查询词典 liquid crystal

The complexes of disk - like crown ether liquid crystal with Eu have theproperties of liquid crystals and havn't the properties of fluorescence. The complexes of disk -like crown ether liquid crystal with Eu and β-diketone have the properties of fluorescence and electroluminescence.

盘状冠醚液晶Eu配合物具有液晶性质而无荧光特性；盘状冠醚液晶与EuⅢ）和β-二酮形成的配合物具有荧光特性，和电致发光性质。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

Liquid crystal is a kind of instar matter between completeness inerratic crystal and isotropic liquid. Its characters are between the solid crystal and the isotropic liquid.

液晶是介于完全规则的晶体和各向同性的液体之间中间态的一种物质，其特性与结构介于固态晶体与各向同性液体之间。

Differential scanning calorimetry and polarizing microscope were used to study their liquid properties. Among them, nine are found to exhibit liquid crystal properties, and most of them displayed as heating monotropic liquid crystals. There are one or two mesophases and certain phase transition temperature,Δ H and temperature range of liquid crystal.

用差示扫描量热仪和偏光显微镜研究了其液晶性，发现其中九个配合物具有液晶性，多为升温单变液晶，有一至两个中介相，有确定的相转变温度、热焓和相变区间。

To the liquid-crystal display from its structure, the principle as well as the classification has carried on the introduction, twists to the row (TN-Twisted Nematic); Ultra distortion to row (STN-Super TN); Double-decked ultra distortion to row (DSTN-Dual Scan Tortuosity Nomograph); The thin film crystal (TFT-Thin Film Transistor), introduced the thin film crystal liquid-crystal display with emphasis.

对液晶显示器从其结构，原理以及分类进行了介绍，扭曲向列型(TN-Twisted Nematic)；超扭曲向列型(STN-Super TN)；双层超扭曲向列型(DSTN-Dual Scan Tortuosity Nomograph)；薄膜晶体管型(TFT-Thin Film Transistor)，重点介绍了薄膜晶体管型液晶显示器。

The results showed that PPC was a thermotropic liquid crystal and displayed the cholesteric banded texture. The reaction conditions had the distinct effects on the propoxy content and liquid crystal property of PPC, with the reaction temperature and content of propionyl chloride increased, the degree of substitution of propoxy increased at the beginning, then trended to steady. The transition temperature and range of liquid crystalline phase were changed with the DS of propoxy, as the DS of propoxy increased, the melt point decreased, and the liquid crystalline phase transition temperature range of PPC get wider.

结果表明，产物PPC具有明显的热致液晶性能，且呈现出胆甾型液晶的彩色条纹织构；反应条件对产物丙酰基含量和液晶性能有显著影响，随反应温度提高和丙酰氯用量增加，产物丙酰基的取代度先增大，后趋于稳定；其相转变温度和温域随丙酰基取代度改变而相应变化，随丙酰基的取代度增大，产物的熔点降低，液晶温度范围变宽。

Among the five oily ingredients tested, C16~18 fatty alcohol can well facilitate the formation of liquid crystal; polar materials PPG-15 stearyl ether and stearic acid are not favorable for the formation of liquid crystal, while non-polar material white oil shows no effect on the formation of liquid crystal.

在所研究的五种油质原料中，十六~十八醇可以很好的促进液晶结构的形成；极性的 PPG-15硬脂醚与十八酸不利于液晶的形成；而非极性的白油则不影响体系液晶结构的形成。

Study PhthCS Lyotropic Cholesteric thermotropic liquid crystal phase transition was found when the concentration of more than 46%, the system of cholesteric liquid crystal phase and gel phase coexistence, gelation occurred after the formation of liquid crystal phase.

研究了PhthCS溶致胆甾液晶的热致相转变，发现当浓度超过46﹪时，体系中胆甾液晶相与凝胶相共存，凝胶化发生在液晶相形成之后。

In this paper, numerical calculations of magnetically induced twist effect in planar nematic liquid crystal are presented. The transmission of polarized light passing through magnetically induced twist distribution in planar nematic liquid crystal is calculated with "4-4" matrix algorithm. On the experimental side, the optical phase retardation method is used to detect the magnetically induced twist effect in planar nematic liquid crystal 5CB(4′-n-penty1-4-cyanobiphenyl) at 27℃.

对平行排列5CB(4′-n-penty1-4-cyanobinpheny1)丝状液晶在静磁场中扭曲变形做了严格的数值解，给出了严格分布情况；利用光学&4*4&矩阵算法，计算了线偏振光在严格分布下的传输情况；在实验方面，应用光学相位延迟法对平行排列5CB丝状液晶在静磁场中(温度27℃)线偏振光的通过情况进行了测量。

Third, the physical indicators: transparent liquid or slightly yellow liquid, density (g/cm3): 1.0 ± 0.02, PH = 9.0 ± 0.02 d, the scope of application: optical glass, diamond, mobile glass, liquid crystal display, liquid crystal glass, optical lenses , optical lenses, glass instrument, P3 wash Lilongwe, silicon and so on.

三、物理指标：透明液体或微黄色液体，密度（g/cm3）：1.0±0.02，PH=9.0±0.02 四、适用范围：光学玻璃、水钻、手机玻璃、液晶显示屏、液晶玻璃、光学镜片、光学透镜、仪表玻璃、P3洗利隆、硅片等。

Plunder melds and run with this jewel!

掠夺melds和运行与此宝石！

My dream is to be a crazy growing tree and extend at the edge between the city and the forest.

此刻，也许正是在通往天国的路上，我体验着这白色的晕旋。