传统的呐偶合反应必须在无水有机溶剂条件下，由金属或金属化合物促进羰基化合物进行呐偶合反应。

The influence of ligand and cooperative metal on carbonyl insertion in heterobimetallic Rh-M species was investigated at the B3LYP level of density functional theory.

采用密度泛函方法研究了配体和协同金属对杂双核Rh-M金属配合物中羰基插入反应的影响。

Two carbonyl triruthenium metal clusters were separated with cellulose tris (3, 5-dimethylphenyl-carbamate) as chiral stationary phase. The effects of the optimal conditions were determined according to the effects of the mobile phase composition, the flow rate of the mobile phase and the solvents of the samples etc on the chiral separation of the metal clusters.

应用纤维素三（3， 5-二甲基苯基氨基甲酸酯）手性固定相对2种羰基钌金属簇合物进行了拆分，通过流动相组成、流速和样品溶剂等条件对拆分影响的考察对拆分条件进行了优化。

The result indicated that MgO and α- methacrylic acid can together thicken epoxy, and the speed of thickening epoxy become quickly with the increasing content of MgO; when the ratio of MgO and α- methacrylic acid is 3:1, thickening epoxy have a better effect; the thickening mechanism: the terminal corboxyl group of α- methacrylic acid react with MgO, and it accompany with large numbers of heat, the heat can accelerate the reaction between the terminal corboxyl group with the secondary hydroxyl groups of epoxy, intermolecular hydrogen bonding which the water of above-mentioned formation result in and complex compound which format the metal atoms and carbonyl group complexing collective increase the viscosity of epoxy resin.

结果表明：MgO和α－甲基丙烯酸配合可增稠环氧树脂，随着MgO加入量的增加，环氧树脂增稠的速度加快；MgO与α－甲基丙烯酸为3：1时，增稠环氧树脂的效果较好；推测环氧树脂的增稠机理是α－甲基丙烯酸中的端羧基与氧化镁反应，放出热量促使其端羧基与环氧树脂中的仲羟基反应，上述反应生成水产生的氢键和羰基与氧化镁中的金属原子形成络合物共同导致环氧树脂的粘度增加。

The positive peptide cleavage promoted by complex, CuⅡL and the negative response of CuⅡ/dien complex suggest the merely hydroxy pendant in complex have no ability to attack the peptide bond. The synergic carbonyl activation by metal coordination is essential for the cleavage of peptide bond promoted by CuⅡL.

比较相应铜配合物及二乙烯三胺铜配合物的切割性能，提示羟乙基侧臂单独难以实现相邻肽键的切割，高配位数金属中心对肽键羰基的活化与羟基的协同进攻是该类配合物切割多肽的可能机制。

The polymerization mechanisms of DTC, TMC and CL initiated by Ln 〓 were fully studied for the first time, and proved to be a"coordination insertion anionic mechanism". Monomer coordinated to rare earth metal on the carbonyl group, and opened ring via acyl-oxygen bond cleavage, forming a growing chain.

本文首次研究了Ln〓引发DTC、TMC和CL聚合的机理，证实都符合&配位插入阴离子机理&：单体首先以环外羰基和引发剂中稀土原子配位，并发生羰基加成，随之通过酰氧键断裂开环而插入到Ln-O键中实现链引发，然后各单体重复上述稀土原子参与的配位、加成、开环、插入聚合步骤，活性链在Ln-O端增长。

"Tenth Five-Year" National Scientific and Technological Plan -"a large shortage of base metal mineral resources exploration and efficient development of integrated technical studies"-"Refined Nickel Production Technology Industry," major projects (2001BA609A-19) in the "Acute Nickel Carbonyl Poisoning and Protection Research,"One of the project leader.

&十五&国家科技攻关计划－&大型紧缺金属矿产资源基地综合勘查与高效开发技术研究&之&镍精炼生产工艺产业化技术&重大项目（2001BA609A-19）中&急性羰基镍中毒救治与防护的研究&，项目负责人之一。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。