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In complex 2, the manganese ion is six-coordinated by two oxygen atoms and two nitrogen atoms from a quadridentate ligand Lb. as well as one oxygen atom from DMF and one cyanide nitrogen atom from [Fe3] (superscript -) in axial positions.

化合物2中，[Fe3]通过其中的1个氰基与桥联，其中Mn离子为六配位，分别和四齿配体Lb的2个氧原子和2个氮原子、DMF的1个氧原子及[Fe3]中的氰基氮原子配位。

the title compound was synthesized and its structure was studied in theory.the schiff base compound was synthesized by condensation of paeonol with furylfurylamine,then it was deoxidized by sodium borohydried.the energies,bound lengths,bound angles,the net charges of main atom and contributive percents of frontier orbital in the title compound have been calculated by software hyperchem 7.0 in half experience method.the yield rate of title compound was 65.6%.the result of calculation showed that the most of the bond lengths and angles in the system were in the the normal range,negative charge mainly concentrate on o1,o2,o3 and n1.the title compound behaves as quadridentate ligand.

目的合成标题化合物并对其结构进行了理论研究。方法以丹皮酚和糠胺为原料合成席夫碱，经硼氢化钠还原得标题化合物；使用hyperchem7.0程序，用半经验方法计算了化合物分子中能量分布、主要键长、键角以及主要原子的净电荷分布和前言轨道分布。结果标题化合物，收率65.6%；计算结果分析表明，分子中主要原子之间的键长、键角基本在正常的范围内；负电荷主要集中于o1，o2，o3和n1上。

However, phosphotyrosine protein and Stat3 are subsequently activa ted through phosphorylation. In scar tissues, although EGFR has an intrinsic ty rosine kinase activity when activated by EGFR correlated ligand, phosphorylation of Stat3 showed no significant changes.

早期不同的配体刺激造成EGFR表达差异，随后导致酪氨酸蛋白磷酸化的不同，在正常的皮肤中Stat3磷酸化继续引起下游信号的表达，而瘢痕组织中Stat3磷酸化与正常情况无显著差别，造成信号不匹配。

The dependence of the radiolabeling yield of ~99mTcO-NIET and 99mTcN-NIET on pH, temperature, ligand concentration, the amount of added stannous chloride, and so on was screened by the normal procedure.

合成了一种新的氨荒酸类化合物，2-（4-硝基咪唑）-乙基二硫代氨基甲酸钾，研究了影响99mTcO-NIET以及99mTcN-NIET标记率的相关因素。

As a result, the steric hindrance in second ligand plays an important role for tuning magnetic transform.

因此，第二配体的位阻效应对调节磁性转变起了决定作用。

However, when trans-4-aryl-3-buten-2-ones were taken as the substrates, the electron-rich but less sterically hindered ligand 9c gives the best results (up to 96.4 % ee) with highly catalytic activity.

而富电子但空间位阻小的配体9c对亚节基丙酮类底物获得最好的结果(%。4%ee)，同时还表现了最好的化学活性。

The electron-rich and sterically hindered ligand 9d provides the best enantioselectivities (up to 97.8 % ee) for various chalcones as the substrates.

其中富电子且空间位阻较大的配体gd对查耳酮类底物表现了最好的手性诱导能力，加成产物的ee值达到94.7一97.8%。

The ligand of the chiral Schiff base and acetylacetone vanadium are subjected to complexation in situ, hydrogen peroxide is taken as an oxidant, aryl alkyl thioether asymmetric oxidation reaction is catalyzed in a toluene or dichloromethane solution under low temperature or room temperature, enantioselectivity of chiral sulphoxide is 72 percent to 95 percent ee, and yield is 42 percent to 83 percent.

将上述手性西佛碱配体与乙酰丙酮氧钒原位络合，采用双氧水为氧化剂，在甲苯或二氯甲烷溶液中低温至室温下催化芳基烷基硫醚不对称氧化反应，手性亚砜的对映选择性为72％-95％ee，产率为42％-83％。

Part 6 explores the reaction system containing O-phthalate, Mn〓 and α,α'-diimine, and yields six novel complexes 16～20 possessing binuclear and tetranuclear matello-crown aether as well as 1-D linear structures, indicating that O-phthalate is a potentially useful ligand to give manganese species in a discrete form.

研究了邻苯二甲酸/锰/双齿亚胺（2，2'-联吡啶和1，10-邻二氮杂菲）的反应体系，合成出6个新颖的双核、四金属冠醚和一维线性结构的化合物16至20，表明邻苯二甲酸是合成有限核数锰簇的有用配体。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。