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We also tested the ligands in the asymmetric epoxide ring opening reaction with thiophenol, and as high as 67%ee was gained while using L7. 3. Studies on the reaction of α-hydroxyketone with nitroalkene.

此外我们还初步尝试了将配体应用于催化苯硫酚对环氧的不对称开环反应中，当使用甲基取代H8-BINOL衍生的配体L7时最高取得了67%ee的结果。

Coordination compounds with thiourea and its derivatives as ligands have been applied widely, including used as nonlinear optical materials, which is a research hotspot.

以硫脲及其衍生物为配体的配合物的研究是非线性光学晶体材料研究的一个热点。

According to the H NMRstudy, it was found that the protons on the cyclopentadienyl ring of 〓 were not splitted, but when one proton on the cyclopentadienylring was substituted by methyl, that is in〓 complexes, thefour protons on the ring were splitted into four groups,the 〓 between the onesignal and the others is large, the total splitting is over 2ppm. The splittings werealso affected by the halides linked with the titanium, they increase according to theorder of CI, Br, I. By the study of the 〓 Sn NMR, it is found that the chemicalshifts of 〓 are present in low field. It is assume that the large space strain causesthe angles of the tin linked with ligands deviate from the normal tetrahedral anglesresults low field shift for 〓Sn. And by MS study,there were no molecular ions for 〓 complexes in the spectra. However, for 〓 when X=CI,Br,NCO and Ar is tolyl or phenyl group,there were molecular ions,but theirabundances were very small,and no that for the iodide was found.

钛上的卤素对茂环氢的裂分也有影响，依〓，Br，I顺序，卤素对茂环氢的裂分依次加大；通过对〓的研究发现，以上这些化合物〓的化学位移都出现在低场，认为大的空间张力造成的锡的键角偏离正常的锡的四面体键角是造成〓化学位移出现在低场的原因；对这些化合物质谱的研究发现，〓系列化合物得不到分子离子峰，而〓系列的化合物，当X=〓，NCO和苯环上不带取代基或只带甲基时，则出现分子离子峰，但丰度很低，而相应的碘化物和其它化合物则没出现分子离子峰。

Tortile octagonal Zn_4O_4 building of μ2-O is edge-bridged by four carboxylates to give a novel topology structure. Viewed along the c zxis, there are channels(10.8A×8.15A)in the structure filled by L1 ligands.

同时，以L1为第一配体，均苯四酸为第二配体与Zn合成了另一个具有新颖结构的三维配位聚合物 [Zn_2(L1)_(0.5)_2]2。

The central atom is bridged to each ofthe two external copper atoms through triple triazole ligands.

在5的配阳离子中，中心铜离子处在反对称中心与六个admtrz桥的六个氮原子形成拉长的八面体配位环境。

Besides, vicinal diamines and hydroxyamines were also synthesized in high enantioselectivities, which should be useful in asymmetric synthesis as optically active ligands.

同时，也高对映选择性地合成了一系列不对称反应中有用的手性邻二胺和邻羟胺化合物。

By virtue of the coordination of Cr2L (L = CO; PPh3; C3H5 BF4-) with N-vinylcarbazole, acenaphthylene and their derivatives as organic ligands, a series of organometallic complexes have been synthesized. Their spectra characterization and X-ray diffraction analysis have been performed. It is found that this kind of complexes possesses an electronic structure with highly extensive π- delocalization.

以N－乙烯基咔唑、苊烯及其衍生物作为配体与金属基团Cr2L(L = CO； PPh3； C3H5 BF4-)配位，合成了一系金属有机配合物，并对其进行了光谱表征和单晶X射线衍射分析，发现该类配合物具有高度离域的电子结构。

Although the acidity of some phenolic ligands, Lascorbic acid and 8 quinolinol is weak, the yield of adipic acid is still high.

尽管一些酚类配体、L抗坏血酸和 8 羟基喹啉的酸性较弱，但己二酸的产率仍然很高。

Both apoptosis-inducing ligands and death receptors exist physiologically and/or pathologically in the body as membrane bound and soluble forms that behave agonistically or antagonistically to exert complicated immunological modulation.

无论是凋亡诱导配体，还是其相应的受体，在不同的条件下均可存在膜型和可溶型，两种形式相互协同或相互拮抗发挥复杂的免疫调节作用。

The carboxyl groups of HPAM replace the H〓O ligands of AlCA, which results in the formation of HPAM-AlCA gel.

首次用实验证明了：HPAM大分子中与AlCA反应的基团为羧基，酰胺基不参与交联反应。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。