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Both T mand T i of all the ligands change regulary with the increase of the end alkoxy group length and when the flexible spacer unit in the ligand gets longer.

它们的熔点和液晶态的清亮点随分子中末端烷氧基增大和柔性间隔段长度增加呈规律性变化。

A new series of the ligands of liquid crystal polymers with T-shaped two-dimensionl mesogens was synthesied by solution condensation polymerization by using 4,4'-(α,ω-alkylenedioyloxy)-dibenzol dichlorids with 2,4-dihydroxy-4 '-alkoxyl azobenzene as the monomers.

摘 要 以4，4′-二苯甲氯和2，4-二羟基-4′-烷氧基偶氮苯为单体，通过溶液聚合，合成了一系列新的含T-型二维液晶基元的液晶高分子配体。

A new series of the ligands of liquid crystal polymers with T-shaped two-dimensionl mesogens was synthesied by solution condensation polymerization by using 4,4'-(,-alkylenedioyloxy)-dibenzol dichlorids with 2,4-dihydroxy-4'-alkoxyl azobenzene as the monomers.

以4，4′-二苯甲酰氯和2，4-二羟基-4′-烷氧基偶氮苯为单体，通过溶液聚合，合成了一系列新的含T-型二维液晶基元的液晶高分子配体。

These ligands can be roughly divided into two groups: those in which the camphor is annulated in the 2,3-positions to the -face of the pyridine ring and those in which the pyridine is contained as a pendent on the C2 or C3 of the camphor framework.

这些配大体可以分为两类：这其中是空心的樟脑2，3-阵地到对面的吡啶环与那些其中吡啶载于作为悬吊的樟脑的C2或C3的架构。

The coordination mode of La can be described as a distorted aquare antiprism, which was completed by two oxygen atoms from one oxalate, four oxygen atoms from four different PDC ligands, and two oxygen atoms from two water molecules.

La呈现四方反棱柱体的配位模式，分别和2个来自同一个草酸配体的氧原子、4个来自4个PDC配体的氧原子以及2个来自2个配位水分子的氧原子配位。

The develop-ment of ligands expands the scope of substrates, improves reaction selectivity and realizes the amination of the cheaper and available aryl chlorides. The application of weak base improves the compatibility of functional groups. Pd-catalyzed amination of aryl halides are used in the synthesis of arylamine.

配体的发展扩展了底物的适用范围，提高了反应的选择性，实现了廉价易得的氯代芳烃的胺化，弱碱的使用提高了官能团的兼容性，因此Pd催化芳胺化广泛应用于合成芳胺类化合物。

The formation of metal complexes causes a large bathochromic shift of the absorption bands and an increase in the molar extinction coefficient compared with the free ligands.

并从一些金属络合物的红外光谱中C(8)=O吸收峰在络合前后的变化，进一步增强了对配位结构的了解。

Chapter VI: Nineteen novel ligands containg triazole and benzotriazole are designed and synthesized. Although we did not get the single crystal of complexes, we get five single crystals of compounds and test the biological activity of all the compounds.

第六章：设计、合成并表征了两个系列共19个新型的三氮唑配体，虽然没有得到配合物的单晶，但是我们得到了其中5个化合物的单晶，并初步测试了所有化合物的生物活性。

Three kinds of small molecular copper and zinc superoxide dismutase mimics were synthesized with N, N-bis (benzimidazol-2-ylmethyl) amine (N3), N, N-bis (benzimidazol-2-ylmethyl) methylamine(MN3) and N,N-bis (benzimidazol-2-ylmethyl) benzylamine(BN3) as ligands. The com-plexes were characterized by UV, IR and element analysis and the structures were proposed.

模拟铜一锌超氧化物歧化酶的活性中心，以二(2-苯并咪唑)丙烷为桥、二(2-苯并咪唑亚甲基)胺(N3)、二(2-苯并咪唑亚甲基)甲胺(MN3)及二(2-苯并咪唑亚甲基)苄胺(BN3)为配体合成了3种异双核的小分子模型化合物，并进行了紫外、红外表征及元素分析，推测了可能的结构。

Stability of the ruthenium benzylidene complexes can be enhanced by introducing thechelating ligands.

通过螯合配位提高了钌卡宾配合物的稳定性。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了