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The results show thatthe substitutions containing sulfur atom in the pyrazole ring remarkably affectthe steric and electronic properties of the pyrazole ligands.

因此，我们研究了吡唑环上带上S原子取代基对形成双吡唑烷配体及其与VIB金属羰基配合物的光化学反应的影响。

Adjacent helical chains are racemic. The Ag atom is linked to two nitrogen atoms of the 2-pyridyl and 4'-pyridyl groups from two different 2,4'-bpy ligands as well as to the oxygen atom of the counterion. In 17 and 19, the adjacent helical chains are linked to wavy two-dimensional network structures by the nitrate counterions.

相邻的螺旋链间是外消旋的，Ag 原子与分别来自两个不同2，4'-联吡啶的2-吡啶基和4'-吡啶基的氮原子以及阴离子的氧原子配位，在配合物17和19中，相邻聚合螺旋链被硝酸根离子桥连接起来，变成了一个波浪形的二维网络结构；配合物18是首次通过无桥连配体支持的Ag ××× Ag键将相邻螺旋链连接成二维非穿插的网络结构。

In comparison with 〓ligand the substitution of one phenyl groupby pyridyl ligand renders this cluster a self defocusing effect different with previousbutterfly shaped clusters, so the peripheral ligands may also play an important role onthe NLO effects.

配体中的吡啶取代基取代苯基的微小改变使标题化合物具有了不同于以往蝴蝶状簇合物的非线性折射性质，即表现为自散焦，从而说明外围配体对非线性也具有大的影响作用。

The X-ray crystal structure analysis of the complexes shows that all lanthanidecomplexes exhibit a tripodal ligand coordination mode, with three imino nitrogenfrom benzimidazolyl and pyridyl group, and one amino nitrogen atoms as donors.The ligands show two kinds of configuration: the fan-like and the pincer-like. Bothintra- and intermolecular π-π interactions are found in these complexes.

晶体结果表明，在所有的稀土配合物中，三脚架配体均用三个支脚上的苯并咪唑、吡啶环氮原子及一个顶端的氮原子和稀土离子进行配位，表现出三脚架式配位方式，同时，三脚架配体有风扇形及钳子形两种空间配位构型，并形成了分子内及分子间的π-π堆积作用。

It follows that the de-protonic reaction of hydroxide group for PVA had taken place in above solution, and the coordination group for deprotonic oxygen of PVA had produced more. These ligands interact with some Fe3+ of ferric hydroxide while the ferric hydroxide in new emergence is forming,causing the formation of Fe-PVA coordination polymer-the composition of the reddish brown resinoid substance.

推定PVA部分羟基在上述条件下发生脱质子反应而提供L-配位体，Fe盐水解生成初生Fe3的Fe3+，它既有空轨道，又有较强的正电场，故能吸引PVA高分子配位体L-上的氧而形成O→Fe配位键，从而发生L-与Fe3+离子间的交联反应，生成多核Fe-PVA配位聚合物而析出红棕色树胶状物。

Synthesis and characterization of tridentate chiral ligands, a series of Schiff-bases which are synthesized by salicylaldehyde, 2-pyridinecarboxaldehyde and amino alcohols derived from the amino acids without coordination group on side chain.

由侧链不带配位基团的天然氨基酸合成的氨基醇与水杨醛及2-吡啶醛缩合的Schiff-Base等三齿配体的合成与结构分析。

A few spiro ligands have been successfully synthesized and applied in asymmetric catalysis .

手性螺环配体的合成及其在不对称催化反应中的应用是不对称合成和催化研究中重要的研究领域之一，一些手性螺环配体被合成出来并成功地应用于不对称催化反应中。

Work 工作:(1) feasible process development for high-pure tetraalkyphosphonium salt as catalysts for polymerizations, potential sale 2-4 million us$;(2) simple and feasible preparation process for phosphonium salt as ionic liquids, biocides and phase transfer catalysts;(3) new and industrially feasible processes for highly sterically hindered alkylphosphines as catalyst ligands, these include tricyclohexyl-phosphine, phosphorinanes and dsmphos2,3- bis(9-phosphabicyclononylbutane;(4) sterically hindered dialkylphosphinic acid as new generation of co/ni extractant;(5) alkylphosphonium wittig reagents and the wittig reactions with them;(6) exploration of the application of borane chemistry in the synthesis of highly sterocally hindered organophosphines;(7) customer preparation of samples of a variety of organophosphorus compounds for customers all over the world.

用作高分子聚合反应催化剂的高纯度四烷基瞵盐的实用生产流程。产品销售前景 2-4 百万美元；(2)用作离子化液体，杀菌剂和相转移催化剂的烷基瞵盐的简单实用合成方法；(3)高位阻烷基磷化氢催化剂配体的工业实用合成路线的研究，这包括，三环己烷基磷， phosphorinanes 和 dsmphos 2，3-bis(9-phosphabicyclononylbutane ；(4)高位阻二烷基膦酸金属萃取剂的工业实用合成路线的研究；(5)烷基膦 wittig 反应试剂的研究；(6)硼化学在高位阻烷基磷化氢合成中的应用；(7)为世界各地提供顾客合成服务。

Many chemists focus on the design and syntheses of small molecular ligands of biological receptors.

用于研究生物受体的有机小分子配体的分子设计和合成已成为许多化学家研究的焦点。

After treated with CuAz, the hydrogen from phenolic hydroxyl group in lignin was replaced by Cu from treated solution, being N-Cu-O complex, or two of the ammonia ligands of the tetrammine complex were replaced by copper-oxygen bonding from hydroxyl, being Cu-N-lignin complex.

在铜唑防腐剂处理后，木质素上酚羟基的H可以被Cu取代，形成&N-Cu-O&形式的络合物；或者处理液中四氨络合物中的2个氨配体被羟基取代，形成芳香族-铜络合物。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了