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The copolymerization of cycloolefin and α-olefin, and structure of the obtained polymer are significantly affected by the structure and symmetry of metallocene catalysts, electronic effect and steric hindrance of ligands.

着重介绍了加成聚合法中茂金属催化剂的结构对称性、配体的电子和体积效应、反应条件等对聚合活性、产物组成与序列分布及相关热性能的影响。

The copolymerization of cycloolefin and α-olefin,and the structure of the obtained polymer are significantly affected by the structure and symmetry of metallocene catalysts ,electronic effect and steric hindrance of ligands.

着重介绍了加成聚合法中茂金属催化剂的结构对称性、配体的电子和体积效应、反应条件等对聚合活性、产物组成与序列分布及相关热性能的影响。

The thermolysis of the isomerized products derived from norbornadiene-coordinated carbonyl iron complexes gave two sorts of the thermolytic products based on different substituents on the olefin ligands. One is the corresponding diiron dimer complex, and the other is the complex in which the C-C bond of the cycloolefin ligand is broken.

以降冰片二烯三羰基铁络合物衍生出来铁卡宾络合物的异构化产物的热解，随着烯烃配体上取代基的不同，而分别得到了络合物发生二聚和烯烃配体发生碳碳键断裂的两类热解产物。

The amino acid histidine and cysteine are the most frequently occurring ligands of zinc in physiological processes.

但在测定生物活体内的游离Zn~(2+)的浓度方面仍存在一定的困难。

The cis novel bisoxazoline ligands L1-L4 have been synthesized through the treatment of new cis dihydroxy diamide with p-toluenesulfonyl chloride in the presence of catalytic quantity of 4--pyridine, and the cis dihydroxy diamide could be achieved from the condensation of the amino alcohols and cis cyclopropane dicarbonyl chloride prepared via oxidation and halogenation from cis-2,2-dimethyl-3-formylcyclopropanecarboxylate with DCC.

我们以蒈醛酸内酯为起始原料，经过氧化反应、酰氯化反应得到顺式环丙烷二酰氯，然后在二环己基碳二亚胺的催化下与相应的氨基醇反应合成了顺式二羟基酰胺，再用对甲苯磺酰氯将羟基活化，最后在二甲氨基吡啶的催化下关环合成顺式双噁唑啉配体L1～L4。

Meanwhile the interesting structures of the five azido-bridged complexes containing a series of bi diazine ligands indicate the varieties of azido ions in designing polymeric archi

2五个高维叠氮桥cd配合物(10一14)：化合物10、n为不同桥联方式的二维(6，3)层状结构，而12一14具有相同的三维(10，3)聚合网络结构。

The fluorescence properties of complexes of europium with β-diketone and terbium with benzoic acid and its derivatives were analyzed and the synergic effect of the second ligand was illustrated from the energy matching of the minimum triplet state of ligands and the resonance energy level of rare earth ions.

提出了掺杂离子荧光增强效应的机理。 4。首次采用ab initio CIS方法，在劈裂价层基组3—21G水平上对各配体进行了量化计算，系统分析了前线分子轨道特征和激发态的能级，从配体最低激发三重态能级与稀土离子共振能级的能级匹配，分析了铕与β-二酮的配合物的荧光性能和铽与苯甲酸系列衍生物的配合物的荧光性能，解释了第二配体的协同效应。

As a complicated multidentate ligand, theβ-diketone ligands and their derivatives have played a significant role in the realm of modern coordination chemistry, crystal engineering, supramolecular chemistry and biomedicine.

β-二酮类衍生配体作为一种优良的含氧配体，一直以来都是现代配位化学、晶体工程和材料科学、超分子化学、生物医学等领域的研究热点之一。

Some of the complexes withβ-diketone derive ligands, which potential applicated in optical, electricity, magnetism, absorption, catalysis, ion exchange, gas storage and so forth.

此类配体所构筑的各式各样的配合物在光、电、磁、吸附、催化、离子交换、气体储存、分子载体、生物活性、荧光器件材料等方面具有一定的应用价值。

Three rare earth β-diketone complexes: Gd3BIPY, Sm3BIPY, La3BIPY were synthesized by a precipitation method with a mixture of ethanol and water using dibenzoylmethane and 2,2'-dipyridyl as the ligands.

以二苯甲酰甲烷和2，2'-联二吡啶为配体，采用乙醇－水溶液析出法合成了三种稀土－β－二酮配合物：Gd3BIPY、Sm3BIPY、La3BIPY。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了