查询词典 ligand

Phenanthroline ligand was tuned by incorporating triphenylamine group with hole-transporting nature and oxadiazole groups with electron-transporting nature into phenanthroline, which can help their europium complexes to have improved carrier-transporting property and increased luminous efficiency.

研究的主要内容有： 1通过引入三芳胺空穴传输单元和噁二唑电子传输单元，对邻菲罗啉中性配体进行分子修饰，从而改善它的铕配合物的载流子传输性能，提高铕配合物的发光效率。

The structure analysis indicates that the reverse symmetry ligand H4LB molecules are linked into a 2D supermolecular network by two types of hydrogen bonds. One type occurs between the oxalamide oxygen group and the phenol hydroxyl qroup of the nearest molecule with d=2.906(2) and ∠O-H…O=151.8°. The other type is between the oxalamide nitrogen group and the oxalamide oxygen group of anther molecule with d=2.849(2),∠N-H…O=158.7°.

晶体结构研究表明配体H4L为顺式桥联分子，晶体中存在两种氢键，一种是草酰胺基团的O原子与苯环上的酚羟基形成O-H…O氢键[d=2.906(2)，∠O-H…O=151.8°]；另一种是草酰胺基团的氨基与相邻草酰胺基上的O原子形成N-H…O氢键[d=2.849(2)，∠N-H…O=158.7°]，通过上述两种氢键将化合物H4LB连接成二维网络结构。

To improve the yield of an Amide-type Tripodal Ligand and investigate its coordination with rare earth ion under mild condition,a series of Amide-type Tripodal Ligands(L1—L4) have been prepared by the reactions of nitrilotriacetic acid and oxalyl chloride with four kinds of amides,respectively.

为了提高酰胺型三脚架型配体的产率，进一步研究其与稀土离子的配位形式及配合物的荧光性能，以氨三乙酸为母体，草酰氯为氯化试剂，与4种胺在较温和的条件下合成了具有三脚架型结构的配体(L1—L4)，并考察了实验条件、反应温度、反应体系溶剂、缚酸剂、反应时间及催化剂对反应产率的影响。

Kinetic spectrophotometric method for the determinationof trace nitrilotriacetic acid;2. To improve the yield of an Amide-type Tripodal Ligand and investigate its coordination with rare earth ion under mild condition,a series of Amide-type Tripodal Ligands(L1—L4) have been prepared by the reactions of nitrilotriacetic acid and oxalyl chloride with four kinds of amides,respectively.

为了提高酰胺型三脚架型配体的产率，进一步研究其与稀土离子的配位形式及配合物的荧光性能，以氨三乙酸为母体，草酰氯为氯化试剂，与4种胺在较温和的条件下合成了具有三脚架型结构的配体(L1—L4)，并考察了实验条件、反应温度、反应体系溶剂、缚酸剂、反应时间及催化剂对反应产率的影响。

In a DMF solution of CuCl〓-ethanolamine-acetic acid (1: 2: 2), 27 formed a highly oxidized heterocyclic compound 2-hydroxymethyl-naphtho [1, 2-a] oxazole (30) by the carbon-nitrogen coupling and carbon-oxygen coupling with the ligand of ethanolamine, which brings a chance to develop a novel approach to this heterocyclic compound via one-pot reaction of phenols under mild condition.

在氯化铜—乙醇胺—乙酸（1：2：2）的DMF溶液中，27与配体乙醇胺发生碳氮偶合与碳氧偶合，生成深度氧化的杂环化合物：2-羟甲基-萘并[1，2-a]〓唑（30）。这可望为酚类一锅化直接转化为30及其类似物提供一种简便的新合成路线。

Objective: To study the pathogenetic role and expression of Fas antigen and Fas ligand in severe cases of hepatitis D.

目的：探讨Fas／FasL途径介导的肝细胞凋亡在丁型肝炎重型化机制中的作用。

The effects of Caoguozhimu Decoction, a TCM antiepileptic, on NMDA receptor binding capacity and the expression of NMDAR1 mRNA in pentylene tetrazole-kindled rat model were observerd by the ligand-receptor method and i n situ hybridization, with MK-801 as a contrast.

观察抗癫痫中药草果知母汤在阻断戊四唑点燃模型形成过程中，对兴奋性氨基酸类神经递质Glu的受体NMDA结合力及其NMDAR1 mRNA的影响。以NMDA的竞争性拮抗剂MK- 801为对照，用配基受体法、原位杂交法检测相应指标的变化。

In order to further understand the dependence of bioactivities on the structure of new fluorine-containing pesticidal compounds to build up significant ligand-receptor models, and to find out the pharmacophores of these analogues, 3D-QSAR analyses have been carried out with DISCO, CoMFA and Leapfrog approaches on the basis of our previous classical QSAR study. Firstly, the compounds were classified according to their structures.

为了能更深入地认识含氟新化合物作为农药的生物活性和其结构间的关系，建立有意义的药物-受体作用模型，寻找同类化合物的药效团，对合成的含氟化合物在经典QSAR方法研究的基础上，又进一步运用DISCO，CoMFA和Leapfrog方法研究了它们的三维构效关系。

Searching for specific ligand to a certain recepter or enzyme in human body from secondary metabolities of plants, animals and microorganisms, Optimization of lead compound under certain theory or hypothesis, and synthesis methodology investigation of pharmaceutically active compound are all tasks of medicinal chemistry.

药物化学的研究领域十分宽广，既有从动物、植物、微生物的次生代谢产物中寻找与人体内特异性的受体、酶的激动剂或拮抗剂，又有在理论、假想指导下的先导化合物的优化，以及生理活性化合物的合成方法学研究。

At last, the construstion of C-glycoside by Stille coupling was described, which involved in the use of CuI as catalyst and 4,7-diphenyl-1,10- phenanthroline as ligand was developed.

第5章研究了Stille偶联反应在构筑碳苷中的应用，发展了以CuI为催化剂，4，7-二苯基邻菲罗啉为配体构筑碳苷的方法。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。