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It isconfirmed by ~1H NMR,~(13)C NMR and X-ray crystallographic analysis that complexes 60-63are monopyridine complexes and show distorted square pyramid geometries; complexes 64and 65 are bispyridine complexes and show pseudo-octahedral geometries, where twopyridine ligands are in cis arrangement and trans to the NHC and the benzylidene ligandrespectively, the bond length between ruthenium and pyridine ligand trans to the benzylideneligand is 16 pm longer than the bond length between ruthenium and pyridine ligand trans tothe NHC ligand.

1H NMR、~(13)C NMR及X射线单晶衍射分析证明，配合物60-63是单吡啶衍生物配位的钌卡宾配合物，具有变形的四方锥构型；配合物64、65为双吡啶衍生物配位的钌卡宾配合物，具有变形的八面体构型，其中两个顺式配位的吡啶衍生物分别处于氮杂环卡宾和苯亚甲基的反位，处于苯亚甲基反位的吡啶衍生物对应的钌-氮键长要比处于氮杂环卡宾反位的长出16 pm。

The protonolysis of carbon-palladium bond with the assistance of bidentate nitrogen-containing ligands is the key step in this tandem reaction.

本论文立足于小组以前工作，以炔烃的乙酰氧钯化作为启动反应的方式，尝试发展Pd催化的反应和再生两价钯的新方法。

In this thesis, the three series of P, O and P, N bidentate ligands chelated palladium complexes ￡40-46} were designed and synthesized for Suziki cross-coupling reaction.

研究了它们对Suzuki偶联反应的催化作用，优化了这些催化剂在联苯类化合物合成中的反应条件。

Structural analyses reveal that all species consist of a pair of hetetrometallic atoms triplybridged by bidentate pivalate ligands.

它们共同的结构特征是异金属离子间均由三个双齿的羧基桥连，在四核的化合物20和21中两个稀土离子通过两个双齿羧基相连。

A new series of Ni complexes [NiBr2] bearing bidentate amino-oxazoline ligands have been synthesized and applied for polymerization of styrene.

系列新的胺基-恶唑啉双牙配位基及其镍金属错合物，[NiBr2] 4，已被成功地合成出来，并且可应用在苯乙烯的聚合反应上。

The spectral data suggest that intramolecular carbonyl oxygen to tin coordination in 1 is existent and is not allowedin order to accommodate two and three bidentate dithiocarbamate ligands in 3 and 4 respectively.

波谱数据表明化合物1和2存在着分子内羰基氧原子对锡原子的配位，而在化合物3和4中这一配位则被两个或三个双齿二硫代氨基甲酸配体所替代。

Metal-Organic coordination polymers are formed by self-assemblythrough coordination bonds between bidentate or multbentate organic ligands and central metal ions.

金属有机配位聚合物是通过含给电子基团的双齿或多齿有机配体和一种或几种中心金属离子通过配位键自组装而形成的。

Chiral N, P bidentate ligands, were used for the first time in Ag -catalyzed asymmetric addition of allyltributyltin to benzaldehyde.

在此催化体系中，MAP系列氮膦配体的不对称诱导性能明显好于H〓-MAP系列的氮膦配体。

Optically active axially dissymmetric binaphthyl derivatives have been extensively used as excellent chiral ligands in asymmetric catalysis and chiral recognition.

光学活性的联萘衍生物以其独特的立体化学性质作为优异的C2轴手性诱导源，已被广泛地应用到不对称催化反应和手性识别中。

A series of novel chiral aminophosphine ligands with binaphthyl backbone and partially reduced binaphthyl backbone were synthesized from optically pure NOBIN and H〓-NOBIN respectively. The effects of binaphthyl backbone and substitutes at the phosphorous atom on Pd (0)-catalyzed allylation of racemic 1, 3-dipheylprop-2-en-1-yl acetate with dimethyl malonate were systematically investigated.

从NOBIN出发合成了一系列膦上含有不同取代基的氮膦配体MAPs以及含有被部分还原的联萘骨架的氮膦配体H〓-MAPs，将此两类配体运用于钯催化的乙酸1，3-二苯基烯丙基酯与丙二酸二甲酯的反应中，考查了膦上取代基和配体骨架对反应的影响。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。