查询词典 ligand

It is worthy pointing out that there are two types of Ag-C bonding models found in 19 including /7\'-C6H6-Ag and /72-Cp-Ag.Three new H-bonded one-dimensional supramolecular compounds, namely M(C3oH2iN2O2)2(C2H5OH)2 M - Cu(II (20), Co (21) and Mn (22), were also synthesized by the reactions of metal (Cu2+, Co2+, Mn2+) acetate with this new type of fulvene ligand.

用所合成刚性多齿有机配体与过渡金属Cu~(2+)(来源：AB4dC论文网www.abclunwen.com)、Co~(2+)、Mn~(2+)的醋酸盐反应，分别合成了含七员金属环的配合物(20—22)，在固态下，20—22为分子间氢键驱动的一维链状超分子聚集体。

O methoxy phenyl lithium reacts with 6,6 dimethyl fulvene to give ligand lithium (Cp ′Li,Cp ′ represents cyclopentadienyl with substituents).

邻甲氧基苯基锂和 6，6-二甲基富烯(或 6，6-二乙基富烯)反应得配体锂盐，Cp′ Li直接和 Cp Zr Cl3· DME反应生成 2个新的锆络合物 Cp′ Cp Zr Cl2 。

A novel supramolecular complex, [Cu2]CH3OHH2O (fum=fumarate dianion, dpphen=4, 7-diphenyl-1, 10-phenanthroline), has been prepared from the reaction of bidentate ligand, fumarate with CuCl2, and were characterized by element analysis, IR, thermal analysis and X-ray diffraction technique.

利用螯合配体4，7-二苯基－1，10-邻菲罗啉与反丁烯二酸钠及铜盐反应合成了一种新型超分子配合物[Cu2]CH3OHH2O（fum=反丁烯二酸根，dpphen=4，7-二苯基－1，10-邻菲罗啉）。通过元素分析、红外光谱、热分析和X射线单晶衍射等技术对其进行了表征。

Furthermore, during the ligand binding process, the decrease in βturns and increase in α-helices was a slow process.

此外，在蛋白与配基的结合过程中，β-回折的减少和α-螺旋的增加是一个缓慢的过程。

NMDA(N-methyl-D-aspartate) receptors are a subtype of excitatory transmitters-glutamate receptor which belong to a heteromeric ligand-gated ionotropic receptors and play an important role in many complex physiological and pathological processes, such as nerve development, neuronal excitatory synaptic transmission, synaptic plasticity, central sensitization and neuronal death.

NMDA(N-methyl-D-aspartate)受体是兴奋性神经递质谷氨酸受体的一种亚型，是一种异聚体配体门控型离子通道，参与体内神经发育、神经元的兴奋性突触传递、突触可塑性、中枢敏化、神经元死亡等多种不同的生理和病理过程。

Glutamate is the major excitatory neurotransmitter in the mammalian brain and key mediator of intracellular communication, plasticity, growth and differentiation. NMDA receptors is one kind of Glutamate receptors. The N-methyl-D-aspartate receptor is a heteromeric ligand-gated ion channel that interacts with multiple intracellular proteins by way of different subunits.

N-甲基-D-天门冬氨酸受体是一种门控离子通道复合物，作为兴奋性氨基酸受体之一，主要分布于大脑皮层、海马、纹状体等部位，是兴奋性氨基酸递质传递的重要基础，同时是维持中枢神经系统功能正常的关键因素。

The transforming growth factor-β superfamily, a large group of highly conserved growth factors including TGF-βs, activins and BMPs, regulate a wide variety of cellular functions such as proliferation, differentiation, apoptosis and migration. Signals from these growth factors are transduced by a group of Smad proteins. To date, there are nine vertebrate Smads, including the receptor-activated Smads , Smadsl-3, 5 and 8, the common mediator Smad4 and Smad4β, and the inhibitory Smads, Smad6 and 7. Signaling is initiated when the ligand induces assembly of a heteromeric complex of type Ⅱ and type Ⅰ TGFβ receptors. Then R-Smads are directly phosphorylated by activated type I TGF-β receptors.

在多种SMADS中，SMAD5令我们产生兴趣，基于三个原因：1、Smad5基因敲除胚胎中发现卵黄囊的异位造血以及CFU-GM祖细胞数目增加，表明SMAD5可能是早期造血发育的负向调控基因。；2、应用反义核酸封闭Smad5可以逆转TGF-β对祖细胞增殖的抑制效应，表明它可能介导TGF-β信号转导，后者的异常，包括某些SMADS的功能异常，和白血病紧密相关；3、Smad5基因定位在人染色体5q21，此区域的缺失和急性髓系白血病和骨髓增生异常综合症相关，因此，Smad5被怀疑为白血病抑制基因。

CdS nanoclusters were synthesized by using the octylthioalcohol or dodecylthioalcohol as ligand and the hexadecyl trimethyl ammonium bromine as organic positive ion.

分别引入辛基硫醇和十二烷基硫醇作配体，十六烷基三甲基溴化铵作有机正离子合成CdS纳米簇合物。

It is concluded that if palladium ion coordinated with ligands is electron deficient and ligands have less steric hinderance, the palladium complex will have higher catalytic activity. According to this rule, we can tone ligand in palladium complex and improve its activity.

如果配体能使Pd〓的电子缺乏，具有较小的空间位阻，Pd配合物的活性就会提高，因此可根据这一结论对Pd配合物中的配体进行调配，提高其催化活性。

Reaction of the ligand with CdI2 or Cu(NO3)2 afforded dinuclear monohelical complexes 1 and 2 equipped with the aromatic rings, and the complex interacted each other through cooperative C-H...π and π...π interactions to form homochiral 2D layer along ab plane.

配体与CdI2和Cu(NO3)2反应得到双核单螺旋化合物1和2，在化合物2中，由于C-H…π和π…π的协同相互作用沿ab面形成单一手性的二维平面。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。