查询词典 liquid crystals

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

The results indicated that both binary interactive parameters of water/isobutanol system from this work and the parameters of water/ethanol from literature can be used to precdict the liquid-liquid equilibria of water/ethanol/isobutanol. But the parameters of ethanol/isobutanol from the literature were not appropriate for the prediction. Furthermore, the model parameters from 30℃ can can be used to predict the liquid-liquid equilibria under 35 ℃. The model parameters of water/isobutanol are independent on the temperatures, so constant parameters irrelative to temperature can meet prediction accuracy. Othmer-Tobias/Bancroft equation was also used to fit the liquid-liquid data of water/ethanol/isobutanol system, but it didnt possess the performance of predicting the liquid-liquid equilibria.The partition coefficients of dipotassium glycyrrhizinat were determined in the liquid-liquid two-phase system of water/ethanol/isobutanol and corrected by experiential equation.

结果表明：由本文的二元液液相平衡实验数据关联得到的水+异丁醇体系的相互作用参数和文献上由二元气液相平衡数据关联得到的水+乙醇体系的相互作用参数都具有预测三元液液相平衡关系的能力，而文献上由二元气液相平衡数据关联得到的乙醇+异丁醇体系的相互作用参数不具有预测三元液液相平衡关系的能力；可以用从30℃三元液液相平衡数据关联回归得到的模型参数来预测35℃时的液液相平衡关系；水+异丁醇的相互作用参数与温度关系不是很密切，计算时取与温度无关的常数即能满足关联精度要求；Othmer-Tobias和Bancroft经验方程可用于水+乙醇+异丁醇两相体系的液液相平衡关系的关联计算，但这类经验方法并不具有预测能力。

The invention belongs to the fluid measuring technical field and relates to an oil, gas and water three-phase oil well continuous gauging device, which comprises a high-efficient gas-liquid separator; the high-efficient gas-liquid separator is connected with an oil, gas and water three-phase inflowing port; a gas phase outlet of the oil, gas and water three-phase inflowing port is connected with a gas phase measuring pipeline; a gas path temperature sensor, a gas path pressure sensor and a gas path endocone flowmeter with high-frequency differential pressure transmitter are arranged on the gas phase measuring pipeline; a liquid phase outlet of the high-efficient gas-liquid separator is connected with a liquid phase measuring pipeline; a liquid path Coriolis mass flowmeter and a liquid path endocone flowmeter are arranged on the liquid phase measuring pipeline; and the cross section of the pipeline for mounting the liquid path Coriolis mass flowmeter is more than the cross section of the pipeline for mounting the liquid path endocone flowmeter.

本发明属于流体测量技术领域，涉及一种油、气、水三相油井连续计量装置，包括高效气液分离器，高效气液分离器与油、气、水三相流入口相连，其气相出口与气相测量管路相连，在气相测量管路上装有气路温度传感器、气路压力传感器、带有高频差压变送器的气路内锥流量计；高效气液分离器的液相出口与液相测量管路相连，在液相测量管路上装有液路科氏质量流量计和液路内锥流量计，安装液路科氏质量流量计的管路的截面积大于安装液路内锥流量计的管路的截面积。

We studied the structural characteristic of AR2O4 crystals within calcium ferrite type, ABO4 crystals in zircon, monazite, and scheelite type, R2M2O7 crystals in pyrochlore type and - and -type R2MoO6 crystals, and performed systematical calculations on the chemical bond parameters, thermal expansion coefficients and bulk moduli of these crystals.

对铁酸钙型AR2O4晶体、锆石、独居石和白钨矿型ABO4晶体、烧绿石型R2M2O7晶体和-和-R2MoO6晶体等复杂体系的结构进行研究，并系统的计算了各晶体组成化学键的属性以及表征晶体膨胀和压缩行为的膨胀系数和体模量等参数。

This thesis demonstrates the pre-polymers in a polymer-dispersed cholesteric liquid crystals can be polymerized into a polymer film, which can eliminate the aligning capability of the homogeneous alignment layer. Thereafter, the textures of the cholesteric liquid crystals in UV-cured region can be changed from reflective planar texture to the scattered focal conic one. Additionally, the clearing temperature of the liquid crystals can be reduced by doping with chiral dopant or monomers. The cause is the increase of the impurity concentration in LCs. In other words, if the monomers are polymerized, the clearing temperature of LCs in that region should increase due to the decrease of the impurity concentration. Therefore, impurities associated with doping with monomeric and chiral dopants cause the clearing temperature of LCs in cured region to differ from that in uncured region.

本文中，我们提出在高分子聚合物薄膜之胆固醇液晶(polymer-dispersed cholesteric liquid crystals，简称PDCLCs)中，利用紫外光使PDCLC中的单体聚合成薄膜，此即为光引致聚合反应，而该薄膜将原本在表面所作的配向膜覆盖且破坏其配向能力，使胆固醇液晶由原本反射的planar结构转换成散射的focal conic结构；另外，有关液晶材料的相变温度会由於掺杂手性分子或单体而降低，此因液晶材料内『杂质』浓度增加，而造成的液晶材料之不纯度增加，最终导致相变温度降低，若搭配上述光引致聚合反应，则由於光照区之单体聚合，使该区域单体占总材料之比例下降，即不纯度降低，进而使液晶材料之相变温度上升，该区域之相变温度与未照光区有所不同。

UDZ Series liquid level indicator of flap disassembly fast and convenient, the installation position can be arbitrary choice, free to change the direction of observation, thus instrumented great visibility; UDZ series of cost-effective liquid level was significantly higher than that used multiple sets of glass plate liquid level of cost performance; UDZ series of liquid level indicator, the sender's device, as well as the liquid level with the main transmission medium within the complete separation of the measured structural design, so that level gauge in the job has pressure (up to 320KG), toxic and inflammable conditions, with absolute safety and reliability; UDZ-3 type uses innovative design, improve the sensitivity of the sensor, and its near-zero drift FarEasTone signals and long-term stability so that it has always been at the scene consistent level instructions; sensors and the main body has a certain interval, which can be solved effectively under high-temperature liquids (up to 480 ) remote detection and control; antifrost type UDZ Series Level Gauge, are I plant the patented product (Patent No.: ZL00221022 3), guarantees that the use of cryogenic liquid level gauge is not freezing (such as liquid CO2), the effective guarantee of the level of a normal job.

UDZ系列液位计的翻板指示器拆装快捷方便，安装方位可任意选择，观察方向可随意改动，因而仪表指示的可视度很大；UDZ系列液位计的性能价格比明显高于采用多组玻璃板式液位计的性能价格比；UDZ系列液位计的指示器，发讯器、以及液位变送均与主体内被测介质完全隔离的结构设计，使液位计工作在有压（可达320KG）、有毒和易燃的工况下，具有绝对的安全性和可靠性；UDZ-3型采用了新颖设计，提高了传感器的灵敏度，其远传信号近乎零温漂和长期稳定性使其始终于现场液位指示保持一致；传感器和主体有一定的间隔，因而能有效地解决高温液体（可达480℃）远距离检测和控制；防霜型UDZ系列液位计，是我厂的专利产品（专利号：ZL00221022·3），保证了在低温液体上使用液位计不结冰（如液体CO2），有效的保证了液位计的正常工作。

With the increasing of undercooling, the mean crystal diameter of supercooled solidification microstructures shows a variation from coarse to fine, then fine to coarse, and finally fine again. The coarse crystals are developed crystals, while the fine crystals are spherical crystals with a mean diameter about 50μm.

2随着过冷度的增加，深过冷凝固的微观组织的晶粒直径呈现出"粗—细—粗—细"的变化规律，粗晶为发达的等轴枝晶，细晶则为直径约50μm的球晶。

By employing such a method, 5 series of elastomers, including natural rubbers, elastomeric polyester fibers and ethylene-octene, ethylene-methyl acrylate as well as SIS triblock copolymers, were investigated with the purpose of studying elongation induced phase structure and mobility changes of the samples. For NR samples, it was demonstrated that there exists a small amount of crystals at RT even for unelongated samples. For both NR and the soft segment of PEE, with the increase of elongation ratio, the elongation-induced crystallinity increases almost linearly in a certain region of R, in accord with the increase of the lamellar thickness of the crystals; The behavior of ethylene copolymers, in terms of elongation induced morphorpholgy changes, are quite different from NR and PEE. The crystals are found to be gradually destroyed with the increase of R, with accord with the decrease of the lamellar thickness; The motional behavior of the soft segment of SIS, changes from "liquid" to "solid", in terms of 13C NMR spin-lattice relaxation.For many of the aformented samples, the dependence of 13C spin-lattice relaxtion time T1 on R are different for different groups, indicating that the changes of mobility at MHz frequency region with elongation are different for different groups.

通过对天然橡胶、聚醚酯嵌段共聚物、乙烯-辛烯共聚物、乙烯-丙烯酸甲酯共聚物、SIS等高分子弹性体样品聚集态结构和分子运动的研究，获得了一些新的实验结果，如：给出了确切的实验证据，证明了室温下未拉伸的天然橡胶样品中存在着微量的结晶；发现随着拉伸比增加，天然橡胶及聚醚酯样品的软段部分会出现拉伸诱导的结晶，且结晶度在一定范围内呈现近似线性的增加，所形成晶片的厚度也随之逐渐增加；而乙烯共聚物随着拉伸比的增加，原有的结晶会被逐渐破坏，晶片厚度逐渐变薄，结晶中的缺陷逐渐增加；随着拉伸比的增加，SIS中PI软段部分的核磁共振弛豫行为会出现从液态到固态的转变等；在对上述多个体系的研究中，还发现不同基团的自旋-晶格弛豫时间随着拉伸比呈现不同的变化趋势，表明不同基团的高频运动随拉伸比增加有不同的变化规律。

All the compounds were isolated and identified from the bituminous coals for the first time, bis(2-ethylheptyl) terephthalate and 18-ethyl-17-(hexan-2\'-yl) docosanoic acid are new compounds.Further more, a Colourless Oil Liquid, a white acerate crystals containing some alkanes, a white tabular crystals consisting of some fatty acid esters and a white powder crystals in which some fatty acids exist were isolated and analysed by GC/MS for the first time.Through this research, a study method of"classification extract of bituminous coal- separation with silica-gel and gelatin column chromatographies- identification of the isolated compounds by FTIR, GC/MS, LC/MS, 1H NMR and 13C NMR analyses"was established and proved to be a practical approach toward separable and non-destructive identification of some organic compounds in bituminous coals for coal chemistry research.

本研究建立了&原煤分级萃取-硅胶与凝胶柱层析分离与纯化-GC/MS或LC/MS检测-FTIR、MS、1H NMR和13C NMR波谱解析&这一煤中有机化学成分的非破坏性分离与分析的研究方法，并验证该研究方法有效可行。

In this paper, research is focused on the two aspects, the study on the liquid-liquid mass transfer of butanone and dichloromethane in emulsion liquid membrane, and the study on the liquid-liquid equilibria of butanone and dichloromethane in emulsion liquid membrane.

本文是针对丁酮与二氯甲烷在乳化液膜体系中油—水相间的液液传质以及液液平衡进行实验研究。

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我们普遍有大祸降临的感觉。