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With good stability and high reactivity, pyridine-based tridentate N-ligands have been widely used in the fields of coordination chemistry, organic synthesis and homogeneous catalysis.

吡啶基含氮三齿配体具有良好的稳定性和反应活性，在配位化学，有机合成和均相催化中均得到了广泛的应用。

Herein, using grafting strategy we have developed a new kind of sulfamide-amine alcohol ligands by grafting a activator to the traditional aminoalcohols, which led to more rigid tridentate coordination model and benefit to the control of chiral surrounding.

本文提出一种嫁接策略设计新的手性配体，即在传统的氨醇配体上嫁接上一个活化剂就可以得到一类新型的手性磺酰胺-氨醇配体。

The central Ni ions are coordinated by six nitrogen atoms from the two I single tridentate ligands L and possess distorted octahedral geometry.

中心镍离子与两个配体上的六个氮原子配位构成变形八面体结构。

The ligands are tridentate and bridge across the Ag〓 triangles with bridging S atoms occupying all three edges of these trans-oriented triangles.

三齿配体通过硫原子形成了跨过Ag〓三角平面的三条边的桥键。

The crystal consists of two similar but independent molecules in the asymmetric unit and the Ce ion coordinated toward ten donor atoms, six of which belong to the nitrogen atoms of two tridentate ligands and four oxygen atoms from two bidentate picrates.

晶体中一个不对称单元内有两个结晶学上独立的分子，这两个分子的构型基本相同，中心Ce3＋均与两个三齿配位的配体及两个双齿配位的苦味酸根配位，配位数为10。

All of the tripodal schiff base ligands and their complexes were characterized.

以三乙醇胺、巯基苯胺、巯基乙胺为初始原料，设计合成了六个三脚架结构的化合物，其合成路线如下：三乙醇胺与氯化亚砜反应得到三(2-氯乙基)胺(1)，然后与巯基苯胺或巯基乙胺在碱性条件下反应生成三脚架结构的三{[2-(2-氨基苯基)硫代]乙基}胺(2)或三{[2-(2-氨基乙基)硫代]乙基}胺(3)，然后再与水杨醛、2-甲酰基-8-羟基喹啉(8)、2-甲酰基-8-苄氧基喹啉(7)反应得到六种新型的含硫西佛碱化合

Also, the measure of the electrochemistry shows that, forall copper complexes, their redox potential data are similar with those reported insome similitude copper complexes with tripodal ligands.

另外，所有铜配合物的电化学测定表明，它们的氧化还原电位与报道过的含有同类型三脚架配体的铜配合物相似。

Furthermore, tripodal ligands and their complexes represent excellent capability and fine application prospect in many aspects, such as coordination chemistry, electrochemistry, medicine, catalytic chemistry, biochemistry, and supramolecular chemistry.

三脚架结构的化合物及其配合物在配位化学、电化学、医学、催化化学、生物化学、超分子化学等方面均表现出优良的性能和很好的应用前景。

In the last few years, the tripodal ligands bearing nitrogen atoms have drown much attention because of their polydentate, flexility and ease to synthesize.

近年来，含氮三脚架配体因其多配位点、半刚性及易合成等特点，对其稀土配合物的发光研究引起了人们的广泛兴趣。

For thecopper and silver complexes, tripodal ligands exhibit rich coordination forms, andthe coppers exhibit different geometry such as square-plan, square pyramidal, andtrigonal bipyramidally geometry.

在铜、银配合物中，三脚架配体表现出多种配位方式，铜离子有平面四边形、四方锥、三角双锥等不同的空间构型。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了