查询词典 liquid crystals

In this thesis, a type of biphenyl rod-like liquid crystals and two types of triphenylene discotic liquid crystals were synthesized.

本文报道了一类新的联苯类棒状液晶化合物和两类苯并菲盘状液晶化合物的合成。

The complexes of disk - like crown ether liquid crystal with Eu have theproperties of liquid crystals and havn't the properties of fluorescence. The complexes of disk -like crown ether liquid crystal with Eu and β-diketone have the properties of fluorescence and electroluminescence.

盘状冠醚液晶Eu配合物具有液晶性质而无荧光特性；盘状冠醚液晶与EuⅢ）和β-二酮形成的配合物具有荧光特性，和电致发光性质。

This thesis demonstrates the pre-polymers in a polymer-dispersed cholesteric liquid crystals can be polymerized into a polymer film, which can eliminate the aligning capability of the homogeneous alignment layer. Thereafter, the textures of the cholesteric liquid crystals in UV-cured region can be changed from reflective planar texture to the scattered focal conic one. Additionally, the clearing temperature of the liquid crystals can be reduced by doping with chiral dopant or monomers. The cause is the increase of the impurity concentration in LCs. In other words, if the monomers are polymerized, the clearing temperature of LCs in that region should increase due to the decrease of the impurity concentration. Therefore, impurities associated with doping with monomeric and chiral dopants cause the clearing temperature of LCs in cured region to differ from that in uncured region.

本文中，我们提出在高分子聚合物薄膜之胆固醇液晶(polymer-dispersed cholesteric liquid crystals，简称PDCLCs)中，利用紫外光使PDCLC中的单体聚合成薄膜，此即为光引致聚合反应，而该薄膜将原本在表面所作的配向膜覆盖且破坏其配向能力，使胆固醇液晶由原本反射的planar结构转换成散射的focal conic结构；另外，有关液晶材料的相变温度会由於掺杂手性分子或单体而降低，此因液晶材料内『杂质』浓度增加，而造成的液晶材料之不纯度增加，最终导致相变温度降低，若搭配上述光引致聚合反应，则由於光照区之单体聚合，使该区域单体占总材料之比例下降，即不纯度降低，进而使液晶材料之相变温度上升，该区域之相变温度与未照光区有所不同。

6Is suitable only fornematic liquid crystals,and cannot be applied to cholesteric or smectic liquid crystals.

文献[6]中的广义平均场方法是针对丝状液晶而提出的。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

Then according to the different ways of mesogenic units connecting to the ladderlike main-chain, the ladderlike polysiloxane liquid crystals are classified into fishbonelike and canoelike polysiloxane liquid crystals.

介绍了梯形聚硅氧烷液晶的结构特点，根据液晶基元接枝到梯形高分子主链上的方式，将梯形聚硅氧烷液晶分为鱼骨形和划艇形两种。

Differential scanning calorimetry and polarizing microscope were used to study their liquid properties. Among them, nine are found to exhibit liquid crystal properties, and most of them displayed as heating monotropic liquid crystals. There are one or two mesophases and certain phase transition temperature,Δ H and temperature range of liquid crystal.

用差示扫描量热仪和偏光显微镜研究了其液晶性，发现其中九个配合物具有液晶性，多为升温单变液晶，有一至两个中介相，有确定的相转变温度、热焓和相变区间。

6To the case of cholesteric and smectic liquid crystals so that it can also beapplied to cholesteric and smectic liquid crystals.

为了使这一广义平均场方法具有更广泛的适用性，使之也可以应用于结构比较复杂的螺旋状和层状液晶，在本文的第一部分，我们将文献[6]中陶瑞宝教授等提出的广义平均场方法作了形式推广，经过推广后的广义平均场方法也可以应用于螺旋状和层状液晶。

The phase diagram and the structure change of W/O→bi-continuous structure→virgulate liquid crystals→lamellar liquid crystals→bi-continuous structure→O/W studied by conductivity measurement were established for this system at 25℃.

在25℃时，作出SDS/正丁醇／正庚烷/水体系中SDS和正丁醇质量比为1：1时的拟三元相图，用电导率曲线讨论了该体系由W/O型→双连续型→棒状液晶→层状液晶→双连续型→O/W型的微观结构转变。

The substrates were used in fabricating liquid crystal cells by sandwiching nematic liquid crystals and the properties of liquid crystal molecule aligned on the surface of LPP films were characterized by using polarizing microscopic and conoscopic observations.

在此基础上，利用偏光显微镜和焦锥观察的方法系统地考察了LPP膜厚度、液晶材料、烘烤温度和时间、取向剂分子末端基团以及紫外辐照强度和时间等因素对取向性能的影响，并测量了液晶分子的预倾角。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。