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Recent data suggested that Notch receptors and their membrane-bound ligands Delta and Serrate were involved in both patterning and cell fate determination during odontogenesis.

越来越多的证据表明:Notch途径参与了牙齿发育的各个过程,包括牙齿早期发育细胞的增殖、分化过程,决定细胞的定向分化方向,决定成牙本质细胞与成釉细胞的终末分化命运,并且参与牙齿炎症损伤后修复过程,与第三期牙本质的形成有关。

Recent advances in the application of chiral nitrogen-containing ligands in asymmetric addition reactions to imines with organolithium reagents are reviewed.

综述了近10余年来手性含氮配体在有机锂试剂对亚胺不对称加成反应中应用的研究进展。

Research progresses in the asymmetric addition of organozinc reagent s to imines in the recent decade are reviewed according to the kinds of chiral ligands.

亚胺的催化不对称加成反应是近年来不对称催化反应中的热点研究领域,从手性配体类型的角度总结了近10余年来有机锌试剂在亚胺不对称加成反应中的应用进展。

The new oxalamide bridging ligands N, N'-bis (4-hydroxy-3-methoxy-benzyl) oxalamide (H4LB) was designed and synthesized.

设计合成一种新型对称的草酰胺桥联配体:N,N'-二(4-羟基-3-甲氧基苯甲基)草酰胺配体(H4LB)。

To improve the yield of an Amide-type Tripodal Ligand and investigate its coordination with rare earth ion under mild condition,a series of Amide-type Tripodal Ligands(L1—L4) have been prepared by the reactions of nitrilotriacetic acid and oxalyl chloride with four kinds of amides,respectively.

为了提高酰胺型三脚架型配体的产率,进一步研究其与稀土离子的配位形式及配合物的荧光性能,以氨三乙酸为母体,草酰氯为氯化试剂,与4种胺在较温和的条件下合成了具有三脚架型结构的配体(L1—L4),并考察了实验条件、反应温度、反应体系溶剂、缚酸剂、反应时间及催化剂对反应产率的影响。

Kinetic spectrophotometric method for the determinationof trace nitrilotriacetic acid;2. To improve the yield of an Amide-type Tripodal Ligand and investigate its coordination with rare earth ion under mild condition,a series of Amide-type Tripodal Ligands(L1—L4) have been prepared by the reactions of nitrilotriacetic acid and oxalyl chloride with four kinds of amides,respectively.

为了提高酰胺型三脚架型配体的产率,进一步研究其与稀土离子的配位形式及配合物的荧光性能,以氨三乙酸为母体,草酰氯为氯化试剂,与4种胺在较温和的条件下合成了具有三脚架型结构的配体(L1—L4),并考察了实验条件、反应温度、反应体系溶剂、缚酸剂、反应时间及催化剂对反应产率的影响。

Through condensing o-aminobenzoic acid, ethyl oxalyl chloride and ethylenediamine(or 1,2-propylenediamine), two new ligands N-benzoato-N′-(2- aminoethyl)oxamido(H3oxbe) and N-benzoato-N-(2-amino-2-methylethyl)oxamido(H3oxbt) have been synthesized. Their mononuclear complexes Na·1.5H2O and Na·1.5H2O have also been obtained.

2以邻氨基苯甲酸、草酸乙酯酰氯和乙二胺(或1,2-丙二胺)缩合制得了两种具有不对称草酰胺结构配体N-(2-苯甲酰基)-N&-(2-氨乙基)草酰胺(H3oxbe)和N-(2-苯甲酰基)-N&-(2-氨丙基)草酰胺(H3oxbt),并得到了它们的单核配合物:Na·1.5H2O和Na·1.5H2O。

Equilibrium constants for reactions of ZnTPP (parasubstituted zinc tetraphenylporphyrins) with ligands of Schiff base complex in CH2Cl2 and several other solvents have been measured by visible spectral techniques, and determined by the method of Rose-Drago.

用紫外-可见光谱和Rose-Drago数据处理方法对多种新型空间不对称含咪唑基团金属Schiff碱配合物与取代四苯基卟啉锌轴向配位反应平衡常数进行了测量。

These results suggested that HDA ligands can provide the higher degree of surface passivation.

这些实验结果表示HDA提供了更高程度的表面钝化。

Researches on the transition metal complexes with polypyridyl bridging ligands, such asbipyridine, phenanthroline and their derivatives or analogues, have received considerableinterest in recent years.

近年来,联吡啶和邻菲啰啉及其衍生物等多吡啶化合物的过渡金属配合物引起了人们的极大兴趣。

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在对危险的南部地区访问时,他斥责什叶派民兵领导人对中央集权的挑衅行为。

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