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Synthesis, molecular structure and magnetic properties of tetranuclear copper complexes with pendant-arm macrocyclic ligands.

主研方向：金属离子导向的分子自组装研究，新型大环配体的设计与合成及其离子和分子识别研究，新药开发与铂药物筛选。

Three new Cu〓 complexes with quinoline-based new monothioether ligands have been synthesized and characterized, and they take tetranuclear, 1D and 2D structures.

发现三个配合物中都存在Cu…Cu相互作用，皆含有扭椅式的Cu〓I〓骨架，配体倾向于两种模式与Cu〓配位。

Six new ligands and 2 mononuclear,5 binuclear,8 tetranuclear complexes all of which are new havebeen synthesised and characterized by elementalanalysis,electric conductance and IR,UV-Vis spactr-oscopic methods.

本文主要研究多核配合物中的磁交换相互作用。共合成了6个新配体，2个单核。5个双核和8个四核配合物，并用元素分析，红外，紫外一可见。

We have studiedthe coordination water-substituted reactions and the phase-transferchemistry of dozens of trinuclear or tetranuclear sandwich-typePOMs and found that organic molecules or polymers can becoordinated to these polyanions after dehydration, thus more thanone hundred coordinated products are obtained, indicating that thesepolyanions are excellent ligands in organic solvents.

我们首次对夹心三、四核等几十种化合物中配位水进行了配位水取代反应及相转移化学研究，脱水后可配位有机分子或有机高分子，得到上百种配位产物，因此在有机溶剂中它们是优秀的配体。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

Both were measured using X-ray single crystal diffraction. For the crystal in MeOH, X-ray in compound. In an ansymmetry unit, there are two Cu atoms, two ligands and twosolvent methanol molecules. The tetranuclear complex contains two kinds of Cucenter.

本文在MeOH中得到了阶梯型四核铜骨架配合物；在THF中得到了扭曲的立方烷型四核铜骨架配合物，经晶体结构分析表明，阶梯型四核铜骨架配合物是由两个Cu2被μ~3-剪刀撑二个醇羟基O所连接形成中心对称的二铜二聚体结构。

The forming mechanisms of thermolytic products were also proposed on the basis of the recombination of free radicals and oxidation of the organic ligands.

本文还对三（2，4-戊二酮）合铱主要热分解产物的自由基生成机理进行了探讨。

The key point for preparing the isolated 1D metal driven nanowires is the non-stoichemetric additions of metal ions and thiolic ligands.

其中，金属离子与巯基乙酸的非等量反应是分离状态螺旋结构的纳米带形成的主要原因。

A series of novel amphipathic macrocyclic polyamine ligands derived from iminodiacetic acid and diethylene triamine have been synthesized and characterized by MS, 1H NMR, IR spectra and elemental analysis.

以亚胺基二乙酸和二乙撑三胺为原料，通过关环等反应合成了一类侧链含有羟基的新型两亲性大环多胺。

All carboxylates from acetate ligands coordinated in tridentate mode and bridge two M centers in adjacent different sheets.

而通过乙酸根配体以三齿模式桥联相邻近的毯子状网络结构的两个金属离子而形成三维网状结构。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了