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The catalytic activity of the mono- and bi-nuclear complexes, and unsymetric complex 〓〓 MeNTB =tris ( N-methylbenzimidazol-2-ylmethyl amine and tetranuclear complex 〓L = N, N, N', N'-tetrakis (N-methylbenzimidazol-2-ylmethyl-1,4-diaminobutane for oxidation of hexane was examined. Thedi-iron complexes with one exchangeable monodentate ligand and unsym-metric(μ-carboxylato) diiron complex exhibit high catalytic ac-tivity, while mononuclear Fe complex are inactive.

这些单核、双核化合物、不对称化合物〓-三氨和四核化合物〓四-1，4-丁二胺催化氧化环己烷的催化活性被测试，结果表明含有可交换配体氧桥联双核Fe化合物和不对称双核Fe化合物表现很高的催化活性，而单核的Fe化合物是非催化活性的。

The chiralMn complexes, especially Jacobsenscatalyst, display high enantioselectivity for asymmetric epoxidation of conjugated cis-di-, tri-and some tetrasubstituted prochiral alkenes in the NaClO biphasic system, but the epoxidationreaction generally requires a long reaction time even in the presence of an axial ligand.

在NaClO两相体系中，手性Mn配合物，尤其是Jacobsen催化剂，对共轭顺式二取代、三取代和部分四取代烯烃的不对称环氧化具有高的对映选择性，然而即使存在轴向配体，环氧化反应也通常需要长的反应时间。

The chiralMn complexes, especially Jacobsen\'scatalyst, display high enantioselectivity for asymmetric epoxidation of conjugated cis-di-, tri-and some tetrasubstituted prochiral alkenes in the NaClO biphasic system, but the epoxidationreaction generally requires a long reaction time even in the presence of an axial ligand.

在NaClO两相体系中，手性Mn配合物，尤其是Jacobsen催化剂，对共轭顺式二取代、三取代和部分四取代烯烃的不对称环氧化具有高的对映选择性，然而即使存在轴向配体，环氧化反应也通常需要长的反应时间。

The ligand of HL3 differs from HL1 and HL2 in having an ethyl group not methyl group on the triazole ring and having a thienyl group on the substituted amino group, meanwhile there are two kinds of 3 molecules in the crystal structure.

在化合物3中配体与化合物1和化合物2的不同，同时其一个结构单元中还存在两个结构几乎相同的分子，这两个分子只在键长、键角上有轻微差别。

A new macrocyclic ligand was synthesized by the condensation of 1,3-propylenediamine and triamine.

用丙二胺和三-胺，在无水甲醇中进行环缩合反应，生成了一个杂原子大环配体。

Chapter 1 describes the synthesis and characterization of a novel tridentate benzamidinato ligand[2SiNMe2](Si=linking group)la.

第一章根据含氮的胺类化合物的良好的反应性和配位性。

Two novel tridentate polypyridyl mixed-ligand cobalt [Co(H2Bzimpy)]3+ and ruthenium complexes were synthesized and characterized via elemental analysis and 1H NMR. The crystal structure of complex B was determined.

合成了两种新型三齿多吡啶钴 [Co(H2Bzimpy)]3+和钌混配配合物，用元素分析和1H NMR等对其结构进行了表征，测定了配合物B的晶体结构。

Two novel tridentate polypyridyl mixed-ligand cobalt [Co (H2Bzimpy)(superscript 3+)] and ruthenium complexes were synthesized and characterized via elemental analysis and (superscript 1)H NMR. The crystal structure of complex B was determined. The interactions between the complexes and calf thymus DNA were investigated with absorption and fluorescence spectroscopys. Photoactivated cleavage of pBR322DNA by the synthesized complexes were studied.

合成了两种新型三齿多吡啶钴[Co(H2Bzimpy)](上标 3+)和钌混配配合物，用元素分析和1HNMR等对其结构进行了表征，测定了配合物B的晶体结构用电子吸收光谱和荧光光谱等方法研究了配合物与小牛胸腺DNA的相互作用以及配合物对pBR322DNA的断裂作用。

Based on literature procedures, a dithiol tridentate ligand containing amino groupand its iron carbonyl complex (4) are synthesised and characterised. An attempt isalso made to protonate this complex.

在文献方法的基础上也合成了含有氨基的二硫醇三齿配体及其铁羰基化合物[Fe_2(SCH_2)_2C(CH_2NH_2)_5](4)的合成与表征，尝试了合成该化合物的质子化产物。

The copper center was situated in a distorted square pyramidal (4+1) CuN3X2 coordination geometry with terpyridine acting as an equatorial tridentate ligand.

在配合物中，中心铜原子的配位环境为变形四为锥，并通过分子内和分子间的C-H…C1和C-H…O氢键作用形成三维梯状结构。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。